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One can show based on dimensional arguments that the system of counterions at a charged wall has only two independent length scales (e.g. the Bjerrum length and the Gouy-Chapman length) and only one independent dimensionless parameter.
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17844366974
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A more accurate estimate of the typical distance between counterions at low couplings (Ξ ≪ 1), a, gives a / μ ∼ Ξ 1 / 3 taking into account the 3D structure of the counterionic layer.
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17844405719
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note
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Note that γ RB may be related to the coupling parameter as γ RB = Ξ / (ξ Δ Δ̃), where Δ Δ̃ = Δ / μ.
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