Open-framework iron phosphates: Syntheses, structures, sorption studies and oxidation catalysis

CrystEngComm

Volumn 5, Issue , 2003, Pages 180-189

  Abu Shandi, Khalid ^a   Winkler, Heiner ^b   Wu, Biao ^a   Janiak, Christoph ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

^b UNIVERSITY OF LÜBECK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALKANE DERIVATIVE; AMINE; CHLORINE DERIVATIVE; ETHER DERIVATIVE; FERRIC PHOSPHATE; HALOCARBON; HYDROGEN; MINERAL; PENTANE; PENTANOL; SORBENT; SPHENICIDITE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLIZATION; HYDROGEN BOND; MOSSBAUER SPECTROSCOPY; OXIDATION; POROSITY; SYNTHESIS; THERMOGRAVIMETRY; X RAY POWDER DIFFRACTION;

EID: 1642463161     PISSN: 14668033     EISSN: None     Source Type: Journal    
DOI: 10.1039/b303498d     Document Type: Article

References (118)

1. C. N. R. Rao, S. Natarajan, A. Choudhury, S. Neeraj and A. A. Ayi, Acc. Chem. Res., 2001, 34, 80.
2. Review: A. K. Cheetham, G. Férey and T. Loiseau, Angew. Chem., Int. Ed. Engl., 1999, 38, 3268.
3. Gallophosphate polymorphs, theory: S. Girard, J. D. Gale, C. Mellot-Draznieks and G. Férey, J. Am. Chem. Soc., 2002, 124, 1040.
4. 2]}: X. Chen, Y. Zhao, R. Wang, M. Li and Z. Mai, J. Chem. Soc., Dalton Trans., 2002, 3092.
5. 2O}: S. Neeraj and A. K. Cheetham, J. Chem. Soc., Chem. Commun., 2002, 1738.
6. Open-framework zinc phosphates: Y. Song, J. Yu, G. Li, Y. Li, Y. Wang and R. Xu, J. Chem. Soc., Chem. Commun., 2002, 1720.
7. 2O}: L.-I. Hung, S.-L. Wang, H.-M. Kao and K.-H. Lii, Inorg. Chem., 2002, 41, 3929.
8. 2O}: S. Mahesh, M. A. Green and S. Natarajan, J. Solid State Chem., 2002, 165, 334.
9. 2]} (bipy = bipyridine): C.-H. Huang, L.-H. Huang and K.-H. Lii, Inorg. Chem., 2001, 40, 2625.
10. 2O} (deta = diethylenetriamine): C.-H. Lin, S.-L. Wang and K.-H. Lii, J. Am. Chem. Soc., 2001, 123, 4649.
11. 2]}: W. Yan, J. Yu, Z. Shi and R. Xu, J. Chem. Soc., Chem. Commun., 2000, 1431.
12. Metal phosphates from amine phosphates: C. N. R. Rao, S. Natarajan and S. Neeraj, J. Solid State Chem., 2000, 152, 302.
13. 2O}: A. M. Chippindale, K. J. Peacock and A. J. Cowley, J. Solid State Chem., 1999, 145, 379.
14. 2]: R. Finn and J. Zubieta, J. Chem. Soc., Chem. Commun., 2000, 1321.
15. J. M. Thomas and R. Raja, Aust. J. Chem., 2001, 54, 551.
16. S. K. Mohapatra, B. Sahoo, W. Keune and P. Selvam, J. Chem. Soc., Chem. Commun., 2002, 1466.
17. E. Roland and P. Kleinschmit, Ullmann's Encyclopedia of Industrial Chemistry. Volume A28, VCH, Weinheim, 5th edn., 1996, p. 475; G. H. Kühl and C. T. Kresge, Kirk-Othmer Encyclopedia of Chemical Technology. Volume 16,Wiley, New York, 4th edn., 1995, p. 888; F. Schüth, Chem. Unserer Zeit, 1995, 29, 42; W. Hölderich, M. Hesse and F. Näumann, Angew. Chem., Int. Ed. Engl., 1988, 27, 226; L. Puppe, Chem. Unserer Zeit, 1986, 20, 117.
