Asymmetric Activation/Deactivation of Racemic Ru Catalysts for Highly Enantioselective Hydrogenation Irrespective of Ketonic Substrates: Molecular Design of Dimethylbinaphthylamine for Enantiomeric Catalysts Discrimination

Advanced Synthesis and Catalysis

Volumn 345, Issue 1-2, 2003, Pages 246-254

  Mikami, Koichi ^a   Korenaga, Toshinobu ^a   Yusa, Yukinori ^a   Yamanaka, Masahiro ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

3,3 dimethyl 2, 2 diamino 1,1 binaphthyl; Asymmetric activation; Asymmetric deactivation; Hydrogenation; Ruthenium(II) complex

Indexed keywords

1,2 DIPHENYLETHYLENEDIAMINE; 3,3' DIMETHYL 2,2' DIAMINO 1,1' BINAPHTHYL; AMINE; DIAMINE; DIMETHYLBINAPHTHYLAMINE; ETHYLENE DERIVATIVE; KETONE; NAPHTHYL GROUP; NITROGEN; RUTHENIUM; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL ANALYSIS; CHIRALITY; DENSITY; ELECTRON; ENANTIOMER; ENANTIOSELECTIVITY; HYDROGENATION; MOLECULE;

EID: 0042750541     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200390019     Document Type: Article

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