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Reaction of 11 under the reaction conditions (1.5 equiv of TBAF, THF, reflux) in the absence of any aldehyde gave nearly quantitative conversion to 3-methyl-4-nitrobenzoic acid.
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Unidentified reaction byproducts, most likely arrising from deprotonation of the methyl sulfone, account for the mass balance.
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65
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17744370901
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17744381930
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note
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Significant amounts of starting materials, in addition to some decomposition, account for the mass balance.
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