-
1
-
-
0033557814
-
-
(a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 428.
-
(1999)
Angew. Chem., Int. Ed.
, vol.38
, pp. 428
-
-
Britovsek, G.J.P.1
Gibson, V.C.2
Wass, D.F.3
-
4
-
-
84985598264
-
-
(a) Starzewski, K. A. O.; Witte, J. Angew. Chem., Int. Ed. Engl. 1985, 24, 599.
-
(1985)
Angew. Chem., Int. Ed. Engl.
, vol.24
, pp. 599
-
-
Starzewski, K.A.O.1
Witte, J.2
-
5
-
-
6544241298
-
-
(b) Johnson, L. K; Killian, C. M.; Brookhart, M. J. Am. Chem. Soc. 1995, 117, 6414.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 6414
-
-
Johnson, L.K.1
Killian, C.M.2
Brookhart, M.3
-
6
-
-
18444374543
-
-
Johnson, L. K.; Killian C. M.; Bennett, A. M. A.; Coughlin, E. B.; Ittel, S. D.; Parthasarathy, A.; Tempel, D. J.; Brookhart, M. S. WO 9603010, 1996
-
(c) Johnson, L. K.; Killian C. M.; Bennett, A. M. A.; Coughlin, E. B.; Ittel, S. D.; Parthasarathy, A.; Tempel, D. J.; Brookhart, M. S. WO 9603010, 1996.
-
-
-
-
7
-
-
0032577046
-
-
(a) Small, B. L.; Brookhart, M.; Bennett, A. M. A. J. Am. Chem. Soc. 1998, 120, 4049.
-
(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 4049
-
-
Small, B.L.1
Brookhart, M.2
Bennett, A.M.A.3
-
8
-
-
21844436802
-
-
(b) Britovsek, G. J. P.; Gibson, V. C.; Kimberley, B. S.; Solan, G. A.; White, A. J. P.; Williams, D. J. Chem. Commun. 1998, 849.
-
(1998)
Chem. Commun.
, pp. 849
-
-
Britovsek, G.J.P.1
Gibson, V.C.2
Kimberley, B.S.3
Solan, G.A.4
White, A.J.P.5
Williams, D.J.6
-
10
-
-
0033615288
-
-
(b) Britovsek, G. J. P.; Bruce, M.; Gibson, V. C.; Kimberley, B. S.; Maddox. P. J.; Mastroianni, S.; McTavish, S. J.; Redshaw, C.; Solan, G. A.; Strömberg, S.; White, A. J. P.; Williams, D. J. J. Am. Chem. Soc. 1999, 121, 8728.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 8728
-
-
Britovsek, G.J.P.1
Bruce, M.2
Gibson, V.C.3
Kimberley, B.S.4
Maddox, P.J.5
Mastroianni, S.6
McTavish, S.J.7
Redshaw, C.8
Solan, G.A.9
Strömberg, S.10
White, A.J.P.11
Williams, D.J.12
-
11
-
-
0034674309
-
-
(c) Britovsek, G. J. P.; Mastroianni, S.; Solan, G. A.; Baugh, S. P. D.; Redshaw, C.; Gibson, V. C.; White, A. J. P.; Williams, D. J.; Elsegood, M. R. J. Chem. Eur. J. 2000, 6, 2221.
-
(2000)
Chem. Eur. J.
, vol.6
, pp. 2221
-
-
Britovsek, G.J.P.1
Mastroianni, S.2
Solan, G.A.3
Baugh, S.P.D.4
Redshaw, C.5
Gibson, V.C.6
White, A.J.P.7
Williams, D.J.8
Elsegood, M.R.J.9
-
12
-
-
0035540725
-
-
(d) Ma, Z.; Wang, H.; Qiu, J.; Xu, D.; Hu, Y. Macromol. Rapid. Commun. 2001, 22, 1280.
-
(2001)
Macromol. Rapid. Commun.
, vol.22
, pp. 1280
-
-
Ma, Z.1
Wang, H.2
Qiu, J.3
Xu, D.4
Hu, Y.5
-
13
-
-
0036810069
-
-
(e) Ma, Z.; Sun, W.-H.; Li, Z.-L.; Shao, C.-X.; Hu, Y.-L., Li, X.-H. Polym. Int. 2002, 51, 994.
-
(2002)
Polym. Int.
