Asymmetric Synthesis of 2,3-Dihydrofurans and of Unsaturated Bicyclic Tetrahydrofurans through α-Elimination and Migratory Cyclization of Silyloxy Alkenyl Aminosulfoxonium Salts. Generation and Intramolecular O, Si-Bond Insertion of Chiral Disubstituted β-Silyloxy AlkyHdene Carbenes

Journal of the American Chemical Society

Volumn 126, Issue 15, 2004, Pages 4859-4864

  Gais, Hans Joachim ^a   Reddy, Leleti R ^a   Babu, Gadamsetti S ^a   Raabe, Gerhard ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; ALDEHYDES; AMINES; CHEMICAL BONDS; ETHERS; FURAN RESINS; SILICON COMPOUNDS; SUBSTITUTION REACTIONS; TITANIUM COMPOUNDS;

2,3-DIHYDROFURANS; ACYCLIC ALLYLIC SULFOXIMINES; HOMOALLYLIC ALCOHOLS; TITANIUM COMPLEXES;

SYNTHESIS (CHEMICAL);

1,8 DIAZABICYCLO[5.4.0] 7 UNDECENE; 2,3 DIHYDROFURAN DERIVATIVE; ACYCLIC HYDROCARBON SUBSTITUENT; ALCOHOL DERIVATIVE; ALDEHYDE; ALKENYL GROUP; ALLYL COMPOUND; AMINE; BICYCLO COMPOUND; CARBENOID; FURAN DERIVATIVE; IMINE; LITHIUM DERIVATIVE; METHYL GROUP; OXYGEN; OXYGEN DERIVATIVE; SILANE DERIVATIVE; SILICON; SILICON DERIVATIVE; SULFINAMIDE; SULFOXIDE; SULFOXIMINE; SULFUR DERIVATIVE; TETRAHYDROFURAN DERIVATIVE; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHIRALITY; CYCLIZATION; DESILYLATION; DIASTEREOISOMER; ELIMINATION REACTION; ENANTIOMER; ISOMERIZATION; METHYLATION; SYNTHESIS;

EID: 1842841039     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja030501v     Document Type: Article

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