C-H Activation by a Diplatinum(II) Complex: Isolation and Structures of [Pt2(CH3)(SMe2)Ph 2(ttab)][BAr′4] and [Pt2(H 2O)2Ph2(ttab)][BAr′4] 2 (ttab = 1,2,4,5-Tetrakis(1-N-7-azaindolyl)benzene)

Organometallics

Volumn 23, Issue 6, 2004, Pages 1194-1196

  Song, Datong ^a   Jia, Wen Li ^a   Wang, Suning ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CATALYSIS; CHEMICAL ACTIVATION; CHEMICAL BONDS; COMPLEXATION; CRYSTAL LATTICES; CRYSTALLIZATION; CRYSTALLOGRAPHY; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SINGLE CRYSTALS; X RAY DIFFRACTION ANALYSIS;

BENZENE RINGS; BOND LENGTHS;

ORGANOMETALLICS;

EID: 1842482225     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0341449     Document Type: Article

References (21)

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14. 1 = 0.0770 (I > 2σ(I)), GOF = 0.788.
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17. 4 has been proposed by the Wayland group: (a) Sherry, A. E.; Wayland, B. B. J. Am. Chem. Soc. 1990, 112, 1259. (b) Wayland, B. B.; Ba, S.; Sherry, A. E. J. Am. Chem. Soc. 1991, 113, 5305.
18. 4 has been proposed by the Wayland group: (a) Sherry, A. E.; Wayland, B. B. J. Am. Chem. Soc. 1990, 112, 1259. (b) Wayland, B. B.; Ba, S.; Sherry, A. E. J. Am. Chem. Soc. 1991, 113, 5305.
19. 2 as the solvent. For details see the Supporting Information.
20. 1H NMR spectra very complex, and it is impossible to assign chemical shifts.
21. 4 was isolated. No evidence of double benzene activation was observed. The details will be reported in due course.