, vol.51
, pp. 994
-
-
Ma, Z.1
Sun, W.-H.2
Li, Z.-L.3
Shao, C.-X.4
Hu, Y.-L.5
Li, X.-H.6
-
14
-
-
0037764798
-
-
(f) Britovsek, G. J. P.; Gibson, V. C.; Hoarau, O. D.; Spitzmesser, S. K.; White, A. J. P.; Williams, D. J. Inorg. Chem. 2003, 42, 3454.
-
(2003)
Inorg. Chem.
, vol.42
, pp. 3454
-
-
Britovsek, G.J.P.1
Gibson, V.C.2
Hoarau, O.D.3
Spitzmesser, S.K.4
White, A.J.P.5
Williams, D.J.6
-
15
-
-
0037451075
-
-
(g) Chen, Y.; Qian, C.; Sun, J. Organometallics 2003, 22, 1231.
-
(2003)
Organometallics
, vol.22
, pp. 1231
-
-
Chen, Y.1
Qian, C.2
Sun, J.3
-
16
-
-
0037432947
-
-
(h) Schmidt, R.; Hammon, U.; Gottfried, S.; Welch, M. B.; Alt, H. G. J. Appl. Polym. Sci. 2003, 88, 476.
-
(2003)
J. Appl. Polym. Sci.
, vol.88
, pp. 476
-
-
Schmidt, R.1
Hammon, U.2
Gottfried, S.3
Welch, M.B.4
Alt, H.G.5
-
17
-
-
0036533107
-
-
(i) Abu-Surrah, A. S.; Lappalainen, K.; Piironen, U.; Lehmus, P.; Repo, T.; Leskelä, M. J. Organomet. Chem. 2002, 55.
-
(2002)
J. Organomet. Chem.
, pp. 55
-
-
Abu-Surrah, A.S.1
Lappalainen, K.2
Piironen, U.3
Lehmus, P.4
Repo, T.5
Leskelä, M.6
-
18
-
-
0142165764
-
-
(j) Chen, Y.; Chen, R.; Qian. C.; Dong, X.; Sun, J. Organometallics 2003, 22, 4312.
-
(2003)
Organometallics
, vol.22
, pp. 4312
-
-
Chen, Y.1
Chen, R.2
Qian, C.3
Dong, X.4
Sun, J.5
-
19
-
-
3543130114
-
-
(k) Ivanchev, S. S.; Tolstikov, G. A.; Badaev, V. K.; Oleinik, I.I.; Ivancheva, N. I.; Rogozin, D. G.; Oleinki, I. V.; Myakin, S. V. Kinet. Catal. 2004, 45, 176.
-
(2004)
Kinet. Catal.
, vol.45
, pp. 176
-
-
Ivanchev, S.S.1
Tolstikov, G.A.2
Badaev, V.K.3
Oleinik, I.I.4
Ivancheva, N.I.5
Rogozin, D.G.6
Oleinki, I.V.7
Myakin, S.V.8
-
21
-
-
1242331853
-
-
(m) Bluhm, M. E.; Folli, C.; DÖring, M. J. Mol. Catal. A 2004, 212, 13.
-
(2004)
J. Mol. Catal. A
, vol.212
, pp. 13
-
-
Bluhm, M.E.1
Folli, C.2
Döring, M.3
-
22
-
-
6344261813
-
-
(n) Smit, T. M.; Tomov, A. K.; Gibson, V. C.; White, A. J. P.; Williams, D. J. Inorg. Chem. 2004, 43, 6511.
-
(2004)
Inorg. Chem.
, vol.43
, pp. 6511
-
-
Smit, T.M.1
Tomov, A.K.2
Gibson, V.C.3
White, A.J.P.4
Williams, D.J.5
-
23
-
-
12844287560
-
-
(o) Tellmann, K. P.; Gibson, V. C.; White, A. J. P.; Williams, D. J. Organometallics 2005, 24, 280.
-
(2005)
Organometallics
, vol.24
, pp. 280
-
-
Tellmann, K.P.1
Gibson, V.C.2
White, A.J.P.3
Williams, D.J.4
-
24
-
-
0032570891
-
-
(a) Siedle, A. R.; Lamanna, W. M.; Newark, R. A.; Schroepfer, J. N. J. Mol. Catal. A 1998, 128, 257.
-
(1998)
J. Mol. Catal. A
, vol.128
, pp. 257
-
-
Siedle, A.R.1
Lamanna, W.M.2
Newark, R.A.3
Schroepfer, J.N.4
-
25
-
-
0033579145
-
-
(b) Svejda, S. A.; Johnson, L. K; Brookhart, M. J. Am. Chem. Soc. 1999, 121, 10634.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 10634
-
-
Svejda, S.A.1
Johnson, L.K.2
Brookhart, M.3
-
26
-
-
0141716965
-
-
(a) For an example on nickel see: Strauch, J. W.; Kehr, G.; Erker, G. J. Organomet. Chem. 2003, 683, 249.
