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0343676495
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note
-
The structures of 4a, 6b, and 7 were determined by X-ray diffraction. The distance between the ammonium nitrogen and the fluorenide plane in 4a is 3.00 Å. ORTEP diagrams and details of the structural determinations are given in the Supporting Information.
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-
-
-
14
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0343240855
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see ref 8
-
The same complex is formed upon treatment of hydroxido complex 2 with phenylacetylene; see ref 8.
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16
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0347847757
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Ellison, G. B.; Davico, G. E.; Bierbaum, V. M.; DePuy, C. H. Int. J. Mass Spectrom. Ion Processes 1996, 156, 109.
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0031790878
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18
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0001413712
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X., Z.
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21
-
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0343676494
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-
note
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- depends on the structure of X. Under our conditions, the ion pair is apparently higher in energy when X = phenyl and p-toluidyl than when X = benzyl or allyl.
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-
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22
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33748405619
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Dóbé, S.; Bérces, T.; Turányi, T.; Márta, F. J. Phys. Chem. 1996, 100, 19864.
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23
-
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0343240853
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-
note
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Amido complex 1 will decompose after prolonged exposures to elevated temperatures.
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-
-
-
24
-
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0001527351
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-
Cycloheptrienyl and fluorenyl radicals rapidly dimerize upon formation; see: (a) Vincow, G.; Dauben, H. J.; Hunter, F. R.; Volland, W. V. J. Am. Chem. Soc. 1969, 91, 2823. (b) Arends, I. W. C. E.; Mulder, P.; Clark, K. B.; Wayner, D. D. M. J. Phys. Chem. 1995, 99, 8182.
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Vincow, G.1
Dauben, H.J.2
Hunter, F.R.3
Volland, W.V.4
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25
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0000117593
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Cycloheptrienyl and fluorenyl radicals rapidly dimerize upon formation; see: (a) Vincow, G.; Dauben, H. J.; Hunter, F. R.; Volland, W. V. J. Am. Chem. Soc. 1969, 91, 2823. (b) Arends, I. W. C. E.; Mulder, P.; Clark, K. B.; Wayner, D. D. M. J. Phys. Chem. 1995, 99, 8182.
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Arends, I.W.C.E.1
Mulder, P.2
Clark, K.B.3
Wayner, D.D.M.4
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26
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0000007502
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Zhang, X.-M.; Bruno, J. W.; Enyinnaya, E. J. Org. Chem. 1998, 63, 4671.
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Enyinnaya, E.3
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28
-
-
0342371338
-
-
note
-
2Ph) (8) with liquid ammonia does not result in the formation of amido complex 1 and toluene, establishing that the failure to observe 8 is not due to thermodynamic factors. We suggest that the exchange occurs via a strongly hydrogen-bonded complex or transition state, which has no low-energy route to the extrusion of ammonia and formation of the Ru-C bond.
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-
-
-
30
-
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0343240847
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note
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Labeled nitrogen is observed in the eis isomer, which is formed after 1 month at room temperature and is presumed to be the more thermodyamically stable isomer.
-
-
-
-
31
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0003160796
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Szwarc, M., Ed.; Wiley-Interscience: New York
-
max of the UV - vis spectrum of 4a is 368 nm, consistent with a contact ion pair and not a solvent-separated ion pair; see: Smid, J. In Ions and Ion Pairs in Organic Reactions; Szwarc, M., Ed.; Wiley-Interscience: New York, 1972; Vol. 1, p 85.
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Smid, J.1
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0000329967
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Holland, P. L.; Andersen, R. A.; Bergman, R. G. Comments Inorg. Chem. 1999, 21, 115.
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Holland, P.L.1
Andersen, R.A.2
Bergman, R.G.3
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