18. E. Roland and P. Kleinschmit, Ullmann's Encyclopedia of Industrial Chemistry. Volume A28, VCH, Weinheim, 5th edn., 1996, p. 475; G. H. Kühl and C. T. Kresge, Kirk-Othmer Encyclopedia of Chemical Technology. Volume 16,Wiley, New York, 4th edn., 1995, p. 888; F. Schüth, Chem. Unserer Zeit, 1995, 29, 42; W. Hölderich, M. Hesse and F. Näumann, Angew. Chem., Int. Ed. Engl., 1988, 27, 226; L. Puppe, Chem. Unserer Zeit, 1986, 20, 117.
19. E. Roland and P. Kleinschmit, Ullmann's Encyclopedia of Industrial Chemistry. Volume A28, VCH, Weinheim, 5th edn., 1996, p. 475; G. H. Kühl and C. T. Kresge, Kirk-Othmer Encyclopedia of Chemical Technology. Volume 16,Wiley, New York, 4th edn., 1995, p. 888; F. Schüth, Chem. Unserer Zeit, 1995, 29, 42; W. Hölderich, M. Hesse and F. Näumann, Angew. Chem., Int. Ed. Engl., 1988, 27, 226; L. Puppe, Chem. Unserer Zeit, 1986, 20, 117.
20. E. Roland and P. Kleinschmit, Ullmann's Encyclopedia of Industrial Chemistry. Volume A28, VCH, Weinheim, 5th edn., 1996, p. 475; G. H. Kühl and C. T. Kresge, Kirk-Othmer Encyclopedia of Chemical Technology. Volume 16,Wiley, New York, 4th edn., 1995, p. 888; F. Schüth, Chem. Unserer Zeit, 1995, 29, 42; W. Hölderich, M. Hesse and F. Näumann, Angew. Chem., Int. Ed. Engl., 1988, 27, 226; L. Puppe, Chem. Unserer Zeit, 1986, 20, 117.
21. E. Roland and P. Kleinschmit, Ullmann's Encyclopedia of Industrial Chemistry. Volume A28, VCH, Weinheim, 5th edn., 1996, p. 475; G. H. Kühl and C. T. Kresge, Kirk-Othmer Encyclopedia of Chemical Technology. Volume 16,Wiley, New York, 4th edn., 1995, p. 888; F. Schüth, Chem. Unserer Zeit, 1995, 29, 42; W. Hölderich, M. Hesse and F. Näumann, Angew. Chem., Int. Ed. Engl., 1988, 27, 226; L. Puppe, Chem. Unserer Zeit, 1986, 20, 117 .
22. 2]: K. Abu-Shandi, C. Janiak and B. Kersting, Acta Crystallogr., Sect. C, 2001, 57, 1261.
23. Reduced molybdenum phosphates: R. C. Haushalter and L. A. Mundi, Chem. Mater., 1992, 4, 31.
24. 2O}: M. I. Khan, L. M. Meyer, R.C. Haushalter, A. L. Schweiter, J. Zubieta and J. L. Dye, Chem. Mater., 1996, 8, 43.
25. Review: S. Oliver, A. Kuperman and G. A. Ozin, Angew. Chem., Int. Ed. Engl., 1998, 37, 46.
26. 2O}: C.-Y. Chen, F. R. Lo, H. M. Kao and K. H. Lii, J. Chem. Soc., Chem. Commun., 2000, 1061.
27. 2O}: A. B. Corradi, M. R. Cramarossa, T. Manfredini, L. P. Battaglia, G. Pelosi, A. Saccani and F. Sandrolini, J. Chem. Soc., Dalton Trans., 1993, 3587.
28. 27]}: W. T. A. Harrison, L. L. Dussack and A. J. Jacobson, Acta Crystallogr., Sect. C, 1996, 52, 1075.
29. 2]}: A. N. Christensen, A. Bareges, R. B. Nielsen, R. G. Hazell, P. Norby and J. C. Hanson, J. Chem. Soc., Dalton Trans., 2001, 1611.
30. 12)]}: A. Marzotto, D. A. Clemente and G. Valle, Acta Crystallogr., Sect. C, 1999, 55, 43.
