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a) J. Baran, I. Bogdanska, D. Jan, L. Delaude, A. Demonceau, A. F. Noels, J. Mol. Catal. A 2002, 190, 109-116;
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Baran, J.1
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Demonceau, A.5
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b) D. Jan, L. Delaude, F. Simal, A. Demonceau, A. F. Noels, J. Organomet. Chem. 2000, 606, 55-64;
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Jan, D.1
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0001014389
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c) A. Hafner, A. Mühlebach, P. A. van der Schaaf, Angew. Chem. 1997, 109, 2213-2216; Angew. Chem. Int. Ed. Engl. 1997, 36, 2121-2124;
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Hafner, A.1
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0030727046
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c) A. Hafner, A. Mühlebach, P. A. van der Schaaf, Angew. Chem. 1997, 109, 2213-2216; Angew. Chem. Int. Ed. Engl. 1997, 36, 2121-2124;
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7
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d) A. Demonceau, A. W. Stumpf, E. Saive, A. F. Noels, Macromolecules 1997, 30, 3127-3136;
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Macromolecules
, vol.30
, pp. 3127-3136
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Demonceau, A.1
Stumpf, A.W.2
Saive, E.3
Noels, A.F.4
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8
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37049082609
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e) A. W. Stumpf, E. Saive, A. Demonceau, A. F. Noels, J. Chem. Soc. Chem. Commun. 1995, 1127-1128;
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, pp. 1127-1128
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Stumpf, A.W.1
Saive, E.2
Demonceau, A.3
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9
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0026939473
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f) A. Demonceau, A. F. Noels, E. Saive, A. J. Hubert, J. Mol. Catal. 1992, 76, 123-132.
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J. Mol. Catal.
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Demonceau, A.1
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10
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0034881934
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a) F. Simal, D. Jan, L. Delaude, A. Demonceau, M.-R. Spirlet, A. F. Noels, Can. J. Chem. 2001, 79, 529-535;
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Can. J. Chem.
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Simal, F.1
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Demonceau, A.4
Spirlet, M.-R.5
Noels, A.F.6
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11
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33846817763
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b) F. Simal, S. Sebille, L. Hallet, A. Demonceau, A. F. Noels, Macromol. Symp. 2000, 161, 73-85;
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Macromol. Symp.
, vol.161
, pp. 73-85
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Simal, F.1
Sebille, S.2
Hallet, L.3
Demonceau, A.4
Noels, A.F.5
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12
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15444377076
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(Ed.: K. Matyjaszwski), ACS Symposium Series 768, ACS, Washington, chap. 16
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c) F. Simal, D. Jan, A. Demonceau, A. F. Noels in Controlled/Living Radical Polymerization (Ed.: K. Matyjaszwski), ACS Symposium Series 768, ACS, Washington, 2000, chap. 16;
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(2000)
Controlled/Living Radical Polymerization
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Simal, F.1
Jan, D.2
Demonceau, A.3
Noels, A.F.4
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13
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0001475761
-
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d) F. Simal, A. Demonceau, A. F. Noels, Angew. Chem. 1999, 111, 559-562; Angew. Chem. Int. Ed. 1999, 38, 538-540.
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Angew. Chem.
, vol.111
, pp. 559-562
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Simal, F.1
Demonceau, A.2
Noels, A.F.3
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14
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0033558185
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d) F. Simal, A. Demonceau, A. F. Noels, Angew. Chem. 1999, 111, 559-562; Angew. Chem. Int. Ed. 1999, 38, 538-540.
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(1999)
Angew. Chem. Int. Ed.
, vol.38
, pp. 538-540
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15
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0033618392
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F. Simal, A. Demonceau, A. F. Noels, Tetrahedron Lett. 1999, 40, 5689-5693.
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(1999)
Tetrahedron Lett.
, vol.40
, pp. 5689-5693
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Simal, F.1
Demonceau, A.2
Noels, A.F.3
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16
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0035781198
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a) M. Kamigaito, T. Ando, M. Sawamoto, Chem. Rev. 2001, 101, 3689-3745;
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(2001)
Chem. Rev.
, vol.101
, pp. 3689-3745
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Kamigaito, M.1
Ando, T.2
Sawamoto, M.3
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19
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0001128645
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M. A. Bennett, T.-N. Huang, J. L. Latten, J. Organomet. Chem. 1984, 272, 189-205.
