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4 in both reactions. This was identified by elemental analysis and by obtaining the unit cell dimensions that conform to those reported in the literature [J. C. J. Bart, Acta Crystallogr. B 25, 762 (1969)].
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3543089043
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note
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2-and Me groups of all the TMEDA ligands are disordered over two 1:1 sites. The disordered toluene molecule is disordered over two sites about a twofold axis.
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23
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0000686021
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25
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0347918576
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R. Steudel, Ed. Elsevier, New York, chap. 11
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For examples of complexes of Zintl ions (of Sb in particular) with transition metal carbonyls, see O. J. Scherer et al., in The Chemistry of Inorganic Ring Systems, R. Steudel, Ed. (Elsevier, New York, 1992), chap. 11, p. 193; S. Charles, B. W. Eichhorn, S. G. Bott, J. Am. Chem. Soc. 115, 5837 (1993); S. Charles, B. W. Eichhorn, A. L. Rheingold, S. G. Bott, ibid. 116, 8077 (1994).
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Scherer, O.J.1
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26
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0000818852
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For examples of complexes of Zintl ions (of Sb in particular) with transition metal carbonyls, see O. J. Scherer et al., in The Chemistry of Inorganic Ring Systems, R. Steudel, Ed. (Elsevier, New York, 1992), chap. 11, p. 193; S. Charles, B. W. Eichhorn, S. G. Bott, J. Am. Chem. Soc. 115, 5837 (1993); S. Charles, B. W. Eichhorn, A. L. Rheingold, S. G. Bott, ibid. 116, 8077 (1994).
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Charles, S.1
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0000297904
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For examples of complexes of Zintl ions (of Sb in particular) with transition metal carbonyls, see O. J. Scherer et al., in The Chemistry of Inorganic Ring Systems, R. Steudel, Ed. (Elsevier, New York, 1992), chap. 11, p. 193; S. Charles, B. W. Eichhorn, S. G. Bott, J. Am. Chem. Soc. 115, 5837 (1993); S. Charles, B. W. Eichhorn, A. L. Rheingold, S. G. Bott, ibid. 116, 8077 (1994).
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SHELXTL PC Version 5.03
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32
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note
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We gratefully acknowledge the EPSRC (M.A.B., C.N.H., A.D.H., and M.McP.), the Leverhulme Trust (D.S.W.), the Royal Society (D.S.W.), and Electron Tubes Ruislip, Ltd. (UK) (Case grant for A.D.H.) for financial support.
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