-
(2003)
J. Organomet. Chem.
, vol.683
, pp. 249
-
-
Strauch, J.W.1
Kehr, G.2
Erker, G.3
-
27
-
-
18444418986
-
-
(b) For an overview see: Erker, G. Acc. Chem. Res. 2001, 34, 47.
-
(2001)
Acc. Chem. Res.
, vol.34
, pp. 47
-
-
Erker, G.1
-
28
-
-
0035958990
-
-
(a) Talsi, E. P.; Babushkin, D. E.; Semikolenova, N. V.; Zudin, V. N.; Panchenko, V. N.; Zakharov, V. A. Macromol. Chem. Phys. 2001, 202, 2046.
-
(2001)
Macromol. Chem. Phys.
, vol.202
, pp. 2046
-
-
Talsi, E.P.1
Babushkin, D.E.2
Semikolenova, N.V.3
Zudin, V.N.4
Panchenko, V.N.5
Zakharov, V.A.6
-
29
-
-
4444288015
-
-
(b) Semikolenova, N. V.; Zakharov, V. A.; Talsi, E. P.; Babushkin, D. E.; Sobolev, A. P.; Echevskaya, L. G.; Khysniyarov, M. M. J. Mol. Catal. A 2002, 182-183, 283.
-
(2002)
J. Mol. Catal. A
, vol.182-183
, pp. 283
-
-
Semikolenova, N.V.1
Zakharov, V.A.2
Talsi, E.P.3
Babushkin, D.E.4
Sobolev, A.P.5
Echevskaya, L.G.6
Khysniyarov, M.M.7
-
30
-
-
8344238959
-
-
(c) Bryliakov, K. P.; Semikolenova, N. V.; Zakharov, V. A.; Talsi, E. P. Organometallics 2004, 23, 5375.
-
(2004)
Organometallics
, vol.23
, pp. 5375
-
-
Bryliakov, K.P.1
Semikolenova, N.V.2
Zakharov, V.A.3
Talsi, E.P.4
-
31
-
-
0001053942
-
-
(a) Britovsek, G. J. P.; Clentsmith, G. K. B.; Gibson, V. C.; Goodgame, D. M. L.; McTavish, S. J.; Pankhurst, Q. A. Catal. Commun. 2002, 3, 207.
-
(2002)
Catal. Commun.
, vol.3
, pp. 207
-
-
Britovsek, G.J.P.1
Clentsmith, G.K.B.2
Gibson, V.C.3
Goodgame, D.M.L.4
McTavish, S.J.5
Pankhurst, Q.A.6
-
32
-
-
1642401888
-
-
(b) Bryliakov, K. P.; Semikolenova, N. V.; Zudin, V. N.; Zakharov, V. A.; Talsi, E. P. Catal. Commun. 2004, 5, 45.
-
(2004)
Catal. Commun.
, vol.5
, pp. 45
-
-
Bryliakov, K.P.1
Semikolenova, N.V.2
Zudin, V.N.3
Zakharov, V.A.4
Talsi, E.P.5
-
33
-
-
0035824042
-
-
(a) Gibson, V. C.; Humphries, M. J.; Tellmann, K. P.; Wass, D. F.; White, A. J. P.; Williams, D. J. Chem. Commun. 2001, 2252.
-
(2001)
Chem. Commun.
, pp. 2252
-
-
Gibson, V.C.1
Humphries, M.J.2
Tellmann, K.P.3
Wass, D.F.4
White, A.J.P.5
Williams, D.J.6
-
34
-
-
0035905511
-
-
(b) Kooistra, T. M.; Knijenburg, Q.; Smits, J. M. M.; D. Horton, A.; Budzelaar, P. H. M.; Gal, A. W. Angew. Chem., Int. Ed. 2001, 40, 4719.
-
(2001)
Angew. Chem., Int. Ed.
, vol.40
, pp. 4719
-
-
Kooistra, T.M.1
Knijenburg, Q.2
Smits, J.M.M.3
Horton, D.A.4
Budzelaar, P.H.M.5
Gal, A.W.6
-
35
-
-
0036406624
-
-
(a) Gibson, V. C.; Tellmann, K. P.; Humphries, M. J.; Wass, D. F. Chem. Commun. 2002, 2316.
