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Volumn 45, Issue 15, 2004, Pages 3101-3103

Direct allylic substitution of allyl alcohols by carbon pronucleophiles in the presence of a palladium/carboxylic acid catalyst under neat conditions

Author keywords

Allylpalladium complex; Allylic alcohol; Allylic substitution; Palladium carboxylic acid catalyst; Palladium catalyst; Pronucleophile; Water

Indexed keywords

ALCOHOL DERIVATIVE; CARBON; CARBOXYLIC ACID; ORGANIC SOLVENT; PALLADIUM;

EID: 1642312894     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.02.094     Document Type: Article
Times cited : (47)

References (28)
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    • oct for lauric acid: 4.6, acetic acid: -0.13, see:
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    • note
    • The present reaction conditions, the allylation under neat conditions, produced 1 equiv of water after completing the reaction. It is not clear at present whether the water generated during the reaction progress is essential or not for promoting the allylation. All we can say here is that water is not needed as a solvent.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.