Enantioselective hydrogenation of ethyl pyruvate catalyzed by α- and β-isocinchonine-modified Pt/Al2O3 in toluene: Inversion of enantioselectivity

Journal of Catalysis

Volumn 231, Issue 1, 2005, Pages 33-40

  Bartók, Mihály ^a,b   Sutyinszki, Mária ^b   Bucsi, Imre ^b   Felföldi, Károly ^b   Szöllosi, György ^a   Bartha, Ferenc ^a   Bartók, Tibor ^c  

^a INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^b UNIVERSITY OF SZEGED   (Hungary)

^c CEREAL RESEARCH NON PROFIT COMPANY   (Hungary)

Author keywords

Chiral hydrogenation; Conformation; ESI MS MS; Ethyl pyruvate; Intermediate; Inversion enantioselectivity; Pt alumina; and Isocinchonine

Indexed keywords

CATALYSIS; CATALYSTS; CHEMICAL MODIFICATION; CONCENTRATION (PROCESS); CONFORMATIONS; MIXTURES; TOLUENE;

CHIRAL HYDROGENATION; ESI-MS-MS; ETHYL PYRUVATE; INTERMEDIATE; INVERSION ENANTIOSELECTIVITY; MODIFIER CONCENTRATION; PT-ALUMINA; REACTION RATE; Α-Β-ISOCINCHONINE;

HYDROGENATION;

PYRUVIC ACID DERIVATIVE; TOLUENE;

ANALYTIC METHOD; ARTICLE; CATALYSIS; CATALYST; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CHIRALITY; CONCENTRATION (PARAMETERS); DESORPTION; ELECTROSPRAY MASS SPECTROMETRY; ENANTIOSELECTIVITY; HYDROGENATION; PRESSURE; REACTION ANALYSIS; SURFACE PROPERTY; TEMPERATURE DEPENDENCE;

EID: 15944422935     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcat.2004.11.013     Document Type: Article

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