31. Hydrothermal synthesis: R. I. Walton, Chem. Soc. Rev., 2002, 31, 230; A. Stein, S. W. Keller and T. E. Mallouk, Science (Washington, D. C.), 1993, 259, 1558.
32. Hydrothermal synthesis: R. I. Walton, Chem. Soc. Rev., 2002, 31, 230; A. Stein, S. W. Keller and T. E. Mallouk, Science (Washington, D. C.), 1993, 259, 1558.
33. F. L. Wagenaar and J. F. Kerwin, J. Org. Chem., 1993, 58, 4331.
34. E. Craven, K. Abu-Shandi and C. Janiak, Z. Anorg. Allg. Chem., 2003, 629, 195.
35. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
36. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
37. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
38. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
39. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
40. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
41. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
42. Review: P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024; O. Kahn, Molecular Magnetism, VCH, Weinheim, 1993, ch. 4, p. 53ff; J. Zarembowitch, New J. Chem., 1992, 16, 255; P. Gütlich and A. Hauser, Coord. Chem. Rev., 1990, 97, 1; H. Toftlund, Coord. Chem. Rev., 1989, 94, 67; E. König, Progr. Inorg. Chem., 1987, 35, 527; P. Gütlich, Struct. Bond., 1981, 44, 83; H. A. Goodwin, Coord. Chem. Rev., 1976, 18, 293.
43. B. Kersting, M. J. Kolm and C. Janiak, Z. Anorg. Allg. Chem., 1998, 624, 775; B. Kersting, D. Siebert, D. Volkmer, M. J. Kolm and C. Janiak, Inorg. Chem., 1999, 38, 3871; A. Geiß, M. J. Kolm, C. Janiak and H. Vahrenkamp, Inorg. Chem., 2000, 39, 4037.
44. B. Kersting, M. J. Kolm and C. Janiak, Z. Anorg. Allg. Chem., 1998, 624, 775; B. Kersting, D. Siebert, D. Volkmer, M. J. Kolm and C. Janiak, Inorg. Chem., 1999, 38, 3871; A. Geiß, M. J. Kolm, C. Janiak and H. Vahrenkamp, Inorg. Chem., 2000, 39, 4037.
45. B. Kersting, M. J. Kolm and C. Janiak, Z. Anorg. Allg. Chem., 1998, 624, 775; B. Kersting, D. Siebert, D. Volkmer, M. J. Kolm and C. Janiak, Inorg. Chem., 1999, 38, 3871; A. Geiß, M. J. Kolm, C. Janiak and H. Vahrenkamp, Inorg. Chem., 2000, 39, 4037.
46. T. Manago, S. Hayami, H. Oshio, S. Osaki, H. Hasuyama, R. H. Herber and Y. Maeda, J. Chem. Soc., Dalton Trans., 1999, 1001.
47. J. R. D. DeBord, W. M. Reiff, C. J. Warren, R. C. Haushalter and J. Zubieta, Chem. Mater., 1997, 9, 1994.
48. D. Lee, J. L. DuBois, B. Pierce, B. Hedman, K. O. Hodgson, M. P. Hendrich and S. J. Lippard, Inorg. Chem., 2002, 41, 3172; W. E. Buschmann, J. Ensling, P. Gütlich and J. S. Miller, Chem. Eur. J., 1999, 5, 3019; J. R. Haradorn, L. Que, Jr and W. B. Tolman, J. Am. Chem. Soc., 1999, 121, 9760; M. Sato, Y. Hayashi, T. Tsuda and M. Katada, Inorg. Chim. Acta, 1997, 261, 113; C.-C. Wu, H. G. Jang, A. L. Rheingold, P. Gütlich and D. N. Hendrickson, Inorg. Chem., 1996, 35, 4137.
49. D. Lee, J. L. DuBois, B. Pierce, B. Hedman, K. O. Hodgson, M. P. Hendrich and S. J. Lippard, Inorg. Chem., 2002, 41, 3172; W. E. Buschmann, J. Ensling, P. Gütlich and J. S. Miller, Chem. Eur. J., 1999, 5, 3019; J. R. Haradorn, L. Que, Jr and W. B. Tolman, J. Am. Chem. Soc., 1999, 121, 9760; M. Sato, Y. Hayashi, T. Tsuda and M. Katada, Inorg. Chim. Acta, 1997, 261, 113; C.-C. Wu, H. G. Jang, A. L. Rheingold, P. Gütlich and D. N. Hendrickson, Inorg. Chem., 1996, 35, 4137.
