Heterobimetallic systems containing organometallic and classical coordination sites: Effects of subtle changes in the Werner-type site

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2005, Pages 1293-1302

  Sheng, Tianlu ^a   Dechert, Sebastian ^a   Stückl, A Claudia ^a   Meyer, Franc ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Bridging ligands; Cyclopentadienyl ligands; Heterometallic complexes; Manganese; N ligands; Zinc

Indexed keywords

ELECTRON SPIN RESONANCE SPECTROSCOPY; LIGANDS; MANGANESE; MANGANESE COMPOUNDS; REDOX REACTIONS; SCAFFOLDS; X RAY CRYSTALLOGRAPHY; ZINC COMPOUNDS;

BRIDGING LIGANDS; COORDINATION SITES; CYCLOPENTADIENYL LIGANDS; HETEROBIMETALLIC SYSTEMS; HETEROMETALLIC COMPLEXES; N LIGANDS; N-LIGANDS; SITE EFFECTS; ZINC; ZN COMPLEX;

ORGANOMETALLICS;

AMINE; CHELATE; COORDINATION COMPOUND; LIGAND; MANGANESE DERIVATIVE; METAL COMPLEX; ORGANOMETALLIC COMPOUND; PYRAZOLE DERIVATIVE; ZINC COMPLEX;

ARTICLE; BINDING SITE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; INFRARED SPECTROSCOPY; OXIDATION; OXIDATION REDUCTION POTENTIAL; X RAY CRYSTALLOGRAPHY;

EID: 17644368934     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400718     Document Type: Article

References (56)

