Diplatinum-center-mediated transformation of a substituted benzene to a cyclohexadienyl dianion and the breaking of C-Cl bonds: Syntheses and structures of Pt2R4(ttab) and Pt2(CH3)4(ttab)Cl2

Organometallics

Volumn 21, Issue 23, 2002, Pages 4978-4983

  Song, Datong ^a   Sliwowski, Katherine ^a   Pang, Jun ^a   Wang, Suning ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

LIGANDS;

BENZENE; CHEMICAL BONDS; COMPLEXATION; NEGATIVE IONS; PLATINUM; REACTION KINETICS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

ORGANOMETALLICS;

EID: 0038337848     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020641y     Document Type: Article

References (41)

1. (a) Houlding, V. H.; Miskowski, V. M. Coord. Chem. Rev. 1991, 111, 145.
2. (b) Pettijohn, C. N.; Jochnowitz, E. B.; Chuong, B.; Nagle, J. K.; Vogler, A. Coord. Chem. Rev. 1998, 771, 85.
3. (c) Yersin, H.; Humbs, W.; Strasser, J. Coord. Chem. Rev. 1997, 159, 325.
4. (d) Paw, W.; Cummings, S. D.; Mansour, M. A.; Connick, W. B.; Gieger, D. K.; Eisenberg, R. Coord. Chem. Rev. 1998, 171, 125.
5. (e) McGarrah, J. E.; Kim, Y. J.; Hissler, M.; Eisenberg, R. Inorg. Chem. 2001, 40, 4510.
6. (a) Chassot, L.; Müller, E.; von Zelewsky, A. Inorg. Chem. 1984, 23, 4249.
7. (b) Sandrini, D.; Maestri, M.; Balzani, V.; Chassot, L.; von Zelewsky, A. J. Am. Chem. Soc. 1987, 109, 3107.
8. (c) Vogler, A.; Kunkely, H. Coord. Chem. Rev. 1998, 177, 81.
9. (d) Wan, K. T.; Che, C. M.; Cho, K. C. J. Chem. Soc., Dalton Trans. 1991, 1077.
10. (a) Baldo, M. A.; O'Brien, D. F.; You, Y.; Shoustikov, A.; Sibley, S.; Thompson, M. E.; Forrest, S. R. Nature 1998, 395, 151.
11. (b) Lu, W.; Mi, B. X.; Chan, M. C. W.; Hui, Z.; Zhu, N.; Lee, S. T.; Che, C. M. Chem. Commun. 2002, 206.
12. (a) Wu, Q.; Hook, A.; Wang, S. Angew. Chem., Int. Ed. 2000, 39, 3933.
13. (b) Song, D.; Wu, Q.; Hook, A.; Kozin, I.; Wang, S. Organometallics 2001, 20, 4683.
14. (c) Liu, Q.; Thorne, L.; Kozin, I.; Song, D.; Seward, C.; D'Iorio, M.; Tao, Y.; Wang, S. J. Chem. Soc., Dalton Trans. 2002, 3234.
15. (a) Scott, J. D.; Puddephatt, R. J. Organometallics 1983, 2, 1643.
16. (b) Hill, G. S.; Irwin, M. J.; Levy, C. J.; Rendina, L. M.; Puddephatt, R. J. Inorg. Synth. 1998, 32, 149.
17. Song, D.; Wang, S. J. Organomet. Chem. 2002, 648, 302.
18. SMART for Window NT v5.050; Bruker AXS Inc: Madison, WI, 1998.
19. SAINT+ for NT v5.00; Bruker AXS Inc: Madison, WI, 1998.
20. SHELXTL NT v. 5.1; Bruker AXS Inc: Madison, WI, 1998.
21. (a) Goodbrand, H. B.; Hu, N. X. J. Org. Chem. 1999, 64, 670.
22. (b) Lindley, J. Tetrahedron 1984, 40, 1433.
23. (c) Fanta, P. E. Synthesis 1974, 1.
24. The Ag(I) and Pd(II) complexes of ttab will be published in due course.
25. Emsley, J. The Elements, 2nd ed.; Clarendon Press: Oxford, 1991.
26. (a) Crespo, M.; Puddephatt, R. J. Organometallics 1987, 6, 2548.
27. (b) Fraser, C. S. A.; Jenkins, H. A.; Jennings, M. C.; Puddephatt, R. J. Organometallics 2000, 19, 1635.
28. (c) Baar, C. R.; Hill, G. S.; Vittal, J. J.; Puddephatt, R. J. Organometallics 1998, 17, 32.
29. (a) Albrecht, M.; Spek, A. L.; van Koten, G. J. Am. Chem. Soc. 2001, 123, 7233.
30. (b) Kuyper, J. Inorg. Chem. 1978, 17, 77.
31. (a) Clark, H. C.; Manzer, L. E. Inorg. Chem. 1974, 13, 1291.
32. (b) Appleton, T. G.; Chisholm, M. H.; Clark, H. C.; Manzer, L. E. Inorg. Chem. 1972, 11, 1786.
33. (c) Clark, H. C.; Manzer, L. E. Inorg. Chem. 1972, 11, 2749.
34. (d) Scott, J. D.; Puddephatt, R. J. Organometallics 1986, 5, 2622.
35. Cassani, M. C.; Gun'ko, Y. K.; Hitchcock, P. B.; Lappert, M. F. Chem. Commun. 1996, 1987.
36. (a) Che, C. M.; W. Mak, T. C.; Gray, H. B. Inorg. Chem. 1984, 23, 4386.
37. (b) Che, C. M.; Lee, W. M.; Cho, K. C.; Harvey, P. D.; Gray, H. B. J. Phys. Chem. 1989, 93, 3095.
38. (c) Roundhill, D. M.; Gray, H. B.; Che, C. M. Acc. Chem. Res. 1989, 22, 55, and references therein.
39. (a) Monaghan, P. K.; Puddephatt, R. J. Organometallics 1983, 2, 1689.
40. (b) Hill, R. H.; Puddephatt, R. J. J. Am. Chem. Soc. 1985, 107, 1218.
41. (c) Sandrini, D.; Maestri, M.; Balzani, V.; Chassot, L.; von Zelewsky, A. J. Am. Chem. Soc. 1987, 109, 7720.