Bis[acetylacetonato(1-)-O,O]di(cyanato-N)silicon(IV): A Neutral Hexacoordinate Silicon Complex with Two Cyanato-N Ligands

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 629, Issue 12-13, 2003, Pages 2415-2420

  Tacke, Reinhold ^a   Bertermann, Rüdiger ^a   Penka, Martin ^a   Seiler, Oliver ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

Computational studies; Coordination chemistry; Cyanato N ligand; Cyanato O ligand; Hexacoordinate silicon; NMR spectroscopy (solid state); Silicon

Indexed keywords

BIS[ACETYLACETONATO(1) O,O]DI(CYANATO N)SILICON; LIGAND; SILICON DERIVATIVE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CALCULATION; CARBON NUCLEAR MAGNETIC RESONANCE; CRYSTAL STRUCTURE; GEOMETRY; NITROGEN NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; SILICON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0346785276     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/zaac.200300259     Document Type: Article

References (52)

1. M. J. Barrow, S. Cradock, E. A. V. Ebsworth, M. M. Harding, J. Chem. Soc., Chem. Commun. 1977, 744.
2. A. I. Gusev, E. B. Chuklanova, A. S. Zhdanov, E. V. Muzovskaya, V. P. Kozyukov, Zh. Strukt. Khim. 1989, 30, 182.
3. E. B. Chuklanova, A. I. Gusev, A. S. Zhdanov, E. V. Muzovskaya, V. P. Kozyukov, Organomet. Chem. USSR 1988, 1, 629.
4. S. S. Al-Juaid, A. A. K. Al-Nasr, G. A. Ayoko, C. Eaborn, P. Hitchcock, J. Organomet. Chem. 1995, 488, 155.
5. G. A. Ayoko, C. Eaborn, P. B. Hitchcock, Organometallics 1995, 14, 4960.
6. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
7. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
8. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
9. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
10. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
11. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
12. -: (a) E. Bär, W. P. Fehlhammer, D. K. Breitinger, J. Mink, Inorg. Chim. Acta 1984, 82, L17. (b) W. Heininger, R. Stucka, G. Nagorsen, Z. Naturforsch. 1986, 41b, 702. (c) W. Heininger, K. Polborn, G. Nagorsen, Z. Naturforsch. 1988, 43b, 857. (d) S. P. Narula, R. Shankar, B. Kaur, S. Soni, Polyhedron 1991, 10, 2463. (e) M. Fritz, D. Rieger, E. Bär, G. Beck, J. Fuchs, G. Holzmann, W. P. Fehlhammer, Inorg. Chim. Acta 1992, 198-200, 513. (f) A. C. Filippou, P. Portius, G. Schnakenburg, J. Am. Chem. Soc. 2002, 124, 12396. (g) O. Seiler, R. Bertermann, N. Buggisch, C. Burschka, M. Penka, D. Tebbe, R. Tacke, Z. Anorg. Allg. Chem. 2003, 629, 1403.
13. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
14. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
15. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
16. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
17. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
18. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
19. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
20. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
21. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
22. Recent publications dealing with compounds of higher-coordinate silicon: (a) R. Tacke, M. Penka, F. Popp, I. Richter, Eur. J. Inorg. Chem. 2002, 1025. (b) A. Biller, C. Burschka, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3901. (c) I. Richter, M. Penka, R. Tacke, Inorg. Chem. 2002, 41, 3950. (d) I. Richter, M. Penka, R. Tacke, Organometallics 2002, 21, 3050. (e) O. Seiler, C. Burschka, M. Penka, R. Tacke, Z. Anorg. Allg. Chem. 2002, 625, 2427. (f) O. Seiler, C. Burschka, M. Penka, R. Tacke, Silicon Chemistry, in press. (g) R. Tacke, R. Bertermann, A. Biller, C. Burschka, M. Penka, Can. J. Chem. 2003, 57, 1315. (h) R. Bertermann, A. Biller, M. Kaupp, M. Penka, O. Seiler, R. Tacke, Organometallics 2003, 22, 4104. (i) S. Dragota, R. Bertermann, C. Burschka, J. Heermann, M. Penka, I. Richter, B. Wagner, R. Tacke, Silicon Chemistry, in press. (j) O. Seiler, M. Penka, R. Tacke, Inorg. Chim. Acta, in press.
23. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
24. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
25. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
26. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
27. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
28. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
29. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
30. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
31. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
32. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
33. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
34. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
35. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
36. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
37. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
38. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
39. Selected reviews dealing with compounds of higher-coordinate silicon: (a) S. N. Tandura, M. G. Voronkov, N. V. Alekseev, Top. Curr. Chem. 1986, 131, 99. (b) W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 227-303. (c) A. R. Bassindale, P. G. Taylor, in: The Chemistry of Organic Silicon Compounds, Part 1, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 839-892. (d) R. J. P. Corriu, J. C. Young, in: The Chemistry of Organic Silicon Compounds, Part 2, S. Patai, Z. Rappoport (eds.), Wiley, Chichester, U.K., 1989, pp. 1241-1288. (e) R. R. Holmes, Chem. Rev. 1990, 90, 17. (f) C. Chuit, R. J. P. Corriu, C. Reye, J. C. Young, Chem. Rev. 1993, 93, 1371 . (g) R. Tacke, J. Becht, A. Lopez-Mras, J. Sperlich, J. Organomet. Chem. 1993, 446, 1. (h) J. G. Verkade, Coord. Chem. Rev. 1994, 137, 233. (i) R. Tacke, O. Dannappel, in: Tailor-made Silicon-Oxygen Compounds - From Molecules to Materials, R. Corriu, P. Jutzi (eds.), Vieweg, Braunschweig-Wiesbaden, Germany, 1996, pp. 75 -86. (j) E. Lukevics, O. A. Pudova, Chem. Heterocycl. Compd. (Engl. Transl.) 1996, 32, 1381. (k) R. R. Holmes, Chem. Rev. 1996, 96, 927. (l) D. Kost, I. Kalikhman, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1339-1445. (m) V. Pestunovich, S. Kirpichenko, M. Voronkov, in: The Chemistry of Organic Silicon Compounds, Vol. 2, Part 2, Z. Rappoport, Y. Apeloig (eds.), Wiley, Chichester, U.K., 1998, pp. 1447-1537. (n) C. Chuit, R. J. P Corriu, C. Reye, in: Chemistry of Hypervalent Compounds, K. Akiba (ed.), Wiley-VCH, New York, 1999, pp. 81-146. (o) R. Tacke, M. Pulm, B. Wagner, Adv. Organomet. Chem. 1999, 44, 221. (p) M. A. Brook, Silicon in Organic, Organometallic, and Polymer Chemistry, Wiley, New York, 2000, pp. 97-114. (q) R. Tacke, O. Seiler, in: Silicon Chemistry: From the atom to Extended Systems, P. Jutzi, U. Schubert (eds.), Wiley-VCH, Weinheim, in press.
40. O. Seiler, N. Buggisch, M. Penka, R. Tacke, XIII International Symposium on Organosilicon Chemistry - 35th Organosilicon Symposium, Guanajuato, Mexico, August 25-30, 2002, Abstracts Book, Abstract P2-45, p. 161.
41. R. G. Neville, J. J. McGee, in: Inorganic Syntheses, Vol. VIII, H. F. Holtzclaw, Jr. (ed.), McGraw-Hill, New York, 1966, pp. 23-27.
42. The low yield is due to the short crystallization time (2 h). In the case of an extended crystallization time (24 h), a mixture of cis-8 and trans-8 was isolated (total yield 80%; 382 mg, 1.23 mmol).
43. (a) F. Weigend, M. Häser, Theor. Chem. Acc. 1997, 97, 331.
44. (b) F. Weigend, M. Häser, H. Patzelt, R. Ahlrichs, Chem. Phys. Lett. 1998, 294, 143.
45. A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571.
46. A. Schäfer, C. Huber, R. Ahlrichs, J. Chem. Phys. 1994, 700, 5829.
47. Program system TURBOMOLE: R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Lett. 1989, 762, 165.
48. A perfect agreement between the calculated and experimentally established structure of cis-8 cannot be expected since the latter is influenced by intermolecular interactions in the crystal.
49. 14N) coupling of the NCO carbon atoms were only poorly resolved because of the low signal to noise ratio of the respective signals and the large chemical shift anisotropy (CSA) of the NCO carbon atoms.
50. G. M. Sheldrick, SHELXS-97, University of Göttingen, Göttingen, Germany, 1997.
51. G. M. Sheldrick, Acta Crystallogr., Sect. A 1990, 46, 467.
52. G M. Sheldrick, SHELXL-97, University of Göttingen, Göttingen, Germany, 1997.