Synthesis and structural characterization of novel neutral hexacoordinate silicon(IV) complexes with SiO2N4 skeletons containing cyanato-N or thiocyanato-N ligands

Inorganic Chemistry

Volumn 44, Issue 7, 2005, Pages 2337-2346

  Seiler, Oliver ^a   Burschka, Christian ^a   Fischer, Markus ^a   Penka, Martin ^a   Tacke, Reinhold ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

4 AMINOPENT 3 EN 2 ONE DERIVATIVE; COORDINATION COMPOUND; CYANIC ACID DERIVATIVE; LIGAND; SILICON DERIVATIVE; THIOCYANIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHELATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; LIGAND BINDING; MATHEMATICAL COMPUTING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; SOLID STATE; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 16244412613     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0485211     Document Type: Article

References (56)

1. (a) Everett, G. W., Jr.; Holm, R. H. J. Am. Chem. Soc. 1965, 87, 2117-2127.
2. (b) Lingafelter, E. C.; Braun, R. L. J. Am. Chem. Soc. 1966, 88, 2951-2956.
3. (c) Robards, K.; Patsalides, E.; Dilli, S. J. Chromatogr. 1987, 411, 1-41.
4. (d) Kim, J.; Hwang, J.-W.; Kim, Y.; Lee, M. H.; Han, Y.; Do, Y. J. Organomet. Chem. 2001, 620, 1-7.
5. (e) Shi, Y.-C.; Yang, H.-M.; Shen, W.-B.; Yan, C.-G.; Hu, X.-Y. Polyhedron 2004, 23, 15-21.
6. (f) Shi, Y.-C.; Yang, H.-M.; Song, H.-B.; Liu, Y.-H. Polyhedron 2004, 23, 1541-1546.
7. (a) Tandon, J. P.; Gupta, S. R.; Prasad, R. N. Monatsh. Chem. 1976, 107, 1379-1389.
8. (b) Singh, R. V.; Tandon, J. P. J. Prakt. Chem. 1979, 321, 151-158.
9. (c) Singh, R. V.; Tandon, J. P. J. Prakt. Chem. 1979, 321, 683-690.
10. (d) Aminabhavi, T. M.; Biradar, N. S.; Patil, S. B. Indian J. Chem. 1986, 25A, 285-286.
11. (a) Mucha, F.; Böhme, U.; Roewer, G. Chem. Commun. 1998, 1289-1290.
12. (b) Mucha, F.; Haberecht, J.; Böhme, U.; Roewer, G. Monatsh. Chem. 1999, 130, 117-132.
13. (c) Wagler, J.; Böhme, U.; Roewer, G. Angew. Chem. 2002, 114, 1825-1827.
14. Wagler, J.; Böhme, U.; Roewer, G. Angew. Chem., Int. Ed. 2002, 41, 1732-1734.
15. (d) Wagler, J.; Doert, T.; Roewer, G. Angew. Chem. 2004, 116, 2495-2498.
16. Wagler, J.; Doert, T.; Roewer, G. Angew. Chem., Int. Ed. 2004, 43, 2441-2444.
17. (a) Seiler, O.; Bertermann, R.; Buggisch, N.; Burschka, C.; Penka, M.; Tebbe, D.; Tacke, R. Z. Anorg. Allg. Chem. 2003, 629, 1403-1411.
18. (b) Tacke, R.; Bertermann, R.; Penka, M.; Seiler, O. Z. Anorg. Allg. Chem. 2003, 629, 2415-2420.
19. Selected reviews dealing with compounds of higher-coordinate silicon: (a) Tandura, S. N.; Voronkov, M. G.; Alekseev, N. V. Top. Curr. Chem. 1986, 131, 99-189.
20. (b) Sheldrick, W. S. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989; Part 1, pp 227-303.
21. (c) Bassindale, A. R.; Taylor, P. G. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989; Part 1, pp 839-892.
22. (d) Corriu, R. J. P.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; Wiley: Chichester, U.K., 1989; Part 2, pp 1241-1288.
23. (e) Holmes, R. R. Chem. Rev. 1990, 90, 17-31.
24. (f) Chuit, C.; Corriu, R. J. P.; Reye, C.; Young, J. C. Chem. Rev. 1993, 93, 1371-1448.
25. (g) Tacke, R.; Becht, J.; Lopez-Mras, A.; Sperlich, J. J. Organomet. Chem. 1993, 446, 1-8.
26. (h) Verkade, J. G. Coord. Chem. Rev. 1994, 137, 233-295.
27. (i) Tacke, R.; Dannappel, O. In Tailor-Made Silicon-Oxygen Compounds - From Molecules to Materials; Corriu, R., Jutzi, P., Eds.; Vieweg: Braunschweig-Wiesbaden, Germany, 1996; pp 75-86.
