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The deposition of metals on suitable substrates can, via pseudomorphism [17], enlarge the in-plane lattice constant of the film. This does not lead, however, to an enlarged atomic volume, because in the direction perpendicular to the surface, the film relaxes, reducing its out-of-plane lattice constant in such a way, that the atomic volume is preserved (equal to that of the natural phase)
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Pseudomorphic growth [17] is a convenient route to growing films in a crystal phase modification. The so called fcc(100) and bcc(100) structures are stabilised via pseudomorphic growth [17], where the lateral periodicity of the film is the same as that of the (100)-oriented metallic substrate surface. Due to the conservation of the atomic volume the film relaxes its out-of-plane interatomic distances by tetragonal deformation, forming a bct(100)- or a fct(100)-oriented film
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