50. D. Lee, J. L. DuBois, B. Pierce, B. Hedman, K. O. Hodgson, M. P. Hendrich and S. J. Lippard, Inorg. Chem., 2002, 41, 3172; W. E. Buschmann, J. Ensling, P. Gütlich and J. S. Miller, Chem. Eur. J., 1999, 5, 3019; J. R. Haradorn, L. Que, Jr and W. B. Tolman, J. Am. Chem. Soc., 1999, 121, 9760; M. Sato, Y. Hayashi, T. Tsuda and M. Katada, Inorg. Chim. Acta, 1997, 261, 113; C.-C. Wu, H. G. Jang, A. L. Rheingold, P. Gütlich and D. N. Hendrickson, Inorg. Chem., 1996, 35, 4137.
51. D. Lee, J. L. DuBois, B. Pierce, B. Hedman, K. O. Hodgson, M. P. Hendrich and S. J. Lippard, Inorg. Chem., 2002, 41, 3172; W. E. Buschmann, J. Ensling, P. Gütlich and J. S. Miller, Chem. Eur. J., 1999, 5, 3019; J. R. Haradorn, L. Que, Jr and W. B. Tolman, J. Am. Chem. Soc., 1999, 121, 9760; M. Sato, Y. Hayashi, T. Tsuda and M. Katada, Inorg. Chim. Acta, 1997, 261, 113; C.-C. Wu, H. G. Jang, A. L. Rheingold, P. Gütlich and D. N. Hendrickson, Inorg. Chem., 1996, 35, 4137.
52. D. Lee, J. L. DuBois, B. Pierce, B. Hedman, K. O. Hodgson, M. P. Hendrich and S. J. Lippard, Inorg. Chem., 2002, 41, 3172; W. E. Buschmann, J. Ensling, P. Gütlich and J. S. Miller, Chem. Eur. J., 1999, 5, 3019; J. R. Haradorn, L. Que, Jr and W. B. Tolman, J. Am. Chem. Soc., 1999, 121, 9760; M. Sato, Y. Hayashi, T. Tsuda and M. Katada, Inorg. Chim. Acta, 1997, 261, 113; C.-C. Wu, H. G. Jang, A. L. Rheingold, P. Gütlich and D. N. Hendrickson, Inorg. Chem., 1996, 35, 4137.
53. N. N. Greenwood and T. C. Gibb, Mössbauer Spectroscopy, Chapman and Hall, London 1971.
54. M. Riou-Cavellec, C. Serre, J. Robino, M. Noguès, J.-M. Grenèche and G. Férey, J. Solid State Chem., 1999, 147, 122.
55. L.-M. Zheng, H.-H. Song, C.-H. Lin, S.-L. Wang, Z. Hu, Z. Yu and X.-Q. Xin, Inorg. Chem., 1999, 38, 4618.
56. J. R. D. DeBord, W. M. Reiff, R. C. Haushalter and J. Zubieta, J. Solid State Chem., 1996, 125, 186.
57. C.-Y. Huang, S.-L. Wang and K.-H. Lii, J. Porous Mater., 1998, 5, 147.
58. 2O}: V. Zima and K.-H. Lii, J. Chem.Soc., Dalton Trans., 1998, 4109.
59. A. Choudhury, S. Natarajan and C. N. R. Rao, J. Chem. Soc., Chem. Commun., 1999, 1305.
60. V. Zima, K.-H. Lii, N. Nguyen and A. Ducouret, Chem. Mater., 1998, 10, 1914.
61. M. Cavellec, G. Férey and J. M. Grenèche, J. Magn. Magn. Mater., 1997, 167, 57.
62. M. Cavellec, D. Riou and G. Férey, Acta Crystallogr., Sect. C, 1994, 50, 1379.
63. Calcuation with PLATON for Windows based on gridpoints at least 1.2 Å away from the nearest van der Waals surface: A. L. Spek, Acta Crystallogr., Sect. A, 1990, 46, C34; PLATON version 29-11-98. Windows implementation: L. J. Farrugia, University of Glasgow, Scotland 1997.
