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note
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There are total of 13 crystal structures were found for ligand 1, whereas only one structure was found for 2a in CSD.
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note
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The Ag-atom was found in disorder over two sites with occupancies of 0.91 and 0.09. The Ag-atom that involved in the double helix formation has 0.91 occupancy while the Ag-atom that has 0.09 occupancy has coordinated to one imine nitrogen and one pyridine nitrogen atom.
-
-
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54
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16244402080
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note
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2b as such, is not unstable in solution but it is unstable in solution when it is coordinated to the metal atoms. Please see ref. 12c for similar type of unstable behavior of the complexes of 4-pyridyl analogues of the ligand.
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