메뉴 건너뛰기




Volumn 10, Issue 6, 2004, Pages 869-879

Electron-rich radicals by neutralization-reionization mass spectrometry. Generation, dissociations and energetics of the hydrogen atom adduct to acetamide

Author keywords

Acetamide radicals; Excited states; Franck Condon effects; Neutralization reionization mass spectrometry; Protonated acetamide

Indexed keywords

ACETAMIDE; AMMONIA; HYDROGEN; METHYL GROUP; SOLVENT; WATER;

EID: 17544377312     PISSN: 14690667     EISSN: None     Source Type: Journal    
DOI: 10.1255/ejms.680     Document Type: Article
Times cited : (8)

References (57)
  • 1
    • 0001757390 scopus 로고
    • Absolute Rates of Recombination and Disproportionation of Dimethylaminyl Radicals
    • Y.G. Lazarou and P. Papagiannakopoulos, "Absolute Rates of Recombination and Disproportionation of Dimethylaminyl Radicals", J. Phys. Chem. 97, 9133 (1993).
    • (1993) J. Phys. Chem. , vol.97 , pp. 9133
    • Lazarou, Y.G.1    Papagiannakopoulos, P.2
  • 2
    • 0020780782 scopus 로고
    • Heats of Formation and Ionization Potential of Some α-Aminoalkyl Radicals
    • T.J. Burkey, A.L. Castelhano, D. Griller and F.P. Lossing, "Heats of Formation and Ionization Potential of Some α-Aminoalkyl Radicals", J. Am. Chem. Soc. 105, 4701 (1983).
    • (1983) J. Am. Chem. Soc. , vol.105 , pp. 4701
    • Burkey, T.J.1    Castelhano, A.L.2    Griller, D.3    Lossing, F.P.4
  • 3
    • 0042282065 scopus 로고    scopus 로고
    • An Assessment of Theoretical Procedures for the Calculation of Reliable Radical Stabilization Energies
    • C.J. Parkinson, P.M. Mayer and L. Radom, "An Assessment of Theoretical Procedures for the Calculation of Reliable Radical Stabilization Energies", J. Chem. Soc., Perkin Trans. 2 2305 (1999).
    • (1999) J. Chem. Soc., Perkin Trans. , vol.2 , pp. 2305
    • Parkinson, C.J.1    Mayer, P.M.2    Radom, L.3
  • 4
    • 45949121469 scopus 로고
    • Heats of Formation of Some Small Molecules and Radicals
    • M. Sana, G. Leroy, D. Peeters and E. Younang, "Heats of Formation of Some Small Molecules and Radicals", THEOCHEM 36, 325 (1987).
    • (1987) THEOCHEM , vol.36 , pp. 325
    • Sana, M.1    Leroy, G.2    Peeters, D.3    Younang, E.4
  • 5
    • 0002540712 scopus 로고
    • The Enthalpies of Formation of Substituted Methyl Radicals: A Theoretical Contribution
    • G. Leroy, M. Sana and C. Wilante, "The Enthalpies of Formation of Substituted Methyl Radicals: a Theoretical Contribution", THEOCHEM 74, 37 (1991).
    • (1991) THEOCHEM , vol.74 , pp. 37
    • Leroy, G.1    Sana, M.2    Wilante, C.3
  • 7
    • 84982485110 scopus 로고
    • Free Radicals by Mass Spectrometry. XLIV. Ionization Potentials and Bond Dissociation Energies for Chloro- and Fluoromethyl Radicals
    • F.P. Lossing, "Free Radicals by Mass Spectrometry. XLIV. Ionization Potentials and Bond Dissociation Energies for Chloro- and Fluoromethyl Radicals", Bull. Soc. Chim. Belg. 81, 125 (1972).
    • (1972) Bull. Soc. Chim. Belg. , vol.81 , pp. 125
    • Lossing, F.P.1
  • 8
    • 0000364804 scopus 로고
    • Thermochemistry of α-Aminoalkyl Radicals
    • D. Griller and P.P. Lossing, "Thermochemistry of α-Aminoalkyl Radicals", J. Am. Chem. Soc. 103, 1586 (1981).
