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Volumn 44, Issue 13, 2005, Pages 1958-1961

Highly porous, homochiral metal-organic frameworks: Solvent-exchange- induced single-crystal to single-crystal transformations

Author keywords

Chirality; Crystal engineering; Functional materials; Heterogeneous catalysis; Metal organic frameworks

Indexed keywords

CATALYSTS; CHEMICAL ANALYSIS; POROUS MATERIALS; SINGLE CRYSTALS; SOLVENTS; VAPORS;

EID: 16844375457     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200462711     Document Type: Article
Times cited : (330)

References (36)
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    • Related chiral hydrogen-bonded networks have also been reported: a) R. Custelcean, M. D. Ward, Angew. Chem. 2002, 114, 1800-1804; Angew. Chem. Int. Ed. 2002, 41, 1724-1728; b) P. Grosshans, A. Jouaiti, V. Bulach, J.-M. Planeix, M. W. Hosseini, J.-F. Nicoud, Chem. Commun. 2003, 1336-1337.
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    • -1, R1 = 0.091, wR2 = 0.229, Flack parameter = 0.05(8) and GOF = 1.17. The high R1 values for 2a, 2b, and 2′ are probably a result of their metastable nature, which can lead to less perfect single crystals. CCDC-256708 (1), -256709 (1′), -256710 (2′), -256711 (2a), -256712 (2b), and -256713 (3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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    • note
    • The macrocycle plane is defined by the Cd atoms and the middle of the 1,1′-carbon atoms of the binaphthyl moiety. 2b and 2′ have a tilt angle of 0.2° and 1.1°, respectively.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.