Reactions of Sn(NMe2)2 with primary aryl phosphides, ArPH-: Synthesis and structures of the heteroleptic cages {(PhP-PPh)Sn(μ-PPh)}2(Na-PMDETA)4 and [{Sn(μ3-Ppy)}2{Sn(μ3,μ1- pyP-Ppy)}3]

Organometallics

Volumn 24, Issue 8, 2005, Pages 1813-1818

  García, Felipe ^a   Hopkins, Alexander D ^a   Kowenicki, Richard A ^a   McPartlin, Mary ^b   Pask, Christopher M ^a   Stead, Matthew L ^a   Woods, Anthony D ^a   Wright, Dominic S ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b LONDON METROPOLITAN UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ASSOCIATION REACTIONS; CHELATION; CHEMICAL BONDS; COMPLEXATION; CONFORMATIONS; COORDINATION REACTIONS; MOLECULAR STRUCTURE; ORGANIC SOLVENTS; PHOSPHORUS COMPOUNDS; STOICHIOMETRY; SYNTHESIS (CHEMICAL); TIN COMPOUNDS; TOLUENE;

CONFORMATIONAL DISORDER; LEWIS BASE; LIGANDS; PHOSPHINIDINE;

REACTION KINETICS;

EID: 17244378583     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049177i     Document Type: Article

References (27)

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2. (a) Hopkins, A. D.; Wood, J. A.; Wright, D. S.; Hopkins, A. D.; Wood, J. A.; Wright, D. S. Coord. Chem. Rev. 2001, 216, 155.
3. (b) Beswick, M. A.; Choi, N.; Harmer, C. N.; Hopkins, A. D.; McPartlin, M.; Wright, D. S. Science 1998, 281, 1500.
4. Inorganic Chemistry; Principles of Structure and Reactivity, 4th ed.; Huheey, J. E., Keiter. E. A., Keiter, R. L., Eds.; 1993; p A21.
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12. For further examples of heterometallic alkali and alkaline earth metal/Sn(II) phosphides (in addition to those listed in ref 3), see: Allan, R. E.; Beswick, M. A.; Cromhout, N. L.; Paver, M. A.; Raithby, P. R.; Steiner, A.; Trevithick, M.; Wright, D. S. J. Chem. Soc., Chem. Commun. 1501, 1996. Westerhausen, M.; Low, R.; Schwarz, W. J. Organomet. Chem. 1996, 513, 213. Westerhausen, M.; Hausen, H.-D.; Schwarz, W. Z. Anorg. Allg. Chem. 1995, 627, 877.
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