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 1586
    • Griller, D.1    Lossing, P.P.2
  • 9
    • 0001384114 scopus 로고
    • Heats of Formation of Alkyl Radicals from Appearance Energies
    • J.L. Holmes, P.P. Lossing and A. Maccoll," Heats of Formation of Alkyl Radicals from Appearance Energies", J. Am. Chem. Soc. 110, 7339 (1988).
    • (1988) J. Am. Chem. Soc. , vol.110 , pp. 7339
    • Holmes, J.L.1    Lossing, P.P.2    Maccoll, A.3
  • 10
    • 33845278704 scopus 로고
    • Heats of Formation and Bond Dissociation Energies in Halogen-Substituted Methyl and Ethyl Radicals
    • J.L. Holmes and P.P. Lossing, "Heats of Formation and Bond Dissociation Energies in Halogen-Substituted Methyl and Ethyl Radicals", J. Am. Chem. Soc. 110, 7343 (1988).
    • (1988) J. Am. Chem. Soc. , vol.110 , pp. 7343
    • Holmes, J.L.1    Lossing, P.P.2
  • 11
    • 0000801872 scopus 로고
    • Heats of Formation of Oxygen-Containing Organic Free Radicals from Appearance Energy Measurements
    • J.L. Holmes, P.P. Lossing and P.M. Mayer, "Heats of Formation of Oxygen-Containing Organic Free Radicals from Appearance Energy Measurements", J. Am. Chem. Soc. 113, 9723 (1991).
    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 9723
    • Holmes, J.L.1    Lossing, P.P.2    Mayer, P.M.3
  • 12
    • 0011641204 scopus 로고
    • The Effects of Methyl Substitution on the Structure and Thermochemistry of the Cyanomethyl Radical and Cation
    • J.L. Holmes, F.P. Lossing and P.M. Mayer, "The Effects of Methyl Substitution on the Structure and Thermochemistry of the Cyanomethyl Radical and Cation", Chem. Phys. Lett. 212, 134 (1993).
    • (1993) Chem. Phys. Lett. , vol.212 , pp. 134
    • Holmes, J.L.1    Lossing, F.P.2    Mayer, P.M.3
  • 13
    • 84989111349 scopus 로고
    • Neutralization-reionization Mass Spectrometry: Efficiency of the Charge-Exchange Process
    • C.E.C.A. Hop and J.L. Holmes, "Neutralization-reionization Mass Spectrometry: Efficiency of the Charge-Exchange Process", Org. Mass Spectrom. 26, 476 (1991).
    • (1991) Org. Mass Spectrom. , vol.26 , pp. 476
    • Hop, C.E.C.A.1    Holmes, J.L.2
  • 15
    • 0000292520 scopus 로고    scopus 로고
    • 2 Radicals and Cations following Collisional Electron Transfer. A Variable-Time Neutralization-Reionization and Ab Initio Study
    • 2 Radicals and Cations following Collisional Electron Transfer. A Variable-Time Neutralization-Reionization and Ab Initio Study", J. Phys. Chem. 100, 224 (1996).
    • (1996) J. Phys. Chem. , vol.100 , pp. 224
    • Sadílek, M.1    Tureček, F.2
  • 18
    • 0035857240 scopus 로고    scopus 로고
    • Hydrogen Atom Adducts to the Amide Bond. Generation and Energetics of the Amino(hydroxy)methyl Radical in the Gas Phase
    • E.A. Syrstad and F. Tureček, "Hydrogen Atom Adducts to the Amide Bond. Generation and Energetics of the Amino(hydroxy)methyl Radical in the Gas Phase", J. Phys. Chem. A 105, 11144 (2001).
    • (2001) J. Phys. Chem. A , vol.105 , pp. 11144
    • Syrstad, E.A.1    Tureček, F.2
  • 19
    • 0037142724 scopus 로고    scopus 로고
    • Protonated Carbonic Acid and the Trihydroxymethyl Radical in the Gas Phase. A Neutralization-Reionization Mass Spectrometric and Ab Initio/RRKM Study"
    • P. Gerbaux and F. Tureček, "Protonated Carbonic Acid and the Trihydroxymethyl Radical in the Gas Phase. A Neutralization-Reionization Mass Spectrometric and Ab Initio/RRKM Study", J. Phys. Chem. A 106, 5938 (2002).
