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3 of solvent was added to a weighed amount of gelator in a septum-capped test tube (ca. 4 cm length and 0.7 cm diameter) in order to obtain the desired concentration. The mixture was warmed to the boiling point until the solid dissolved, and then the mixture was allowed to cool to room temperature. When a gel was formed (generally within several minutes), the sample did not flow when the test tube was inverted.
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0036274287
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A "supergelator" is considered to have a cc ≈ 0.3-2.5 mM at rt according to Shinkai (Gronwald, O.; Snip, E.; Shinkai, S. Curr. Opin. Colloid Int. Sci. 2002, 7, 148-156) and Menger (Menger, F. M.; Caran, K. L. J. Am. Chem. Soc. 2000, 122, 11679-11691).
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Gronwald, O.1
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0034731020
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A "supergelator" is considered to have a cc ≈ 0.3-2.5 mM at rt according to Shinkai (Gronwald, O.; Snip, E.; Shinkai, S. Curr. Opin. Colloid Int. Sci. 2002, 7, 148-156) and Menger (Menger, F. M.; Caran, K. L. J. Am. Chem. Soc. 2000, 122, 11679-11691).
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Menger, F.M.1
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18244362935
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note
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0001011847
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Hypochromic effects have been also observed in gels by others: (a) Kobayashi, H.; Friggeri, A.; Koumoto, K.; Amaikee, M.; Shinkai, S. Org. Lett. 2002, 4, 1423-1426. (b) Tamaru, S.; Nakamura, M.; Takeuchi, M.; Shinkai, S. Org. Lett. 2001, 3, 3631-3634. (c) Tamaru, S.; Uchino, S.; Takeuchi, M.; Ideker, M.; Hatano, T.; Shinkai, S. Tetrahedron Lett. 2002, 43, 3751-3755.
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Shinkai, S.5
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0000310793
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Hypochromic effects have been also observed in gels by others: (a) Kobayashi, H.; Friggeri, A.; Koumoto, K.; Amaikee, M.; Shinkai, S. Org. Lett. 2002, 4, 1423-1426. (b) Tamaru, S.; Nakamura, M.; Takeuchi, M.; Shinkai, S. Org. Lett. 2001, 3, 3631-3634. (c) Tamaru, S.; Uchino, S.; Takeuchi, M.; Ideker, M.; Hatano, T.; Shinkai, S. Tetrahedron Lett. 2002, 43, 3751-3755.
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