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1842348362
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note
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In addition to frequency, the strain amplitude, temperature, and thermal history can all modify the selection of alignment in certain regimes (27, 30, 31). The rate and even the direction of alignment are influenced by the amplitude of the oscillatory shear (27, 30); temperature enters primarily through its effect on the relaxation dynamics of the chains (24, 28), and annealing can alter alignment behavior at very low frequencies (33, 31).
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68
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1842273422
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note
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g,PS-rich + 20°C) (31).
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71
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1842346411
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note
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d). This regime has been studied by rheo-optical techniques in PEP-PEE-2, but this system is not amenable to TEM. In PS-PI, this regime is not accessible without a prolonged annealing treatment (33), which is beyond the scope of the present study.
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72
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1842362082
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note
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13 has been noted (28).
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73
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1842356238
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note
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This research was carried out with the support of NSF (grant CTS 9421015), the Air Force Office of Scientific Research (Liquid Crystals MURI), Chevron, and Raychem.
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