64. Calcuation with PLATON for Windows based on gridpoints at least 1.2 Å away from the nearest van der Waals surface: A. L. Spek, Acta Crystallogr., Sect. A, 1990, 46, C34; PLATON version 29-11-98. Windows implementation: L. J. Farrugia, University of Glasgow, Scotland 1997.
65. A. Choudhury and S. Natarajan, Proc. Indian Acad. Sci. (Chem. Sci.), 1999, 111, 627.
66. STOE WinXpow, Version 1.06, copyright 1999, STOE & Cie GMBH. ICSD Inorganic Crystal Structure Database, FIZ Karlsruhe, February 1995.
67. τ = (difference between the two largest anges)/60 for five-coordinated metal centers allows for the assignment of a square-pyramidal (ideally τ = 0) or a trigonal-biypramidal geometry (ideally τ = 1): A. W. Addison, T. N. Rao, J. Reedijk, J. van Rijn and G. C. Verschoor, J. Chem. Soc., Dalton Trans., 1984, 1349.
68. 3+-O, B = 0.37; Program VALENCE (Version 2.00, February 1993); I. D. Brown, J. Appl. Crystallogr., 1996, 29, 479.
69. 3+-O, B = 0.37; Program VALENCE (Version 2.00, February 1993); I. D. Brown, J. Appl. Crystallogr., 1996, 29, 479.
70. I. D. Brown and R. D. Shannon, Acta Crystallogr., Sect. A, 1973, 29, 266; I. D. Brown and K. K. Wu, Acta Crystallogr., Sect. B, 1976, 32, 1957; I. D. Brown and D. Altermatt, Acta Crystallogr., Sect. B, 1985, 41, 244.
71. I. D. Brown and R. D. Shannon, Acta Crystallogr., Sect. A, 1973, 29, 266; I. D. Brown and K. K. Wu, Acta Crystallogr., Sect. B, 1976, 32, 1957; I. D. Brown and D. Altermatt, Acta Crystallogr., Sect. B, 1985, 41, 244.
72. I. D. Brown and R. D. Shannon, Acta Crystallogr., Sect. A, 1973, 29, 266; I. D. Brown and K. K. Wu, Acta Crystallogr., Sect. B, 1976, 32, 1957; I. D. Brown and D. Altermatt, Acta Crystallogr., Sect. B, 1985, 41, 244.
73. V. Zima and K.-H. Lii, J. Solid State Chem., 1998, 139, 326.
74. L.-M. Zheng, X. Fang, K.-H. Lii, H.-H. Song, X.-Q. Xin, H.-K. Fun, K. Chinnakali and I. A. Razak, J. Chem. Soc., Dalton Trans., 1999, 2311; N. Okabe and T. Makino, Acta Crystallogr., Sect. C, 1998, 54, 1279; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5129; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5138.
75. L.-M. Zheng, X. Fang, K.-H. Lii, H.-H. Song, X.-Q. Xin, H.-K. Fun, K. Chinnakali and I. A. Razak, J. Chem. Soc., Dalton Trans., 1999, 2311; N. Okabe and T. Makino, Acta Crystallogr., Sect. C, 1998, 54, 1279; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5129; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5138.
76. L.-M. Zheng, X. Fang, K.-H. Lii, H.-H. Song, X.-Q. Xin, H.-K. Fun, K. Chinnakali and I. A. Razak, J. Chem. Soc., Dalton Trans., 1999, 2311; N. Okabe and T. Makino, Acta Crystallogr., Sect. C, 1998, 54, 1279; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5129; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5138.
77. L.-M. Zheng, X. Fang, K.-H. Lii, H.-H. Song, X.-Q. Xin, H.-K. Fun, K. Chinnakali and I. A. Razak, J. Chem. Soc., Dalton Trans., 1999, 2311; N. Okabe and T. Makino, Acta Crystallogr., Sect. C, 1998, 54, 1279; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5129; P. Laine, A. Gourdon and J.-P. Launay, Inorg. Chem., 1995, 34, 5138.
