Green chemistry and engineering: Drivers, metrics, and reduction to practice

Annual Review of Environment and Resources

Volumn 28, Issue , 2003, Pages 401-428

  Marteel, Anne E ^a   Davies, Julian A ^a   Olson, Walter W ^b   Abraham, Martin A ^b  

^a UNIVERSITY OF TOLEDO   (United States)

^b The University of Toledo   (United States)

Author keywords

Benign manufacturing; Benign solvents; Catalyst design; Industrial ecology

Indexed keywords

CATALYSTS; CHEMICAL INDUSTRY; CHEMICAL REACTORS; ECOLOGY; ECONOMIC AND SOCIAL EFFECTS; ORGANIC SOLVENTS;

CHEMICAL MANUFACTURING; GREEN CHEMISTRY; INDUSTRIAL ECOLOGY;

ENVIRONMENTAL IMPACT;

EID: 1642439047     PISSN: 15435938     EISSN: None     Source Type: Book Series    
DOI: 10.1146/annurev.energy.28.011503.163459     Document Type: Article

References (117)

1. Anastas, PT, Warner, JC. 1998. Green Chemistry Theory and Practice, p 7. New York: Oxford Univ. Press. 152 pp.
2. Anastas, PT, Zimmerman JB. 2003. Design through the 12 principles of green engineering. Environ. Sci. Technol. 37(5); A94-101
3. Wei J, Cussler, EL. 2003. Chemical engineers are key to product engineering. AIChE J. 49(5): 1072
4. Allen DT, Rosselot KS. 1997. Pollution Prevention for Chemical Processes. New York: Wiley. 434 pp.
5. Thornton J. 2001. Implementing green chemistry. An environmental policy for sustainability. Pure Appl. Chem. 73(8): 1231-36
6. Reinert, KH. 2001. Integrating green chemistry and sustainability into a specialty chemical company. Pure Appl. Chem. 73(8):1269-72
7. Brandt C. 2002. Sustainable development and responsible care-chemical industry headed for a green future? Chem. Unserer Zeit 36(4):214-24
8. Graedel T. 1999. Green chemistry in an industrial ecology context. Green Chem. 1(5):126-28
9. Allen DT, Butner RS. 2002. Industrial ecology: a chemical engineering challenge. Chem. Eng. Prog. 98(11):40-45
10. Herrchen M, Klein W. 2000. Use of the life-cycle assessment (LCA) tool-box for an environmental evaluation of production processes. Pure Appl. Chem. 72(7): 1247-52
11. Fava J, Denison R, Jones B, Curran M, Vigon B. 1991. Technical Framework for Life Cycle Assessment. Pensacola, FL: Soc. Environ. Toxicol. Chem.
12. Graedl TE, Allenby BR. 1995. Industrial Ecology. Englewood Cliffs, NJ: Prentice-Hall. 384 pp.
13. Keoleian GA, Kar K, Manion MM, Bulkley JW. 1997. Industrial Ecology of the Automobile. Warrendale, PA: Soc. Automot. Eng.
14. Sullivan JL, Williams RL, Yester S, Cobas-Flores E, Chubbs ST, Hentges SG, Pomper SD. 1998. Life cycle assessment of a generic U.S. family sedan, overview of results USCAR AMP Project in SAE P-339. Pap. SAE 982160. Presented at Total Life Cycle Conf. Proc., Warrendale, PA
15. Owens JW. 1997. Life cycle assessment in relation to risk assessment: an evolving perspective. Risk Anal. 17(3): 359-66
16. Olson W, Abraham M. 2000. When is green really green? A pilot investigation of the time effects using LCA data. SAE 2000-01-1494/SAEP-353. Proc. SAE Total Life Cycle Conf., pp. 213-23, Detroit, MI
17. Thiel C. 2000. Comparative life cycle assessment of aluminum and steel bumper carriers. Presented at Total Life Cycle Conf., Detroit, MI
18. Cascio J, Baughn KT. 2000. Health safety, and ISO 14001. Manuf. Eng. 124(5):126-35
19. Herrchen M. 1998. Perspective of the systematic and extended use of temporal and spatial aspects of LCA of long lived products. Chemosphere 37(2):265-70
20. Grimberg KJ, Greener CS. 2003. Sustainability Mapping Tool. SAE 2003-01-0548/SAE SP-1788. Proc. Sustain. Environ. Syst. Mater., pp. 1-44
21. Hersey K. 1998. A close look at ISO 14000. Prof. Saf. 43(7):26-29