    • (2002) J. Phys. Chem. A , vol.106 , pp. 5938
    • Gerbaux, P.1    Tureček, F.2
  • 20
    • 0037426870 scopus 로고    scopus 로고
    • Hydrogen Atom Adducts to the Amide Bond. Generation and Energetics of Amide Radicals in the Gas Phase
    • E.A. Syrstad, D.D. Stephens and F. Tureček, "Hydrogen Atom Adducts to the Amide Bond. Generation and Energetics of Amide Radicals in the Gas Phase", J. Phys. Chem. A 107, 115 (2003).
    • (2003) J. Phys. Chem. A , vol.107 , pp. 115
    • Syrstad, E.A.1    Stephens, D.D.2    Tureček, F.3
  • 21
    • 0038756506 scopus 로고    scopus 로고
    • Mechanism and Energetics of Intramolecular Hydrogen Transfer Atom Transfer in Amide and Peptide Radicals and Cation-Radicals
    • F. Tureček and E.A. Syrstad, "Mechanism and Energetics of Intramolecular Hydrogen Transfer Atom Transfer in Amide and Peptide Radicals and Cation-Radicals", J. Am. Chem. Soc. 125, 3353 (2003).
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 3353
    • Tureček, F.1    Syrstad, E.A.2
  • 22
    • 0038634619 scopus 로고    scopus 로고
    • N-Cα Bond Dissociation Energies and Kinetics in Amide and Peptide Radicals. Is the Dissociation a Non-Ergodic Process?
    • F. Tureček, "N-Cα Bond Dissociation Energies and Kinetics in Amide and Peptide Radicals. Is the Dissociation a Non-Ergodic Process?", J. Am. Chem. Soc. 125, 5954 (2003).
    • (2003) J. Am. Chem. Soc. , vol.125 , pp. 5954
    • Tureček, F.1
  • 23
    • 0003734582 scopus 로고
    • Hydrogen Abstraction Reactions by Amide Electron Adducts
    • M.D. Sevilla, C.L. Sevilla and S. Swarts, "Hydrogen Abstraction Reactions by Amide Electron Adducts", Rad. Phys. Chem. 20, 141 (1982).
    • (1982) Rad. Phys. Chem. , vol.20 , pp. 141
    • Sevilla, M.D.1    Sevilla, C.L.2    Swarts, S.3
  • 24
    • 0029845464 scopus 로고    scopus 로고
    • Protonation Sites in Gaseous Pyrrole and Imidazole and the Stabilities of Their Radicals
    • V.Q. Nguyen and F. Tureček, "Protonation Sites in Gaseous Pyrrole and Imidazole and the Stabilities of Their Radicals", J. Mass Spectrom. 31, 1173 (1996).
    • (1996) J. Mass Spectrom. , vol.31 , pp. 1173
    • Nguyen, V.Q.1    Tureček, F.2
  • 25
    • 12044257029 scopus 로고
    • The Dimethylaminomethyl Radical. A Neutralization-Reionization and Ab Initio Study
    • S.A. Shaffer, F. Tureček and R.L. Cerny, "The Dimethylaminomethyl Radical. A Neutralization-Reionization and Ab Initio Study", J. Am. Chem. Soc. 115, 12117 (1993).
    • (1993) J. Am. Chem. Soc. , vol.115 , pp. 12117
    • Shaffer, S.A.1    Tureček, F.2    Cerny, R.L.3
  • 26
    • 0007754523 scopus 로고
    • An Experimental Study of the Energetics of Fragmentation of Triatomic Hydrogen
    • P.M. Curtis, B.W. Williams and R.F. Porter, "An Experimental Study of the Energetics of Fragmentation of Triatomic Hydrogen", Chem. Phys. Lett. 65, 296 (1979).
