Synthesis, structure, and reactivity of hydridobis(silylene)ruthenium(IV)- xantsil complexes (xantsil = (9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)) - A stabilized form of key intermediates in the catalytic oligomerization- deoligomerization of hydrosilanes

Canadian Journal of Chemistry

Volumn 81, Issue 11, 2003, Pages 1350-1358

  Okazaki, Masaaki ^a   Minglana, Jim Josephus Gabrillo ^a,b   Yamahira, Nobukazu ^a   Tobita, Hiromi ^a   Ogino, Hiroshi ^a,c  

^a TOHOKU UNIVERSITY   (Japan)

^b University of the Philippines Diliman   (Philippines)

^c OPEN UNIVERSITY OF JAPAN   (Japan)

Author keywords

Dehydrogenative coupling; Oligomerization; Polysilane; Ruthenium; Silylene complex

Indexed keywords

CATALYSIS; RUTHENIUM COMPOUNDS; SILANES; SYNTHESIS (CHEMICAL);

DEOLIGOMERIZATION; INTERMEDIATES; OLIGOMERIZATION;

AROMATIC COMPOUNDS;

CARBON DIOXIDE; HYDROGEN; RUTHENIUM COMPLEX; SILANE DERIVATIVE; TOLUENE;

ARTICLE; ATMOSPHERE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; MOLECULAR DYNAMICS; MOLECULAR STABILITY; OLIGOMERIZATION; SYNTHESIS;

EID: 1642580806     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-151     Document Type: Article

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