Interlocked chiral nanotubes assembled from quintuple helices

Journal of the American Chemical Society

Volumn 125, Issue 20, 2003, Pages 6014-6015

  Cui, Yong ^a   Lee, Suk Joong ^a   Lin, Wenbin ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,1 BINAPHTHYL 6,6' BIPYRIDINE; BIPYRIDINE DERIVATIVE; NANOPARTICLE; NAPHTHYL GROUP; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; INFRARED SPECTROSCOPY; MICROANALYSIS; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; THERMOGRAVIMETRY; TUBE;

EID: 0038288990     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029926s     Document Type: Article

References (26)

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15. A helical chain has been constructed using a combination of 2,2′dihydroxy-1,1′-binaphthalene-6,6′-dicarboxylic acid and Cd centers. See: Cui, Y.; Ngo, H. L.; White, P. S.; Lin, W. Inorg. Chem. 2003, 42, 652.
16. 2 and derivatives have been used as metal-connecting points for the formation of 1D polymeric structures by Stang et al. See: (a) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. Angew. Chem., Int. Ed. 2001, 40, 1529. (b) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. J. Am. Chem. Soc. 2001, 123, 11982. (c) Tabellion. F. M.; Seidel, S. R.; Arif. A. M.; Stang, P. J. J. Am. Chem. Soc. 2001, 123, 7740-7741.
17. 2 and derivatives have been used as metal-connecting points for the formation of 1D polymeric structures by Stang et al. See: (a) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. Angew. Chem., Int. Ed. 2001, 40, 1529. (b) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. J. Am. Chem. Soc. 2001, 123, 11982. (c) Tabellion. F. M.; Seidel, S. R.; Arif. A. M.; Stang, P. J. J. Am. Chem. Soc. 2001, 123, 7740-7741.
18. 2 and derivatives have been used as metal-connecting points for the formation of 1D polymeric structures by Stang et al. See: (a) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. Angew. Chem., Int. Ed. 2001, 40, 1529. (b) Tabellion, F. M.; Seidel, S. R.; Arif, A. M.; Stang, P. J. J. Am. Chem. Soc. 2001, 123, 11982. (c) Tabellion. F. M.; Seidel, S. R.; Arif. A. M.; Stang, P. J. J. Am. Chem. Soc. 2001, 123, 7740-7741.
19. ,6′-Dibromo-2,2′-(pentaethylene glycol)-1,1′-binaphthalene was synthesized in 57% yield by treating 6,6′-dibromo-2,2′-dihydroxy-1,1′-binaphthalene with NaH, followed by pentaethylene glycol ditosylate.
20. Microanalysis, TGA, and XRPD data indicated that 1 and 2 readily lose their guest molecules upon exposure to air.
21. 3. R1 = 0.108, wR2 = 0.269, and GOF = 1.05. Flack parameter = 0.01(3).
22. A pstep value of 5 is used, which slightly underestimates the void volume. Spek, A. L. PLATON, Version 1.62. University of Utrecht, 1999.
23. 3. R1 = 0.148, wR2 = 0.344 and GOF = 1.23. Flack parameter = 0.10(5).
24. Parallel stacking has face-to-face separations of 3.26 and 3.34 Å, while nonparallel stacking has the nearest carbon to carbon distances of 3.62 and 3.74 Å.
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