    • (1979) Chem. Phys. Lett. , vol.65 , pp. 296
    • Curtis, P.M.1    Williams, B.W.2    Porter, R.F.3
  • 28
    • 0001890346 scopus 로고
    • Neutral Products of Ion Fragmentations: Hydrogen Cyanide and Hydrogen Isocyanide (HNC) Identified by Collisionally Induced Dissociative Ionization
    • P.C. Burgers, J.L. Holmes, A.A. Mommers and J.K. Terlouw, "Neutral Products of Ion Fragmentations: Hydrogen Cyanide and Hydrogen Isocyanide (HNC) Identified by Collisionally Induced Dissociative Ionization", Chem. Phys. Lett. 102, 1 (1983).
    • (1983) Chem. Phys. Lett. , vol.102 , pp. 1
    • Burgers, P.C.1    Holmes, J.L.2    Mommers, A.A.3    Terlouw, J.K.4
  • 29
    • 1442294187 scopus 로고    scopus 로고
    • Transient Intermediates of Chemical Reactions by Neutralization- Reionization Mass Spectrometry
    • F. Tureček, "Transient Intermediates of Chemical Reactions by Neutralization-Reionization Mass Spectrometry", Top. Curr. Chem. 225, 77 (2003).
    • (2003) Top. Curr. Chem. , vol.225 , pp. 77
    • Tureček, F.1
  • 30
    • 0002165113 scopus 로고    scopus 로고
    • NeutralizationReionization Mass Spectrometry Applied to Organometallic and Coordination Chemistry (update: 1994-1998)
    • D.V. Zagorevskii and J.L. Holmes, "NeutralizationReionization Mass Spectrometry Applied to Organometallic and Coordination Chemistry (update: 1994-1998)", Mass Spectrom. Rev. 18, 87 (1999).
    • (1999) Mass Spectrom. Rev. , vol.18 , pp. 87
    • Zagorevskii, D.V.1    Holmes, J.L.2
  • 31
    • 0032371428 scopus 로고    scopus 로고
    • Mass Spectrometric Approaches to the Reactivity of Transient Neutrals
    • C.A. Schalley, G. Hornung, D. Schroder and H. Schwarz, "Mass Spectrometric Approaches to the Reactivity of Transient Neutrals", Chem. Soc. Rev. 27, 91 (1998).
    • (1998) Chem. Soc. Rev. , vol.27 , pp. 91
    • Schalley, C.A.1    Hornung, G.2    Schroder, D.3    Schwarz, H.4
  • 32
    • 0001525693 scopus 로고
    • A Novel Tandem Quadrupole Acceleration Deceleration Mass Spectrometer for Neutralization-Reionization Studies
    • F. Tureček, M. Gu and S.A. Shaffer, "A Novel Tandem Quadrupole Acceleration Deceleration Mass Spectrometer for Neutralization- Reionization Studies", J. Am. Soc. Mass Spectrom. 3, 493 (1992).
    • (1992) J. Am. Soc. Mass Spectrom. , vol.3 , pp. 493
    • Tureček, F.1    Gu, M.2    Shaffer, S.A.3
  • 33
    • 84989093057 scopus 로고
    • The Modern Mass Spectrometer. A Laboratory for Unstable Neutral Species
    • F. Tureček, "The Modern Mass Spectrometer. A Laboratory for Unstable Neutral Species", Org. Mass Spectrom. 27, 1087 (1992).
    • (1992) Org. Mass Spectrom. , vol.27 , pp. 1087
    • Tureček, F.1
  • 35
    • 34250817103 scopus 로고
    • A New Mixing of Hartree-Fock and Local Density Functional Theories
    • A.D. Becke, "A New Mixing of Hartree-Fock and Local Density Functional Theories", J. Chem. Phys. 98, 1372 (1993).
    • (1993) J. Chem. Phys. , vol.98 , pp. 1372
    • Becke, A.D.1
  • 36
    • 33751157732 scopus 로고
    • Ab Initio Calculations of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields
    • P.J. Stephens, F.J. Devlin, C.F. Chabalowski and M.J. Frisch, "Ab Initio Calculations of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields", J. Phys. Chem. 98, 11623 (1994).