-
(2002)
Chem. Commun.
, pp. 2316
-
-
Gibson, V.C.1
Tellmann, K.P.2
Humphries, M.J.3
Wass, D.F.4
-
36
-
-
9144247820
-
-
(b) Tellmann, K. P.; Humphries, M. J.; Rzepa, H. S.; Gibson, V. C. Organometallics 2004, 23, 5503.
-
(2004)
Organometallics
, vol.23
, pp. 5503
-
-
Tellmann, K.P.1
Humphries, M.J.2
Rzepa, H.S.3
Gibson, V.C.4
-
37
-
-
0002426616
-
-
Brookhart, M.; Green, M. L. H.; Wong, L.-L. Progr. Inarg. Chem. 1988, 36, 1.
-
(1988)
Progr. Inarg. Chem.
, vol.36
, pp. 1
-
-
Brookhart, M.1
Green, M.L.H.2
Wong, L.-L.3
-
38
-
-
4544273791
-
-
Knijnenburg, Q.; Hetterscheid, D.; Kooistra, T. M.; Budzelaar, P. H. M. Eur. J. Inorg. Chem. 2004, 1204.
-
(2004)
Eur. J. Inorg. Chem.
, pp. 1204
-
-
Knijnenburg, Q.1
Hetterscheid, D.2
Kooistra, T.M.3
Budzelaar, P.H.M.4
-
39
-
-
18444378568
-
-
note
-
While this description of the systems as cobalt(II) bound to a ligand radical may be correct, we will continue to refer to these systems as Co(I) in this article in order to avoid confusion with cobalt(II) complexes such as 1. The distribution of electrons within the cobalt(I) complexes docs not affect our later mechanistic experiments and conclusions.
-
-
-
-
40
-
-
18444381866
-
-
note
-
3 or MAO; the MAO-activated cation will be referred to as 13-MAO.
-
-
-
-
42
-
-
0036301896
-
-
Clentsmith, G. K. B.; Gibson, V. C.; Hitchcock, P. B.; Kimberley, B. C.; Rees, C. W. Chem. Commun. 2002, 1498.
-
(2002)
Chem. Commun.
, pp. 1498
-
-
Clentsmith, G.K.B.1
Gibson, V.C.2
Hitchcock, P.B.3
Kimberley, B.C.4
Rees, C.W.5
-
43
-
-
18444392842
-
-
note
-
2H NMR data to be obtained. Although the cobalt (I) complexes are generally unstable in chlorinated and brominated solvents, leading to unidentified paramagnetic products, no decomposition is seen in the sterically protected 2-chlorotoluene over a period of at least 5 h.
-
-
-
-
44
-
-
18444397587
-
-
note
-
Dry MAO is the white solid obtained by removal of solvent and trialkylaluminums from a solution of MAO, followed by repeated slurrying in heptane and removal of the volatile components.
-
-
-
-
47
-
-
0035796595
-
-
(b) Cano, J.: Royo, P.; Lanfranchi, M.; Pellmghelli, M. A.; Tiripicchio, A. Angew. Chem., Int. Ed. 2001, 40, 2495.
-
(2001)
Angew. Chem., Int. Ed.
, vol.40
, pp. 2495
-
-
Cano, J.1
Royo, P.2
Lanfranchi, M.3
Pellmghelli, M.A.4
Tiripicchio, A.5
-
51
-
-
33845185515
-
-
(c) Ghosh, C. K.; Hoyano, J. K.; Krentz, R.; Graham, W. A. G. J. Am. Chem. Soc. 1989, 111, 5480.
-
(1989)
J. Am. Chem. Soc.
, vol.111
, pp. 5480
-
-
Ghosh, C.K.1
Hoyano, J.K.2
Krentz, R.3
Graham, W.A.G.4
-
53
-
-
0006360491
-
-
(e) Papenfuhs, B.; Mahr, N.; Werner, H. Organometallics 1993, 12, 4244.
-
(1993)
Organometallics
, vol.12
, pp. 4244
-
-
Papenfuhs, B.1
Mahr, N.2
Werner, H.3
-
54
-
-
0038620081
-
-
(f) Gutiérrez-Puebla, E.; Monge, A.; Nicasio, M. C.; Feréz, P. J.; Poveda, M. L.; Rey, L.; Ruíz, C.; Carmona, E. Inorg. Chem. 1998, 37, 4538.
-
(1998)
Inorg. Chem.