22. Bhat VN. 1999. Does it pay to be green? Int. J. Environ. Stud. A,B 56(4):497-508
23. Eissen M, Metzger JO. 2001. Environmental performance metrics for daily use in synthetic chemistry. Chem.-Eur. J. 8(16):3580-85
24. Constable DJC, Curzons AD, dos Santos LMF, Green GR, Hannah RE. 2001. Green chemistry measures for process research and development. Green Chem. 3(1):7-9
25. Schwarz J, Beloff B, Beaver E. 2002. Use sustainability metrics to guide decisionmaking. Chem. Eng. Prog. 98(7):58-63
26. Sheldon RA. 1997. Catalysis: the key to waste minimization. J. Chem. Technol. Biotechnol. 68(4):381-88
27. Sheldon RA. 2000. Atom utilization, E factors and the catalytic solution. C. R. Acad. Sci., Sér. II 3:541-51
28. Trost BM. 1991. The atom economy: a search for synthetic efficiency. Science 254(5037):1471-77
29. Mallick SK, Cabezas H, Bare JC, Sikdar SK. 1996. A pollution prevention methodology for chemical process simulators. Ind. Eng. Chem. Res. 35(11):4128-38
30. Cabezas H, Bare JC, Mallick SK. 1997. Pollution prevention with chemical process simulators: the generalized waste reduction (WAR) algorithm. Comput. Chem. Eng. 21:S305-10
31. Young D, Scharp K, Cabezas H. 2000. The waste reduction (WAR) algorithm: environmental impacts, energy consumption, and engineering economics. Waste Manag. 20(8):605-15
32. Castillo EF, Mora M. 2000. Mathematical modelling as a tool for environmental evaluation of industrial sectors in Colombia. Waste Manag. 20(8):617-23
33. US Dep. Energy. Energy Information Administration Home Page. http://www.eia.doe.gov/
34. Narodoslawski N, Krotscheck C. 2000. Integrated ecological optimization of processes with the sustainable process index. Waste Manag. 20(8):599-603
35. Dewulf J, Van Langenhove H. 2002. Assessment of the sustainability of technology by means of a thermodynamically-based life cycle analysis. Environ. Sci. Pollut. Res. 9(4):267-73
36. Finnveden G, Ostlund P. 1997. Exergies of natural resources in life-cycle assessment and other applications. Energy 22(9):923-31
37. Bakshi BR. 2002. A thermodynamic framework for ecologically conscious process systems engineering. Comput. Chem. Eng. 26(2):269-82
38. Barrer-Roldan A, Saldivar-Valdes A. 2002. Proposal and application of a Sustainable Development Index. Ecol. Indic. 2:251-56
39. Sustain. Dev. Work. Group, Inst. Chem. Eng. 2001. Sustainable Development Progress Metrics: Recommended for Use in the Process Industries, Inst. Chem. Eng. Rugby, Warwickshire, UK, pp. 1-28
40. Palmer AR. 1999. Ecological footprints: evaluating sustainability. Environ. Geosci. 6(4):200-4
41. Spangenberg JJ. 2002. Environmental space and the prism of sustainability: frameworks for indicators measuring sustainable development. Ecol. Indic. 2:295-309
42. Shane AM, Graedel TE. 2000. Urban environmental sustainability metrics: a provisional set. J. Environ. Plan. Manag. 43(5):643-63.
43. Lankey RL, Anastas PT. 2002. Life-cycle approaches for assessing green chemistry technologies. Ind. Eng. Chem. Res. 41(18):4498-502
44. Graedel TE. 2001. Green chemistry as systems science. Pure Appl. Chem. 73(8):1243-46
45. Reinius HK, Suomalainen P, Riihimaki H, Karvinen E, Pursiainen J, et al. 2001. o-Alkyl-substituted triphenyl phosphines: activity and regioselectivity in rhodium-catalyzed propene hydroformylation. J. Catal. 199(2):302-8
46. Karlsson M, Andersson C, Hjortkjaer J. 2001. Hydroformylation of propene and 1-hexene catalyzed by a α-zirconium phosphate supported rhodium-phosphine complex. J. Mol. Catal. A-Chem. 166(2): 337-43