78. J. Sletten, H. Daraghmeh, F. Lloret and M. Julve, Inorg. Chim. Acta, 1998, 127, 279; E. Andres, G. De Munno, M. Julve, J. A. Real and F. Lloret, J. Chem. Soc., Dalton Trans., 1993, 2169.
79. J. Sletten, H. Daraghmeh, F. Lloret and M. Julve, Inorg. Chim. Acta, 1998, 127, 279; E. Andres, G. De Munno, M. Julve, J. A. Real and F. Lloret, J. Chem. Soc., Dalton Trans., 1993, 2169.
80. Q. Liu, Y. Wei, W. Wang and S. Zhang, Acta Crystallogr., Sect. C, 1999, 55, 9900127; S. Noro, M. Kondo, S. Kitagawa, T. Ishii and H. Matsuzaka, Chem. Lett, 1999, 727; J. M. C. Juan, C. Mackiewicz, M. Verelst, F. Dahan, A. Bousseksou, Y. Sanakis and J.-P. Tuchagues, Inorg. Chem., 2002, 41, 1478.
81. Q. Liu, Y. Wei, W. Wang and S. Zhang, Acta Crystallogr., Sect. C, 1999, 55, 9900127; S. Noro, M. Kondo, S. Kitagawa, T. Ishii and H. Matsuzaka, Chem. Lett, 1999, 727; J. M. C. Juan, C. Mackiewicz, M. Verelst, F. Dahan, A. Bousseksou, Y. Sanakis and J.-P. Tuchagues, Inorg. Chem., 2002, 41, 1478.
82. Q. Liu, Y. Wei, W. Wang and S. Zhang, Acta Crystallogr., Sect. C, 1999, 55, 9900127; S. Noro, M. Kondo, S. Kitagawa, T. Ishii and H. Matsuzaka, Chem. Lett, 1999, 727; J. M. C. Juan, C. Mackiewicz, M. Verelst, F. Dahan, A. Bousseksou, Y. Sanakis and J.-P. Tuchagues, Inorg. Chem., 2002, 41, 1478.
83. M. Tiliakos, P. Cordopatis, A. Terzis, C. P. Raptopoulou, S. P. Perlepes and E. M. Zoupa, Polyhedron, 2001, 20, 2203; S. Kiani, A. Tapper, R. J. Staples and P. Stavropoulos, J. Am. Chem. Soc., 2000, 122, 7503.
84. M. Tiliakos, P. Cordopatis, A. Terzis, C. P. Raptopoulou, S. P. Perlepes and E. M. Zoupa, Polyhedron, 2001, 20, 2203; S. Kiani, A. Tapper, R. J. Staples and P. Stavropoulos, J. Am. Chem. Soc., 2000, 122, 7503.
85. A. Neves, M. A. de Brito, I. Vencato, V. Drago, K. Griesar, W. Haase and Y. P. Mascarenhas, Inorg. Chim. Acta, 1993, 5, 214; A. Neves, M. A. de Brito, I. Vencato, V. Drago, K. Griesar and W. Haase, Inorg. Chem., 1996, 35, 2360; D. Zirong, S. Bhattacharya, J. K. McCusker, P. M. Hagen, D. N. Hendrickson and C. G. Pierpont, Inorg. Chem., 1992, 31, 870.
86. A. Neves, M. A. de Brito, I. Vencato, V. Drago, K. Griesar, W. Haase and Y. P. Mascarenhas, Inorg. Chim. Acta, 1993, 5, 214; A. Neves, M. A. de Brito, I. Vencato, V. Drago, K. Griesar and W. Haase, Inorg. Chem., 1996, 35, 2360; D. Zirong, S. Bhattacharya, J. K. McCusker, P. M. Hagen, D. N. Hendrickson and C. G. Pierpont, Inorg. Chem., 1992, 31, 870.
87. A. Neves, M. A. de Brito, I. Vencato, V. Drago, K. Griesar, W. Haase and Y. P. Mascarenhas, Inorg. Chim. Acta, 1993, 5, 214; A. Neves, M. A. de Brito, I. Vencato, V. Drago, K. Griesar and W. Haase, Inorg. Chem., 1996, 35, 2360; D. Zirong, S. Bhattacharya, J. K. McCusker, P. M. Hagen, D. N. Hendrickson and C. G. Pierpont, Inorg. Chem., 1992, 31, 870.
88. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
89. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
90. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
91. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
92. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
93. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
94. Y. Feng, S.-L. Ong, J. Hu and W. J. Ng, Acta Crystallogr., Sect. C, 2002, 58, m34; A. Horn, A. Neves, A. J. Bortoluzzi, V. Drago and W. A. Ortiz, Inorg. Chem. Commun., 2001, 4, 173; E. J. Seddon, J. Yoo, K. Folting, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 3640; C. M. Grant, M. J. Knapp, J. C. Huffman, D. N. Hendrickson and G. Christou, J. Chem. Soc., Chem. Commun., 1998, 1753; C. M. Grant, M. J. Knapp, W. E. Streib, J. C. Huffman, D. N. Hendrickson and G. Christou, Inorg. Chem., 1998, 37, 6065; S. M. Gorun and S. J. Lippard, Inorg. Chem., 1988, 27, 149; A. J. Blake, C. M. Grant, S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Dalton Trans., 1996, 321.
95. R. W. Saalfrank, I. Bernt, M. M. Chowdhry, F. Hampel and G. B. M. Vaughan, Chem. Eur. J., 2001, 7, 2765; E. J. Seddon, J. C. Huffman and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 4446; P. J. Zapf, R. P. Hammond, R. C. Haushalter and J. Zubieta, Chem. Mater., 1998, 10, 1366.
96. R. W. Saalfrank, I. Bernt, M. M. Chowdhry, F. Hampel and G. B. M. Vaughan, Chem. Eur. J., 2001, 7, 2765; E. J. Seddon, J. C. Huffman and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 4446; P. J. Zapf, R. P. Hammond, R. C. Haushalter and J. Zubieta, Chem. Mater., 1998, 10, 1366.
97. R. W. Saalfrank, I. Bernt, M. M. Chowdhry, F. Hampel and G. B. M. Vaughan, Chem. Eur. J., 2001, 7, 2765; E. J. Seddon, J. C. Huffman and G. Christou, J. Chem. Soc., Dalton Trans., 2000, 4446; P. J. Zapf, R. P. Hammond, R. C. Haushalter and J. Zubieta, Chem. Mater., 1998, 10, 1366.
98. A. K. Boudalis, N. Lalioti, G. A. Spyroulias, C. P. Raptopoulou, A. Terzis, V. Tangoulis and S. P. Perlepes, J. Chem. Soc., Dalton Trans., 2001, 955; K. A. Abboud, C. Xu and R. S. Drago, Acta Crystallogr., Sect. C, 1998, 54, 1270; K. L. Taft, A. Masschelein, S. Liu, S. J. Lippard, D. G-Shweky and A. Bino, Inorg. Chim. Acta, 1992, 198, 627.
99. A. K. Boudalis, N. Lalioti, G. A. Spyroulias, C. P. Raptopoulou, A. Terzis, V. Tangoulis and S. P. Perlepes, J. Chem. Soc., Dalton Trans., 2001, 955; K. A. Abboud, C. Xu and R. S. Drago, Acta Crystallogr., Sect. C, 1998, 54, 1270; K. L. Taft, A. Masschelein, S. Liu, S. J. Lippard, D. G-Shweky and A. Bino, Inorg. Chim. Acta, 1992, 198, 627.
100. A. K. Boudalis, N. Lalioti, G. A. Spyroulias, C. P. Raptopoulou, A. Terzis, V. Tangoulis and S. P. Perlepes, J. Chem. Soc., Dalton Trans., 2001, 955; K. A. Abboud, C. Xu and R. S. Drago, Acta Crystallogr., Sect. C, 1998, 54, 1270; K. L. Taft, A. Masschelein, S. Liu, S. J. Lippard, D. G-Shweky and A. Bino, Inorg. Chim. Acta, 1992, 198, 627.
101. K. Abu-Shandi, H. Winkler, M. Gerdan, F. Emmerling, B. Wu and C. Janiak, Dalton Trans., 2003, DOI: 10.1039/b303498d.
