Isotopic hydrogen analysis via conventional and surface-enhanced fiber optic Raman spectroscopy

Proceedings of SPIE - The International Society for Optical Engineering

Volumn 5586, Issue , 2004, Pages 83-93

  Lascola, Robert ^a   Zeigler, Kristine Eland ^a   McWhorter, C Scott ^a   Villa Aleman, Eliel ^a   Tovo, Laura L ^a   Ward, April E ^a  

^a SAVANNAH RIVER NATIONAL LABORATORY   (United States)

Author keywords

Fiber optics; Hydrogen; On line analysis; Process monitoring; Raman; SERS

Indexed keywords

ON-LINE ANALYSIS; PROCESS MONITORING; RAMAN; SERS;

COMPOSITION; DEUTERIUM; FIBER OPTICS; ISOTOPES; ONLINE SYSTEMS; PALLADIUM; RAMAN SPECTROSCOPY; RIVERS;

HYDROGEN;

EID: 16844370289     PISSN: 0277786X     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1117/12.571898     Document Type: Conference Paper

References (32)

1. A.S. Horen and M.W. Lee, "Metal hydride based isotope separation - large-scale operations", Fusion Technology, 21, 282-286, 1992.
2. M.W. Lee, "Hydrogen isotope separation experience at the Savannah River Site", Fusion Technology, 27, 95-97, 1995.
3. J.H. Scogin and A.S. Poore, "Startup and operation of a metal hydride based isotope separation process", Fusion Technology, 28, 736-741, 1995.
4. W.A. Spencer and L.L. Tovo, "Miniature mass spectrometers for hydrogen isotopic analyses", Westinghouse Savannah River Company, U.S. Dept. of Energy Report No. WSRC-TR-2002-00554, 2002 (unclassified).
5. K.E. Zeigler, R.J. Lascola, and L.L. Tovo, "Fiber-optic laser Raman spectroscopy sensor", Westinghouse Savannah River Company, U.S. Dept. of Energy Report No. WSRC-TR-2003-00284, 2003 (unclassified).
6. 2", J. Mol. Spectrosc., 121, 401-419, 1987.
7. T. Vo-Dinh, "Surface-enhanced Raman spectroscopy using metallic nanostructures", Trends Anal. Chem., 17, 557-582, 1998.
8. J.M. Sylvia, J.A. Janni, J.D. Klein, and K.M. Spencer, "Surface-enhanced Raman detection of 2,4-dinitrotoluene impurity vapor as a marker to locate landmines", Anal. Chem., 72, 5834-5840, 2000.
9. D.L. Stokes, A. Pal, V.A. Narayanan, T. Vo-Dinh, "Evaluation of a chemical vapor dosimeter using polymer-coated SERS substrates", Anal. Chim. Acta, 399, 265-274, 1999.
10. W. Hill, V. Fallourd, and D. Klockow, "Investigation of the adsorption of gaseous aromatic compounds at surfaces coated with haptakis(6-thio-6-deoxy)-b-cyclodextrin by surface-enhanced Raman scattering", J. Phys. Chem. B, 103, 4707-4713, 1999.
11. W. Hill, D. Wehling, and D. Klockow, "Analysis of odorous vapor exhaled from rubber by surface-enhanced Raman scattering", Appl. Spectrosc., 53, 547-550, 1999.
12. P.A. Mosier-Boss and S.H. Lieberman, "Detection of volatile organic compounds using surface enhanced Raman spectroscopy substrates mounted on a thermoelectric cooler", Anal. Chim. Acta, 488, 15-23, 2003.
13. K.T. Carron and B.J. Kennedy, "Molecular-specific Chromatographic detector using modified SERS substrates", Anal. Chem., 67, 3353-3356, 1995.
14. L. Bao, S.M. Mahurin, R.G. Haire, and S. Dai, "Silver-doped sol-gel film as a surface-enhanced Raman-scattering substrate for detection of uranyl and neptunyl ions", Anal. Chem., 75, 6614-6620, 2003.
15. J. Neddersen, G. Chumanov, and T.M. Cotton, "Laser ablation of metals: a new method for preparing SERS active colloids", Appl. Spectrosc., 47, 1959-1964, 1993.
16. J.C. Hulteen et al., "Nanosphere lithography: size-tunable silver particle and surface cluster arrays", J. Phys. Chem. B, 103, 3854-3863, 1999.
17. R.H. Sherman, J.R. Bartlit, and D.K. Viers, "Experimental results from hydrogen/deuterium distillations at the Tritium Systems Test Assembly", Fusion Technology, 6, 625-628, 1984.
18. K. Okuno, T. Uda, S. O'Hira, and Y. Naruse, "Development of in-situ gas analyzer for hydrogen isotopes in fusion fuel gas processing", J. Nucl. Sci. Tech., 28, 509-516, 1991.
19. S. O'Hira et al., "On-line tritium process gas analysis by laser Raman spectroscopy at TSTA", Fusion Technology, 21, 465-470, 1992.
20. S. O'hira and K. Okuno, "Development of real-time and remote fuel process gas analysis system using laser Raman spectroscopy", Fusion Technology, 30, 869-873, 1996.
21. S.E. Nave, P.E. O'Rourke, R.A. Malstrom, and W.S. Prather, "Fiber-optic Raman spectroscopy at the Savannah River Site: uses and techniques", Proc. Control and Quality, 3, 43-48, 1992.
22. S.E. Nave, "Rugged fiber optic probes and sampling systems for remote chemical analysis via the Raman technique", Westinghouse Savannah River Company, Dept. of Energy Report WSRC-MS-96-0295, 1996 (unclassified).
23. J.B. Slater et al. "Raman spectrometry and its adaptation to the industrial environment", in "Handbook of Raman Spectroscopy", I.R. Lewis and H.G.M. Edwards, eds., Marcel Dekker, New York, 41-143, 2001.
24. J.M. Berg et al., "Performance of fiber-optic Raman probes for analysis of gas mixtures in enclosures", Appl. Spectrosc., 56, 83-90, 2002.
25. J.P. Wold et al., "Rapid quantification of carotenoids and fat in Atlantic salmon (Salmo salar L.) by Raman spectroscopy and chemometrics", Appl Spectrosc., 58, 395-403 (2004).
26. K. Viers, "A Raman spectroscopic investigation of molecular hydrogen", Lawrence Berkeley Laboratory, U.S. Dept. of Energy Report No. LA-UR-86-276, 1985 (unclassified).
27. B. Ren et al., "Surface Raman spectra of pyridine and hydrogen on bare platinum and nickel electrodes", J. Electroanal. Chem., 415, 175-178, 1996.
28. P. Plaza et al., "Simulation et optimisation des capteurs à fibres optiques adjacentes", Appl. Optics, 25, 3448-3454, 1986.
29. M. Kerker, D.-S. Wang, and H. Chew, "Surface enhanced Raman scattering (SERS) by molecules absorbed at spherical particles: errata", Appl. Optics, 19, 4159-4174, 1980.
30. O.M. Løvvik and R.A. Olsen, "Density functional calculations on hydrogen in palladium-silver alloys", J. Alloys Compounds, 330-332, 332-337, 2002.
31. S. Zou et al., "Surface-enhanced Raman scattering as a ubiquitous vibrational probe of transition-metal interfaces: benzene and related chemisorbates on palladium and rhodium in aqueous solution", J. Phys. Chem. B, 102, 9039-9049, 1998.
32. Y. Sun et al., "Ag nanowires coated with Ag/Pd alloy sheaths and their use as substrates for reversible absorption and desorption of hydrogen", J. Amer. Chem. Soc., 126, 5940-5941, 2004.