A magnetic route to measure the average oxidation state of mixed-valent manganese in manganese oxide octahedral molecular sieves (OMS)

Journal of the American Chemical Society

Volumn 127, Issue 17, 2005, Pages 6166-6167

  Shen, Xiong Fei ^a   Ding, Yun Shuang ^a   Liu, Jia ^a   Han, Zhao Hui ^a   Budnick, Joseph I ^a   Hines, William A ^a   Suib, Steven L ^a  

^a UNIVERSITY OF CONNECTICUT   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MANGANESE; MANGANESE OXIDE; POTASSIUM MANGANESE DIOXIDE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; MAGNETISM; MATHEMATICAL ANALYSIS; OXIDATION; POROSITY; REACTION ANALYSIS; TITRIMETRY; X RAY DIFFRACTION;

EID: 18344395549     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja043406a     Document Type: Article

References (28)

1. (a) Bish, D. L.; Post, J. E. Am. Mineral. 1989, 74, 177.
2. (b) Shen, Y. F.; Zerger, R. P.; DeGuzman, R. N.; Suib, S. L.; Macurdy, L.; Potter, D. I.; O'Young, C. L. Science 1993, 260, 511.
3. (c) Tian, Z. R.; Tong, W.; Wang, J. Y.; Duan, N. G.; Krishnan, V. V.; Suib, S. L. Science 1997, 276, 926.
4. (d) Yin, M.; O'Brien, S. J. Am. Chem. Soc. 2003, 125, 10180.
5. (e) Ma, R.; Bando, Y.; Zhang, L.; Sasaki, T. Adv. Mater. 2004, 16, 918.
6. (f) Giraldo, O.; Brock, S. L.; Marquez, M.; Suib, S. L.; Hillhouse, H.; Tspatsis, M. Nature 2000, 405, 38.
7. (a) Kim, J.; Manthiram, A. Nature 1997, 390, 165.
8. (b) Geisselmann, A.; Klufers, P.; Pilawa, B. Angew. Chem., Int. Ed. 1998, 47, 1119.
9. (c) Omomo, Y.; Sasak, T.; Wang, L. Z.; Watanabe, M. J. Am. Chem. Soc. 2003, 125, 3568.
10. (a) Schlottmann, P. Phys. Rev. B 2000, 62, 439.
11. (b) Shankar, K. S.; Kar, S.; Raychaudhuri, A. K.; Subbanna, G. N. Appl. Phys. Lett. 2004, 84, 993.
12. (a) Ohno, H. J. Magn. Magn. Mater. 2002, 242-245, 105.
13. (b) Sharma, P.; Gupta, A.; Rao, K. V.; Owens, F. J.; Sharma, R.; Ahuja, R.; Guillen, J. M. O.; Johansson, B.; Gehring, G. A. Nat. Mater. 2003, 2, 673.
14. (a) Murray, J. Y.; Balistieri, L. S.; Paul, B. Geochim. Cosmochim. Acta 1984, 48, 1237.
15. (b) Xia, G. G.; Tong, W.; Tolentino, E. N.; Duan, N. G.; Brock. S. L.; Wang, J. Y.; Suib, S. L. Chem. Mater. 2001, 13, 1585.
16. Liu, J.; Son, Y.-C.; Cai, J.; Shen, X.-F.; Suib, S. L.; Aindow, M. Chem. Mater. 2004, 16, 276.
17. (a) Peng, J. L.; Klavins, P.; Shelton, R. N.; Radousky, H. B.; Hahn, P. A.; Bernardez, L.; Costantino, M. Phys. Rev. B. 1989, 39, 9074.
18. (b) Williams, D. S.; Shand, P. M.; Pekarek, T. M.; Skomski, R.; Petkov, V.; Leslie-Pelecky, D. L. Phys. Rev. B. 2003, 68, 214404.
19. (c) Selwood, P. W. Magnetochemistry; Interscience: New York, 1956; p 78.
20. Sato, H.; Enoki, T. Phys. Rev. B 1999, 59, 12836.
21. (a) Mori, S.; Chen, C.-H.; Cheong, S.-W. Nature 1998, 392, 473.
22. (b) Rodriguez-Martinez, L. M.; Attfield, J. P. Phys. Rev. B 1998, 58, 2426.
23. (a) Reinen, D.; Kesper, U.; Beider, D. J. Solid State Chem. 1995, 116, 355.
24. (b) Kumar, P. S. A.; Joy, P. A.; Pate, S. K. J. Phys. B 1998, 10, L269.
25. (c) Zheng, R.-K.; Zhu, C-F.; Cie, J.-Q.; Li, X.-G. Phys. Rev. B 2001, 63, 024427.
26. Titrations were carefully repeated five times.
27. (a) Solid State Chemistry: Synthesis; Wold, A., Dwight, K., Eds.; Springer: London, 1993; pp 27-53.
28. (b) Bai, C. S.; Soled, S.; Kershaw, R.; Dwight, K.; Wold, A. J. Solid State Chem. 1992, 100, 307.