    • (1994) J. Phys. Chem. , vol.98 , pp. 11623
    • Stephens, P.J.1    Devlin, F.J.2    Chabalowski, C.F.3    Frisch, M.J.4
  • 37
    • 0011627934 scopus 로고
    • Potential Energy Curves Using Unrestricted Moller-Plesset Perturbation Theory with Spin Annihilation
    • H.B. Schlegel, "Potential Energy Curves Using Unrestricted Moller-Plesset Perturbation Theory with Spin Annihilation", J. Chem. Phys. 84, 4530 (1986).
    • (1986) J. Chem. Phys. , vol.84 , pp. 4530
    • Schlegel, H.B.1
  • 38
    • 36449002507 scopus 로고
    • Gaussian-2 Theory Using Reduced Moeller-Plesset Orders
    • L.A. Curtiss, K. Raghavachari and J.A. Pople, "Gaussian-2 Theory Using Reduced Moeller-Plesset Orders", J. Chem. Phys. 98, 1293 (1993).
    • (1993) J. Chem. Phys. , vol.98 , pp. 1293
    • Curtiss, L.A.1    Raghavachari, K.2    Pople, J.A.3
  • 39
    • 0032533083 scopus 로고    scopus 로고
    • An Efficient Implementation of Time-Dependent Density-Functional Theory for the Calculation of Excitation Energies of Large Molecules
    • R.E. Stratmann, G.E. Scuseria and M.J. Frisch, "An Efficient Implementation of Time-Dependent Density-Functional Theory for the Calculation of Excitation Energies of Large Molecules," J. Chem. Phys. 109, 8218 (1998).
    • (1998) J. Chem. Phys. , vol.109 , pp. 8218
    • Stratmann, R.E.1    Scuseria, G.E.2    Frisch, M.J.3
  • 40
    • 84961986752 scopus 로고    scopus 로고
    • New Developments in the Polarizable Continuum Model for Quantum Mechanical and Classical Calculations on Molecules in Solution
    • M. Cossi, G. Scalmani, N. Rega and V. Barone, "New Developments in the Polarizable Continuum Model for Quantum Mechanical and Classical Calculations on Molecules in Solution", J. Chem. Phys. 117, 43 (2002).
    • (2002) J. Chem. Phys. , vol.117 , pp. 43
    • Cossi, M.1    Scalmani, G.2    Rega, N.3    Barone, V.4
  • 42
    • 2642589025 scopus 로고    scopus 로고
    • Sulfur Oxyacids and Radicals in the Gas Phase. A Variable-Time Neutralization-Photoexcitation-Reionization Mass Spectrometric and Ab Initio/RRKM Study
    • A.J. Frank, M. Sadílek, J.G. Ferrier and F. Tureček, "Sulfur Oxyacids and Radicals in the Gas Phase. A Variable-Time Neutralization-Photoexcitation-Reionization Mass Spectrometric and Ab Initio/RRKM Study", J. Am. Chem. Soc. 119, 12343 (1997).
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 12343
    • Frank, A.J.1    Sadílek, M.2    Ferrier, J.G.3    Tureček, F.4
  • 45
    • 0007468066 scopus 로고
    • Gas-Phase Basicities of Amines. Hydrogen Bonding in Proton-Bound Amine Dimers and Proton-INduced Cyclization of α,ω-Diamines
    • R. Yamdagni and P. Kebarle, "Gas-Phase Basicities of Amines. Hydrogen Bonding in Proton-Bound Amine Dimers and Proton-INduced Cyclization of α,ω-Diamines", J. Am. Chem. Soc. 95, 3504 (1973).
    • (1973) J. Am. Chem. Soc. , vol.95 , pp. 3504
    • Yamdagni, R.1    Kebarle, P.2
  • 46
    • 3042691488 scopus 로고    scopus 로고
    • Heat of Formation of the Acetyl Radicals and Ion Obtained by Threshold Photoelectron Phototion Coincidence
    • E.A. Fogleman, H. Koizumi, J.P. Kercher, B. Sztaray and T. Baer, "Heat of Formation of the Acetyl Radicals and Ion Obtained by Threshold Photoelectron Phototion Coincidence", J. Phys. Chem. A 108, 5288 (2004).