47. Shibahara F, Nozaki K, Matsuo T, Hiyama, T. 2002. Asymmetric hydroformylation with highly crosslinked polystyrene-supported (R,S)-BINAPHOS-Rh(I) complexes: the effect of immobilization position. Bioorg. Med. Chem. Lett. 12(14):1825-27
48. Nozaki K, Shibahara F, Hiyama T. 2000. Vapor-phase asymmetric hydroformylation. Chem. Lett. (6):694-95
49. Lu S, Li X, Wang A. 2000. A new chiral diphosphine ligand and its asymmetric induction in catalytic hydroformylation of olefins. Catal. Today 63(2-4):531-36
50. van Leeuwen PWNM, Claver C. 2000. Rhodium Catalyzed Hydroformylation. Dordrecht, Ger.: Kluwer Acad.
51. Hanson BE. 1999. New directions in water soluble homogeneous catalysis. Coord. Chem. Rev. 185-186:795-807
52. Buhling A, Kamer PCJ, van Leeuwen PWNM. 1995. Rhodium-catalyzed hydroformylation of higher alkenes using amphiphilic ligands. J. Mol. Catal. A-Chem. 98(2):69-80
53. Chen H, Li YZ, Chen JR, Cheng PM, He YE, et al. 1999. Micellar effect in high olefin hydroformylation catalyzed by water-soluble rhodium complex. J. Mol. Catal. A-Chem. 149(1-2):1-6
54. Arhancet JP, Davis ME, Hanson BE. 1991. Supported aqueous-phase, rhodium hydroformylation catalysts. 2. Hydroformylation of linear, terminal and internal olefins. J. Catal. 129(1):100-5
55. Bourque SC, Alper H, Manzer LE, Arya P. 2000. Hydroformylation reactions using recyclable rhodium-complexed dendrimers on silica. J. Am. Chem. Soc. 122(5):956-57
56. de Groot D, Emmerink PG, Coucke C, Reek JNH, Kamer PCJ, et al. 2000. Rhodium catalysed hydroformylation using diphenylphosphine functionalised carbosilane dendrimers. Inorg. Chem. Commun. 3(12):711-13
57. Horváth IT, Rabai J. 1994. Facile catalyst separation without water-fluorous biphase hydroformylation of olefins. Science 266(5182):72-75
58. Fish RH. 1999. Fluorous biphasic catalysis: a new paradigm for the separation of homogeneous catalysts from their reaction substrates and products. Chem.-Eur. J. 5(6):1677-80
59. Rutherford D, Juliette JJJ, Rocaboy C, Horváth IT, Gladysz JA. 1998. Transition metal catalysis in fluorous media: application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes. Catal. Today 42(4):381-88
60. Curran D, Hadidad S. 1996. Tris(2-(perfluorohexyl)ethyl)tin hydride: a new fluorous reagent for use in traditional organic synthesis and liquid phase combinatorial synthesis. J. Am. Chem. Soc. 118(10):2531-32
61. Juliette JJJ, Rutherford D, Horváth IT, Gladysz JA. 1999. Transition metal catalysis in fluorous media: practical application of a new immobilization principle to rhodium-catalyzed hydroborations of alkenes and alkynes. J. Am. Chem. Soc. 121(12):2696-704
62. Pozzi G, Cinato F, Montanari F, Quici S. 1998 Efficient aerobic epoxidation of alkenes in perfluorinated solvents catalysed by chiral (salen) Mn complexes. Chem. Commun. 8:877-78
63. 2. Angew. Chem.-Int. Ed. Engl. 36(21):2346-49
64. Wasserscheid P, Waffenschmidt H. 2000. Ionic liquids in regioselective platinum-catalysed hydroformylation. J. Mol. Catal. A-Chem. 164(1-2):61-67
65. Wasserscheid P, Waffenschmidt H, Machnitzki P, Kottsieper KW, Stelzer O. 2001. Cationic phosphine ligands with phenylguanidinium modified xanthene moieties-a successful concept for highly regioselective, biphasic hydroformylation of oct-1-ene in hexafluorophosphate ionic liquids. Chem. Commun. 5:451-52
66. Sellin MF, Webb PB, Cole-Hamilton DJ. 2001 Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures. Chem. Commun. 8:781-82
67. Huddleston J, Willauer H, Swatloski R, Visser A, Rogers R. 1998 Room temperature ionic liquids as novel media for 'clean' liquid-liquid extraction. Chem. Commun. 16:1765-66