1. a) J. Okuda, Comments Inorg. Chem. 1994, 16, 185-205;
2. b) C. Müller, D. Vos, P. Jutzi, J. Organomet. Chem. 2000, 600, 127-143;
3. c) P. Jutzi, J. Dahlhaus, Coord. Chem. Rev. 1994, 137, 179-199.
4. a) I. L. Fedushkin, S. Dechert, H. Schumann, Organometallics 2000, 19, 4066-4076;
5. b) L. F. Groux, F. Bélanger-Gariépy, D. Zargarian, R. Vollmerhaus, Organometallics 2000, 19, 1507-1513;
6. c) O. Segnitz, M. Winter, K. Merz, R. A. Fischer, Eur. J. Inorg. Chem. 2000, 2077-2085;
7. d) A. I. Philippopoulos, B. Donnadieu, R. Poilblanc, N. Hadjiliadis, J. Organomet. Chem. 1999, 582, 286-291;
8. e) H. Schumann, E. C. Rosenthal, J. Demtschuk, G. A. Molander, Organometallics 1998, 17, 5324-5333;
9. f) P. T. Gomes, M. L. H. Green, A. M. Martins, J. Organomet. Chem. 1998, 551, 133-138;
10. g) P. Foster, J. C. W. Chien, M. D. Rausch, J. Organomet. Chem. 1997, 545-546, 35-38;
11. h) Z. Ziniuk, I. Goldberg, M. Kol, J. Organomet. Chem. 1997, 545-546, 441-446;
12. i) P.-J. Sinnema, L. van der Veen, A. L. Spek, N. Veldman, J. H. Teuben, Organometallics 1997, 16, 4245-4247;
13. j) A. K. Hughes, J. A. Kingsley, J. Chem. Soc., Dalton Trans. 1997, 4139-4142;
14. k) M. Enders, R. Rudolph, H. Pritzkow, Chem. Ber. 1996, 129, 459-463;
15. l) W. A. Herrmann, M. J. A. Morawietz, T. Priermeier, K. J. Mashima, J. Organomet. Chem. 1995, 486, 291-295.
16. a) U. Siemeling, P. Jutzi, J. Organomet. Chem. 1995, 500, 175-185;
17. b) P. Jutzi, T. Redeker, Eur. J. Inorg. Chem. 1998, 663-674.
18. a) P. J. Shapiro, E. Bunel, W. P. Schaefer, J. E. Bercaw, Organometallics 1990, 9, 867-869;
19. b) A. L. McKnight, R. M. Waymouth, Chem. Rev. 1998, 98, 2587-2598 and references cited therein;
20. c) R. Emrich, O. Heinemann, P. W. Jolly, C. Krüger, G. P. J. Verhovnik, Organometallics 1997, 16, 1511-1513;
21. d) M. S. Blais, J. C. W. Chien, M. D. Rausch, Organometallics 1998, 17, 3775-3783;
22. e) K. C. Hultzsch, T. P. Spaniol, J. Okuda, Angew. Chem. 1999, 111, 163-165; Angew. Chem. Int. Ed. 1999, 38, 227-230;
23. e) K. C. Hultzsch, T. P. Spaniol, J. Okuda, Angew. Chem. 1999, 111, 163-165; Angew. Chem. Int. Ed. 1999, 38, 227-230;
24. f) P. T. Witte, A. Meetsma, B. Hessen, Organometallics 1999, 18, 2944-2946.
25. J. C. Röder, F. Meyer, H. Pritzkow, Organometallics 2001, 20, 811-817.
26. a) J. C. Röder, F. Meyer, E. Kaifer, Angew. Chem. 2002, 114, 2414-2417; Angew. Chem. Int. Ed. 2002, 41, 2304-2306;
27. a) J. C. Röder, F. Meyer, E. Kaifer, Angew. Chem. 2002, 114, 2414-2417; Angew. Chem. Int. Ed. 2002, 41, 2304-2306;
28. b) J. C. Röder, F. Meyer, I. Hyla-Kryspin, R. F. Winter, E. Kaifer, Chem. Eur. J. 2003, 9, 2636-2648.
29. J. C. Röder, F. Meyer, R. F. Winter, E. Kaifer, J. Organomet. Chem. 2002, 641, 113-120.
30. a) C. J. Qin, A. L. Gavrilova, B. Bosnich, Pure Appl. Chem. 2001, 73, 221-226;
31. b) A. L. Gavrilova, B. Bosnich, Inorg. Chim. Acta 2003, 352, 24-30.
32. K. G. Caulton, Coord. Chem. Rev. 1981, 38, 1-43.
33. W. Kaim, R. Gross, Comments Inorg. Chem. 1988, 7, 269-285.
34. T. G. Schenck, C. R. C. Milne, J. F. Sawyer, B. Bosnich, Inorg. Chem. 1985, 24, 2338-2344.
35. 3] and its derivatives is well established: a) W. Strohmeier, Angew. Chem. 1964, 76, 873-881; Angew. Chem. Int. Ed. Engl. 1964, 3, 730-738;
36. 3] and its derivatives is well established: a) W. Strohmeier, Angew. Chem. 1964, 76, 873-881; Angew. Chem. Int. Ed. Engl. 1964, 3, 730-738;
37. b) W. Strohmeier, F.-J. Müller, Chem. Ber. 1969, 102, 3608-3612.
38. a) N. C. Mösch-Zanetti, M. Ferbinteanu, J. Magull, Eur. J. Inorg. Chem. 2002, 950-956;
39. b) G. B. Deacon, C. M. Forsyth, A. Gitlits, R. Harika, P. C. Junk, B. W. Skelton, A. H. White, Angew. Chem. 2002, 114, 3383-3385; Angew. Chem. Int. Ed. 2002, 41, 3249-3251;
40. b) G. B. Deacon, C. M. Forsyth, A. Gitlits, R. Harika, P. C. Junk, B. W. Skelton, A. H. White, Angew. Chem. 2002, 114, 3383-3385; Angew. Chem. Int. Ed. 2002, 41, 3249-3251;
41. c) J. Hitzbleck, A. Y. O'Brien, C. M. Forsyth, G. B. Deacon, K. Ruhlandt-Senge, Chem. Eur. J. 2004, 10, 3315-3323.
42. The degree of trigonality can be evaluated by means of the angular structural parameter τ = (β - α)/60, where α and β represent the two largest angles around the central atom with β > α (a perfect TB-5 structure is associated with τ = 1, while τ = 0 is expected for ideal SPY-5 geometry): A. W. Addison, T. N. Rao, J. Reedijk, J. van Rijn, G. C. Verschoor, J. Chem. Soc., Dalton Trans. 1984, 1349-1356.
43. H. Adams, N. A. Bailey, D. A. Fenton, Q.-Y. He, J. Chem. Soc., Dalton Trans. 1997, 1533-1540.
44. G. B. Deacon, R. J. Phillips, Coord. Chem. Rev. 1980, 33, 227-250.
45. X. Xu, C. S. Allen, C.-L. Chuang, J. W. Canary, Acta Crystallogr., Sect. C 1998, 54, 600-601.
46. An unusual side-on π-interaction has been observed for a nitrile moiety within the bimetallic pocket of a pyrazolate-based dinickel(II) complex, with Ni-N and Ni-C distances around 2.9 Å: F. Meyer, I. Hyla-Kryspin, E. Kaifer, P. Kircher, Eur. J. Inorg. Chem. 2000, 771-781.
47. R. Gross, W. Kaim, Angew. Chem. 1985, 97, 869-870; Angew. Chem. Int. Ed. Engl. 1985, 24, 856-858.
48. R. Gross, W. Kaim, Angew. Chem. 1985, 97, 869-870; Angew. Chem. Int. Ed. Engl. 1985, 24, 856-858.
49. I. A. Veselov, V. G. Shtyrlin, V. A. Zakharov, Koord. Khim. (Koordinatsionnaya Khimiya; Russ. J. Coord. Chem.) 1988, 14, 943-947.
50. 55Mn hyperfine tensors: R. D. Pike, A. L. Rieger, P. H. Rieger, J. Chem. Soc., Faraday Trans. 1 1989, 85, 3913-3925.
51. Spartan 02, Wavefunction Inc.: Irvine, CA. The UB3LYP method with the LACVP* basis set was employed. Geometry optimization was started from the coordinates obtained from the X-ray structure of 8. A doublet ground state was applied as the only constraint.
52. N. G. Connelly, W. E. Geiger, Chem. Rev. 1996, 96, 877-910.
53. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, 1997. G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, 1997.
54. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, 1997. G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, 1997.
55. STOE & CIE GmbH, X-RED, Darmstadt, 2002.
56. A. L. Spek, PLATON, A Multipurpose Crystallographic Tool, Utrecht University, 2003.