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J. Organomet. Chem.
, vol.272
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Bennett, M.A.1
Huang, T.-N.2
Latten, J.L.3
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21
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15444376566
-
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For some recent examples of Ru-catalyzed ATRP reactions see: a) T. Opstal, F. Verpoort, Angew. Chem. 2003, 115, 2982-2985; Angew. Chem. Int. Ed. 2003, 42, 2876-2879;
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Angew. Chem.
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, pp. 2982-2985
-
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Opstal, T.1
Verpoort, F.2
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22
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0038373084
-
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For some recent examples of Ru-catalyzed ATRP reactions see: a) T. Opstal, F. Verpoort, Angew. Chem. 2003, 115, 2982-2985; Angew. Chem. Int. Ed. 2003, 42, 2876-2879;
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(2003)
Angew. Chem. Int. Ed.
, vol.42
, pp. 2876-2879
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23
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0037590608
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b) L. Delaude, S. Delfosse, A. Richel, A. Demonceau, A. F. Noels, Chem. Commun. 2003, 1526-1527;
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Chem. Commun.
, pp. 1526-1527
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Delaude, L.1
Delfosse, S.2
Richel, A.3
Demonceau, A.4
Noels, A.F.5
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24
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0242438800
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c) T. Opstal, K. Couchez, F. Verpoort, Adv. Synth. Catal. 2003, 345, 393-401;
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Adv. Synth. Catal.
, vol.345
, pp. 393-401
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Opstal, T.1
Couchez, K.2
Verpoort, F.3
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25
-
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0037007911
-
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d) F. Simal, S. Delfosse, A. Demonceau, A. F. Noels, K. Denk, F. J. Kohl, T. Weskamp, W. A. Herrmann, Chem. Eur. J. 2002, 8, 3047-3052;
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Chem. Eur. J.
, vol.8
, pp. 3047-3052
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Simal, F.1
Delfosse, S.2
Demonceau, A.3
Noels, A.F.4
Denk, K.5
Kohl, F.J.6
Weskamp, T.7
Herrmann, W.A.8
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26
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0037190081
-
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e) M. Kamigaito, Y. Watanabe, T. Ando, M. Sawamoto, J. Am. Chem. Soc. 2002, 124, 9994-9995;
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J. Am. Chem. Soc.
, vol.124
, pp. 9994-9995
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Kamigaito, M.1
Watanabe, Y.2
Ando, T.3
Sawamoto, M.4
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29
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0037046332
-
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S. Hamasaki, M. Kamigaito, M. Sawamoto, Macromolecules 2002, 35, 2934-2940;
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(2002)
Macromolecules
, vol.35
, pp. 2934-2940
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Hamasaki, S.1
Kamigaito, M.2
Sawamoto, M.3
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30
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0035912976
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h) Y. Watanabe, T. Ando, M. Kamigaito, M. Sawamoto, Macromolecules 2001, 34, 4370-4374;
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(2001)
Macromolecules
, vol.34
, pp. 4370-4374
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Watanabe, Y.1
Ando, T.2
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Sawamoto, M.4
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31
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0034248079
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i) T. Ando, M. Kamigaito, M. Sawamoto, Macromolecules 2000, 33, 5825-5829.
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(2000)
Macromolecules
, vol.33
, pp. 5825-5829
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Ando, T.1
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Sawamoto, M.3
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32
-
-
0032595999
-
-
4] was reported to catalyze the controlled polymerization of MMA at 30 °C, but significantly higher catalyst concentrations (MMA/Ru = 200:1) and reaction times (300 h) were required: H. Takahashi, T. Ando, M. Kamigaito, M. Sawamoto, Macromolecules 1999, 32, 6455-6461.
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Macromolecules
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, pp. 6455-6461
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Takahashi, H.1
Ando, T.2
Kamigaito, M.3
Sawamoto, M.4
-
33
-
-
15444380297
-
-
note
-
Generally, values below 1.0 are observed. Currently, we have no explanation for this discrepancy.
-
-
-
-
34
-
-
15444380796
-
-
note
-
The initial TOF was calculated from the conversion of MMA per ruthenium atom after 6 h as determined by gas chromatography.