, vol.37
, pp. 4538
-
-
Gutiérrez-Puebla, E.1
Monge, A.2
Nicasio, M.C.3
Feréz, P.J.4
Poveda, M.L.5
Rey, L.6
Ruíz, C.7
Carmona, E.8
-
55
-
-
3743090718
-
-
Kawakami, K.; Mizoroki, T.; Ozaki, A. Bull. Chem. Soc. Jpn. 1978, 51, 21.
-
(1978)
Bull. Chem. Soc. Jpn.
, vol.51
, pp. 21
-
-
Kawakami, K.1
Mizoroki, T.2
Ozaki, A.3
-
56
-
-
18444409495
-
-
note
-
4; no equilibrium is observed. It thus appears that the tertiary amine is too bulky to interact with the sterically protected cobalt center.
-
-
-
-
57
-
-
2942702054
-
-
Steffen, W.; Blömker, T.; Kleigrewe, N.; Kehr, G.; Fröhlich, R.; Erker, G. Chem. Commun. 2004, 1188.
-
(2004)
Chem. Commun.
, pp. 1188
-
-
Steffen, W.1
Blömker, T.2
Kleigrewe, N.3
Kehr, G.4
Fröhlich, R.5
Erker, G.6
-
58
-
-
1042288201
-
-
Agapie, T.; Schofer, S. J.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 2004, 126, 1304
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 1304
-
-
Agapie, T.1
Schofer, S.J.2
Labinger, J.A.3
Bercaw, J.E.4
-
59
-
-
18444403866
-
-
note
-
5) groups were detectable in the polymer.
-
-
-
-
60
-
-
18444416962
-
-
note
-
Errors in all quantitative measurements obtained by NMR spectroscopy are estimated to be ±20%, arising mainly from errors in the integration of NMR signals.
-
-
-
-
61
-
-
18444376886
-
-
note
-
1H NMR spectrum, the presence of very low amounts of chain transfer cannot be ruled out completely.
-
-
-
-
62
-
-
18444389889
-
-
note
-
Insertion into the Co-H bond that results from a vinylic C-H activation (the less sterically demanding bond into which insertion could occur) would result in a polymer or oligomer with one methyl and one vinyl bond (as observed) whether the polymer was terminated by β-hydrogen elimination or reductive elimination. Insertion into the Co-vinyl bond would afford chains with one methyl and one vinyl chain end only if termination occurred via reductive elimination. If termination occurred by β-hydrogen elimination, dienes would result, which would be detectable among the oligomeric products.
-
-
-
-
63
-
-
0037577522
-
-
Habadie, N.; Dartiguenave, M.; Dartiguenave, Y.; Britten, J. F.; Beauchamp, A. Organometallics 1989, 8, 2564.
-
(1989)
Organometallics
, vol.8
, pp. 2564
-
-
Habadie, N.1
Dartiguenave, M.2
Dartiguenave, Y.3
Britten, J.F.4
Beauchamp, A.5
-
65
-
-
0345447044
-
-
(b) Daugulis, O.; Brookhart, M.; White, P. S. Organometallics 2003, 22, 4699.
-
(2003)
Organometallics
, vol.22
, pp. 4699
-
-
Daugulis, O.1
Brookhart, M.2
White, P.S.3
-
67
-
-
5244370033
-
-
Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1996, 15, 1518.
-
(1996)
Organometallics
, vol.15
, pp. 1518
-
-
Pangborn, A.B.1
Giardello, M.A.2
Grubbs, R.H.3
Rosen, R.K.4
Timmers, F.J.5
-
69
-
-
0002969691
-
-
(b) Chernega, A. N.; Graham, A. J.; Green, M. L. H.; Haggitt, J.; Lloyd, J.; Mehnert, C. P.; Metzler, N.; Souter, J. J. Chem. Soc., Dalton Trans. 1997, 2293.
-
(1997)
J. Chem. Soc., Dalton Trans.
, pp. 2293
-
-
Chernega, A.N.1
Graham, A.J.2
Green, M.L.H.3
Haggitt, J.4
Lloyd, J.5
Mehnert, C.P.6
Metzler, N.7
Souter, J.8
-
70
-
-
0005642333
-
-
Yang, P.-W.; Liou, K.-F.; Lin, Y.-T. J. Organomet. Chem. 1986, 307, 273.
-
(1986)
J. Organomet. Chem.
, vol.307
, pp. 273
-
-
Yang, P.-W.1
Liou, K.-F.2
Lin, Y.-T.3
|