28. (j) Lukevics, E.; Pudova, O. A. Chem. Heterocycl. Compd. 1996, 32, 1381-1418.
29. (k) Holmes, R. R. Chem. Rev. 1996, 96, 927-950.
30. (l) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 2, pp 1339-1445.
31. (m) Pestunovich, V.; Kirpichenko, S.; Voronkov, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chichester, U.K., 1998; Vol. 2, Part 2, pp 1447-1537.
32. (n) Chuit, C.; Corriu, R. J. P.; Reye, C. In Chemistry of Hypervalent Compounds; Akiba, K., Ed.; Wiley-VCH: New York, 1999; pp 81-146.
33. (o) Tacke, R.; Pülm, M.; Wagner, B. Adv. Organomet. Chem. 1999, 44, 221-273.
34. (p) Brook, M. A. Silicon in Organic, Organometallic, and Polymer Chemistry; Wiley: New York, 2000; pp 97-114.
35. (q) Tacke, R.; Seiler, O. In Silicon Chemistry: From the Atom to Extended Systems; Jutzi, P., Schubert, U., Eds.; Wiley-VCH: Weinheim, Germany, 2003; pp 324-337.
36. Seiler, O.; Fischer, M.; Penka, M.; Tacke, R. Book of Abstracts, 2nd European Organosilicon Days, München, Germany, September 11-12, 2003; Abstract P 146.
37. The solution NMR spectra of (OC-6-12)-3, (OC-6-12)-4, (OC-6-12)-5, and (OC-6-12)-6 are characterized by multiple sets of resonance signals, indicating the presence of more than one species. The data given in the Experimental Section correspond to the respective major species. In the case of (OC-6-12)-3 and (OC-6-12)-6, no solution NMR data are given because the NMR spectra could not be interpreted unequivocally.
38. (a) WIN-DAISY 4.05; Bruker-Franzen GmbH: Bremen, Germany, 1998.
39. (b) Weber, U.; Germanus, A.; Thiele, H. Fresenius' J. Anal. Chem. 1997, 359, 46-49.
40. Neville, R. G.; McGee, J. J. In Inorganic Syntheses; Holtzclaw, H. F., Jr., Ed.; McGraw-Hill: New York, 1966; Vol. VIII, pp 23-31.
41. (a) Sheldrick, G. M. SHELXS-97; University of Göttingen: Göttingen, Germany, 1997.
42. (b) Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467-473.
43. Sheldrick, G. M. SHELXL-97; University of Göttingen: Göttingen, Germany, 1997.
44. (a) Weigend, F.; Häser, M. Theor. Chem. Acc. 1997, 97, 331-340.
45. (b) Weigend, F.; Häser, M.; Patzelt, H.; Ahlrichs, R. Chem. Phys. Lett. 1998, 294, 143-152.
46. Schäfer, A.; Horn, H.; Ahlrichs, R. J. Chem. Phys. 1992, 97, 2571-2577.
47. Schäfer, A.; Huber, C.; Ahlrichs, R. J. Chem. Phys. 1994, 100, 5829-5835.
48. Program system TURBOMOLE: Ahlrichs, R.; Bär, M.; Häser, M.; Horn, H.; Kölmel, C. Chem. Phys. Lett. 1989, 162, 165-169.
49. 4 with Me-C(Ni-PrH)=CH-C(O)-Me: Jones, D.; Roberts, A.; Cavell, K.; Keim, W.; Englert, U.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1998, 255-262.
50. The hydrogen-bonding system was analyzed by using the program PLATON: Spek, A. L. PLATON; University of Utrecht: Utrecht, The Netherlands, 1998.
51. The nomenclature of the chelate complexes studied is also based on this idealized formal description.
52. Tayyari, S. F.; Fazli, M.; Milani-nejad, F. J. Mol. Struct.: THEOCHEM 2001, 541, 11-15.
53. A perfect agreement between the calculated and experimentally established structures cannot be expected since the latter are influenced by intermolecular interactions in the crystal.
54. 1H NMR spectrum of rrans-8 that could point to the existence of cis-8 in solution.
55. Guo, M.; Kenney, M. E. Book of Abstracts, 37th Silicon Symposium, Philadelphia, PA, May 20-22, 2004; Abstract B18.
56. Seiler, O.; Metz, S.; Penka, M.; Tacke, R. Manuscript in preparation