68. Mizushima E, Hayashi T, Tanaka M. 2001 Palladium-catalysed carbonylation of aryl halides in ionic liquid media: high catalyst stability and significant rate-enhancement in alkoxycarbonylation. Green Chem. 3(2):76-79
69. 2 systems. J. Phys. Chem. B 105(12):2437-2444
70. Wasserscheid P, van Hal R, Bosman A. 2002 1-n-Butyl-3-methylimidazolium ([bmim]) octylsulfate-an even 'greener' ionic liquid. Green Chem. 4(4):400-4
71. McNamara CA, Dixon MJ, Bradley M. 2002 Recoverable catalysts and reagents using recyclable polystyrene-based supports. Chem. Rev. 102(10):3275-99
72. Iwasawa Y. 1986. Inorganic oxide-attached metal catalysts. In Tailored Metal Catalysts, Vol. 1, ed. Y Iwasawa, pp. 1-85. Dordrecht, Ger.: Reidel
73. 2 using a heterogeneous rhodium catalyst. 1. Effect of process parameters. J. Supercrit. Fluids 25(2):183-95
74. Tadd AR, Marteel A, Mason MR, Davies JA, Abraham MA. 2002 Hydroformylation of 1-hexene in supercritical carbon dioxide using a heterogeneous rhodium catalyst. 2. Evaluation of reaction kinetics. Ind. Eng. Chem. Res. 41(18):4514-22
75. Hemminger O, Marteel A, Mason MR, Davies JA, Tadd AR, et al. 2002 Hydroformylation of 1-hexene in supercritical carbon dioxide using a heterogeneous rhodium catalyst. 3. Evaluation of solvent effects. Green Chem. 4(5):507-12
76. Clark JH. 2002 Solid acids for green chemistry. Acc. Chem. Res. 35(9):791-97
77. Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, et al. 1992 A new family of mesoporous molecular-sieves prepared with liquid-crystal templates. J. Am. Chem. Soc. 114(27):10834-43
78. Marteel AE. Davies JA, Mason RR, Tadd A, Tack T. 2002 Development of heterogeneous catalysts for hydroformylation of 1-hexene in supercritical carbon dioxide. Presented at Annu. Green Chem. Eng. Meet., 6th, Washington, DC
79. Marteel AE, Davies JA, Mason MR, Tack T, Bektesevic S, Abraham MA. 2003 Supported platinum/tin complexes as catalysts for hydroformylation of 1-hexene in supercritical carbon dioxide. Catal. Commun. 4(7):309-314
80. Ikariya T, Kayaki Y. 2000 Supercritical fluids as reaction media for molecular catalysis. Catal. Surv. Jpn. 4(1):39-50
81. Jessop PG, Ikariya T, Noyori R. 1999 Homogeneous catalysis in supercritical fluids. Chem. Rev. 99(2):475-93
82. Kainz S, Koch D, Baumann W, Leitner W. 1997 Perfluoroalkyl-substituted arylphosphanes as ligands for homogeneous catalysis in supercritical carbon dioxide. Angew. Chem.-Int. Ed. Engl. 36(15):1628-1630
83. 3. Ind. Eng. Chem. Res. 38(5):2163-65
84. Sellin MF, Cole-Hamilton DJ. 2000 Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes. J. Chem. Soc.-Dalton Trans. (11):1681-83
85. Dharmidhikari S, Abraham MA. 2000 Rhodium supported on activated carbon as a heterogeneous catalyst for hydroformylation of propylene in supercritical carbon dioxide. J. Supercrit. Fluids 18(1): 1-10
86. 2. Ind. Eng. Chem. Res. 40(23):5317-25
87. Meehan NJ. Sandee AJ, Reek JNH, Kamer PCJ, van Leeuwen PWNM, Poliakoff M. 2000 Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst. Chem. Commun. (16):1497-98
88. Collins T, Inst. Green Oxid. Chem. 2001. Ethics: The Great Fields of Green Chemistry http://www.chem.cmu.edu/groups/Collins/ethics/ethics06.html
89. World Comm. Environ. Dev. 1987 Our Common Future. New York: Oxford Univ. Press.
90. Rounds KS, Cooper JS. 2002 Development of product design requirements using taxonomies of environmental issues. Res. Eng. Design 13:94-108
91. Epstein MJ, Wisner PS. 2001 Using a balanced scorecard to implement sustainability. Environ. Qual. Manag. 11(2):1-10
