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Volumn 132, Issue 2, 2004, Pages 97-102

Quantum well states of d3z2-r2 and dxz,yz orbital character in Pd nanofilms

Author keywords

A: Quantum wells; A: Thin films; D: Quantum localisation; E: Photoelectron spectroscopy

Indexed keywords

LIQUID NITROGEN; ORBITAL STRUCTURES; QUANTUM LOCALIZATION;

EID: 4344649590     PISSN: 00381098     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ssc.2004.07.024     Document Type: Article
Times cited : (5)

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    • note
    • A film-structure is called pseudomorphic (ps) when its lateral atomic arrangement is identical with that of the substrate surface. The deposition of metals on suitable substrates can, via pseudomorphism [59], enlarge the in-plane lattice constant of the film. This is the case for Pd de-posited on Nb(100), where the ps-Pd films are strongly stretched in-plane in comparison to the (100) plane of the natural fcc lattice of bulk Pd. This does not lead, however, to an enlarged atomic volume, because in the direction perpendicular to the surface, the film relaxes, reducing its out-of-plane lattice constant in such a way, that the atomic volume is preserved (equal to that of the natural phase). The compression of the out-of plane lattice induces a (100)-oriented body centred tetragonal structure in the ps Pd films on Nb(100).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.