    • (2004) J. Phys. Chem. A , vol.108 , pp. 5288
    • Fogleman, E.A.1    Koizumi, H.2    Kercher, J.P.3    Sztaray, B.4    Baer, T.5
  • 47
    • 2442694147 scopus 로고    scopus 로고
    • Direct Observation of the Forbidden Hydrogen Atom Adduct to Acetonitrile. A Neutralization-Reionization Mass Spectrometric and CCSD(T) ab initio/RRKM Study
    • X. Chen, E.A. Syrstad and F. Tureček, "Direct Observation of the Forbidden Hydrogen Atom Adduct to Acetonitrile. A Neutralization- Reionization Mass Spectrometric and CCSD(T) ab initio/RRKM Study", J. Phys. Chem. A 108, 4163 (2004).
    • (2004) J. Phys. Chem. A , vol.108 , pp. 4163
    • Chen, X.1    Syrstad, E.A.2    Tureček, F.3
  • 51
    • 84989040513 scopus 로고
    • Competition in the Formation of Ion-neutral Complexes. Expulsion of Methane from the Molecular Ion of Acetamide
    • T.H. Morton, "Competition in the Formation of Ion-neutral Complexes. Expulsion of Methane from the Molecular Ion of Acetamide", Org. Mass Spectrom. 26, 18 (1991).
    • (1991) Org. Mass Spectrom. , vol.26 , pp. 18
    • Morton, T.H.1
  • 52
    • 0038517896 scopus 로고    scopus 로고
    • The Use of Kinetic Isotope Effects for the Determination of Internal Energy Distributions of Isolated Transient Species in the Gas Phase
    • F. Tureček, "The Use of Kinetic Isotope Effects for the Determination of Internal Energy Distributions of Isolated Transient Species in the Gas Phase", Int. J. Mass Spectrom. 227, 327 (2003).
    • (2003) Int. J. Mass Spectrom. , vol.227 , pp. 327
    • Tureček, F.1
  • 53
    • 0000087750 scopus 로고
    • Infrared Radiative Cooling of Isolated Polyatomic Molecules
    • R.C. Dunbar, "Infrared Radiative Cooling of Isolated Polyatomic Molecules", J. Chem. Phys. 90, 7369 (1989).
    • (1989) J. Chem. Phys. , vol.90 , pp. 7369
    • Dunbar, R.C.1
  • 54
    • 0000242779 scopus 로고
    • Franck-Condon Dominated Chemistry. Dissociations of Dimethyl(hydroxy) silyl Radicals Prepared by Femtosecond Reduction of Their Cations in the Gas Phase
    • V.Q. Nguyen, S.A. Shaffer, F. Tureček and C.E.C.A. Hop, "Franck-Condon Dominated Chemistry. Dissociations of Dimethyl(hydroxy)silyl Radicals Prepared by Femtosecond Reduction of Their Cations in the Gas Phase", J. Phys. Chem. 99, 15454 (1995).
    • (1995) J. Phys. Chem. , vol.99 , pp. 15454
    • Nguyen, V.Q.1    Shaffer, S.A.2    Tureček, F.3    Hop, C.E.C.A.4
  • 55
    • 0030572353 scopus 로고    scopus 로고
    • Probing Hypervalent Radicals by Neutralization-Laser Photoionization Mass Spectrometry
    • M. Sadílek and F. Tureček, "Probing Hypervalent Radicals by Neutralization-Laser Photoionization Mass Spectrometry", J. Phys. Chem. 100, 9610 (1996).
    • (1996) J. Phys. Chem. , vol.100 , pp. 9610
    • Sadílek, M.1    Tureček, F.2
  • 56
    • 0030573157 scopus 로고    scopus 로고
    • • and Trimethylamine formed by Collisional Neutralization of Their Cations in the Gas Phase
    • • and Trimethylamine formed by Collisional Neutralization of Their Cations in the Gas Phase", Chem. Phys. Lett. 263, 203 (1996).
    • (1996) Chem. Phys. Lett. , vol.263 , pp. 203
    • Sadílek, M.1    Tureček, F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.