Asymmetric hydrogenation of isobutyrophenone using a [(diphosphine) RuCl2 (1,4-diamine)] catalyst

Organic Letters

Volumn 7, Issue 8, 2005, Pages 1449-1451

  Grasa, Gabriela A ^a   Zanotti Gerosa, Antonio ^a   Medlock, Jonathan A ^a   Hems, William P ^a  

^a JOHNSON MATTHEY TECHNOLOGY CENTRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACETOPHENONE; BUTYROPHENONE; CHLORIDE; DIAMINE; PHOSPHINE; PHOSPHINE DERIVATIVE; RUTHENIUM;

ARTICLE; CATALYST; CHIRALITY; ENANTIOMER; HYDROGENATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 17844390991     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol047355y     Document Type: Article

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21. See Supporting Information for a full table of results.
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25. For an example of a conformationally flexible phosphine and chiral diamine, see: Mikami, K.; Korrenaga, T.; Terada, M.; Ohkuma, T.; Pham, T.; Noyori, R. Angew. Chem., Int. Ed. 1999, 38, 495. Mikami, K., Matsukawa, S. Nature 1997, 285, 613. Aikawa, K.; Mikami, K. Angew Chem., Int. Ed. 2003, 42, 5455. Mikami, K.; Korenaga, T.; Yusu, Y.; Yamanaka, M. Adv. Synth. Catal. 2003, 345, 246.
26. For an example of a conformationally flexible phosphine and chiral diamine, see: Mikami, K.; Korrenaga, T.; Terada, M.; Ohkuma, T.; Pham, T.; Noyori, R. Angew. Chem., Int. Ed. 1999, 38, 495. Mikami, K., Matsukawa, S. Nature 1997, 285, 613. Aikawa, K.; Mikami, K. Angew Chem., Int. Ed. 2003, 42, 5455. Mikami, K.; Korenaga, T.; Yusu, Y.; Yamanaka, M. Adv. Synth. Catal. 2003, 345, 246.
27. See Supporting Information for a full table of the hydrogenation of cyclic aromatic ketones such as tetralone.