102. C. E. Buss and K. R. Mann, J. Am. Chem. Soc., 2002, 124, 1031; E. J. Cussen, J. B. Claridge, M. J. Rosseinsky and C. J. Kepert, J. Am. Chem. Soc., 2002, 124, 9574.
103. C. E. Buss and K. R. Mann, J. Am. Chem. Soc., 2002, 124, 1031; E. J. Cussen, J. B. Claridge, M. J. Rosseinsky and C. J. Kepert, J. Am. Chem. Soc., 2002, 124, 9574.
104. M. Hartmann and S. Ernst, Angew. Chem., Int. Ed., 2000, 39, 888; P. A. MacFaul, D. D. M. Wayner and K. U. Ingold, Acc. Chem. Res., 1998, 31, 159.
105. M. Hartmann and S. Ernst, Angew. Chem., Int. Ed., 2000, 39, 888; P. A. MacFaul, D. D. M. Wayner and K. U. Ingold, Acc. Chem. Res., 1998, 31, 159.
106. Activation and Functionalization of Alkanes, ed. C. L. Hill, Wiley: Chichester, 1989; ch. 6-8; P. A. MacFaul, K. U. Ingold, D. D. M. Wayner and L. Que, Jr., J. Am. Chem. Soc., 1997, 119, 10594; P. A. MacFaul, I. W. C. E. Arends, K. U. Ingold and D. D. M. Wayner, J. Chem. Soc., Perkin Trans. 2, 1997, 135.
107. Activation and Functionalization of Alkanes, ed. C. L. Hill, Wiley: Chichester, 1989; ch. 6-8; P. A. MacFaul, K. U. Ingold, D. D. M. Wayner and L. Que, Jr., J. Am. Chem. Soc., 1997, 119, 10594; P. A. MacFaul, I. W. C. E. Arends, K. U. Ingold and D. D. M. Wayner, J. Chem. Soc., Perkin Trans. 2, 1997, 135.
108. Activation and Functionalization of Alkanes, ed. C. L. Hill, Wiley: Chichester, 1989; ch. 6-8; P. A. MacFaul, K. U. Ingold, D. D. M. Wayner and L. Que, Jr., J. Am. Chem. Soc., 1997, 119, 10594; P. A. MacFaul, I. W. C. E. Arends, K. U. Ingold and D. D. M. Wayner, J. Chem. Soc., Perkin Trans. 2, 1997, 135.
109. R. Raja, G. Sankar and J. M. Thomas, J. Am. Chem. Soc., 1999, 121, 11926.
110. J. M. Thomas, R. Raja, G. Sankar and R. G. Bell, Acc. Chem. Res., 2001, 34, 191.
111. J. M. Thomas, R. Raja, G. Sankar and R. G. Bell, Nature (London), 1999, 398, 227; R. Raja, G. Sankar and J. M. Thomas, J. Chem. Soc., Chem. Commun., 1999, 829.
112. J. M. Thomas, R. Raja, G. Sankar and R. G. Bell, Nature (London), 1999, 398, 227; R. Raja, G. Sankar and J. M. Thomas, J. Chem. Soc., Chem. Commun., 1999, 829.
113. K. Abu-Shandi and C. Janiak, unpublished work.
114. SMART, Data Collection Program for the CCD Area-Detector System; SAINT, Data Reduction and Frame Integration Program for the CCD Area-Detector System, Bruker Analytical X-ray Systems, Madison, Wisconsin, USA, 1997.
115. SMART, Data Collection Program for the CCD Area-Detector System; SAINT, Data Reduction and Frame Integration Program for the CCD Area-Detector System, Bruker Analytical X-ray Systems, Madison, Wisconsin, USA, 1997.
116. G. Sheldrick, Program SADABS: Area-detector absorption correction, University of Göttingen, Germany, 1996.
117. G. M. Sheldrick, SHELXS-97, SHELXL-97, Programs for Crystal Structure Analysis, University of Göttingen, Germany, 1997.
118. DIAMOND 2.1e for Windows. Crystal Impact Gbr, Bonn, Germany.; http://www.crystalimpact.com/diamond.