92. Elkington J. 1998 Cannibals with Forks. Stony Creek, CT: New Soc. 408 pp.
93. Hawken P, Lovins A, Lovins LH. 1999 Natural Capitalism. New York: Little, Brown. 396 pp.
94. Frankel C. 1998. Earth's Company. Stony Creek, CT: New Soc. 263 pp.
95. Fiksel J. 2001. Emergence of a sustainable business community. Pure Appl. Chem. 73:1265-68
96. Edinger R, Kaul S, 2000. Humankind's detour toward sustainability: past, present, and future of renewable energies and electric power generation. Renew. Sustain. Energy Rev. 3:295-313
97. Carette L, Friedrich KA, Stimming U. 2000 Fuel cells: principles, types, fuels, and applications. ChemPhysChem 1:162-93
98. Ghenciu AF. 2002 Review of fuel processing catalysts for hydrogen production in PEM fuel cell systems. Curr. Opin. Solid State Mater. Sci. 6:389-99
99. Joensen F, Rostrup-Nielsen JR. 2002 Conversion of hydrocarbons and alcohols for fuel cells. J. Power Sour. 105:195-201
100. Paglieri SN, Way JD. 2002. Innovations in palladium membrane research. Sep. Purif. Methods 31:1-169
101. Würfel P. 2002 Thermodynamic limitations to solar energy conversion. Physica E 14:18-26
102. Zalba B, Marin JM, Cabeza LF, Mehling H. 2003 Review on thermal energy storage with phase change: materials, heat transfer analysis and applications. Appl. Thermal Eng. 23:251-83
103. Steinfeld A. 2002. Solar hydrogen production via a two-step water-splitting thermochemical cycle based on ZnZnO redox reactions. Int. J. Hydrog. Energy 27:611-19
104. Green MA. 2002. Photovoltaic principles. Physica E 14:11-17
105. Bozell JJ, Hoberg JO, Claffey D, Hames BR, Dimmel DR. 1998. New methodology for the production of chemicals from renewable feedstocks. In Green Chemistry, ed. PT Anastas, TC Williamson, pp. 27-45. New York: Oxford Univ. Press
106. Danner H, Braun R. 1999. Biotechnology for the production of commodity chemicals from biomass. Chem. Soc. Rev. 28:395-405
107. Abbadi A, Gotlieb KF, van Bekkum H. 1998. Study on solid acid catalyzed hydrolysis of maltose and related polysaccharides. Starch-Starke 50:23-28
108. Embree HD, Chen T, Payne GF. 2001. Oxygenated aromatic compounds from renewable resources: motivation, opportunities, and adsorptive separations. Chem. Eng. J. 84:133-47
109. Bozell JJ, Moens L, Elliott DC, Wang Y, Neuenscwander GG, Fitzpatrick SW. 2000. Production of levulinic acid and use as a platform chemical for derived products. Resour. Conserv. Recycl. 28:227-39
110. McKendry P. 2002. Energy production from biomass (part 1 to 30): overview of biomass. Bioresour. Technol. 83:37-46
111. Bridgwater AV. 2003. Renewable fuels and chemicals by thermal processing of biomass. Chem. Eng. J. 91:87-102
112. Mohanty AK, Misra M, Drzal LT. 2002. Sustainable bio-composites from renewable resources: opportunities and challenges in the green materials world. J. Polym. Environ. 10:19-26
113. Herrmann AS, Nickel J, Riedel U. 1998. Construction materials based upon biologically renewable resources - from components to finished parts. Polym. Degrad. Stab. 59:251-61
114. Vink ETH, Rabago KR, Glassner DA, Gruber PR. 2003. Applications of life cycle assessment to NatureWorks polylactide (PLA) production. Polym. Degrad. Stab. 80:403-19
115. Mulholland KL, Sylvester RW, Dyer JA. 2000. Sustainability: waste minimization, green chemistry and inherently safer processing. Environ. Prog. 19(4):260-68
116. Hjeresen DL, Kirchhoff MM, Lankey RL. 2002. Green chemistry: environment, economics, and competitiveness. Corp. Environ. Strategy 9(3):259-66
117. Centi G, Ciambelli P, Perathoner S, Russo P. 2002. Environmental catalysis: trends and outlook. Catal. Today 75(1-4):3-15