-
-
-
-
35
-
-
4444355976
-
-
Some copper complexes are also able to catalyze the ATRP of MMA at ambient temperatures, but the catalyst concentrations are generally higher (MMA/Cus ≈ 100:1). See for example: a) D. P. Chatterjee, U. Chatterjee, B. M. Mandal, J. Polym. Sci. Part A 2004, 42, 4132-4142;
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Chatterjee, D.P.1
Chatterjee, U.2
Mandal, B.M.3
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36
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0032140124
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b) D. M. Haddleton, D. Kukulj, D. J. Duncalf, A. M. Heming, A. J. Shooter, Macromolecules 1998, 31, 5201-5205.
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Macromolecules
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, pp. 5201-5205
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Haddleton, D.M.1
Kukulj, D.2
Duncalf, D.J.3
Heming, A.M.4
Shooter, A.J.5
-
37
-
-
0036828318
-
-
Bimodal GPC profiles have previously been observed in ATRP reactions with ruthenium catalysts and butyl acrylate as the monomer: O. Tutusaus, S. Delfosse, F. Simal, A. Demonceau, A. F. Noels, R. Núñez, C. Viñas, F. Teixidor, Inorg. Chem. Commun. 2002, 5, 941-945.
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Inorg. Chem. Commun.
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Tutusaus, O.1
Delfosse, S.2
Simal, F.3
Demonceau, A.4
Noels, A.F.5
Núñez, R.6
Viñas, C.7
Teixidor, F.8
-
38
-
-
15444371814
-
-
note
-
3.
-
-
-
-
39
-
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3342889513
-
-
a) B. T. Lee, T. O. Schrader, B. Martín-Matute, C. R. Kauffman, P. Zhang, M. L. Snapper, Tetrahedron 2004, 60, 7391-7396;
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Tetrahedron
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Lee, B.T.1
Schrader, T.O.2
Martín-Matute, B.3
Kauffman, C.R.4
Zhang, P.5
Snapper, M.L.6
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40
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0033593413
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b) J. A. Tallarico, L. M. Malnick, M. L. Snapper, J. Org. Chem. 1999, 64, 344-345.
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J. Org. Chem.
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Tallarico, J.A.1
Malnick, L.M.2
Snapper, M.L.3
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41
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0034934284
-
-
2] (TON = 207, 85°C, 24 h; Cp* = pentamethylcyclopentadienyl): F. Simal, L. Wlodarczak, A. Demonceau, A. F. Noels, Eur. J. Org. Chem. 2001, 2689-2695.
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Eur. J. Org. Chem.
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Simal, F.1
Wlodarczak, L.2
Demonceau, A.3
Noels, A.F.4
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42
-
-
0004150157
-
-
University of Göttingen, Göttingen (Germany)
-
-3. Structure solution and refinement by SHELX97 (G. M. Sheldrick, SHELX97, Programs for Crystal Structure Analysis, University of Göttingen, Göttingen (Germany), 1998). H atoms were placed in calculated positions by using the riding model. CCDC-247810 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
-
(1998)
SHELX97, Programs for Crystal Structure Analysis
-
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Sheldrick, G.M.1
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43
-
-
4043051503
-
-
For some recent publications about mixed, halogeno-bridged complexes see: a) S. Gauthier, R. Scopelliti, K. Severin Organometallics 2004, 23, 3769-3771;
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(2004)
Organometallics
, vol.23
, pp. 3769-3771
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Gauthier, S.1
Scopelliti, R.2
Severin, K.3
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44
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3042570470
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b) S. Gauthier, L. Quebatte, R. Scopelliti, K. Severin, Chem. Eur. J. 2004, 10, 2811-2821;
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Chem. Eur. J.
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Gauthier, S.1
Quebatte, L.2
Scopelliti, R.3
Severin, K.4
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45
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2342485667
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c) S. Gauthier, L. Quebatte, R. Scopelliti, K. Severin, Inorg. Chem. Commun. 2004, 7, 708-712;
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Inorg. Chem. Commun.
, vol.7
, pp. 708-712
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Gauthier, S.1
Quebatte, L.2
Scopelliti, R.3
Severin, K.4
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46
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1642426891
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and references therein
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d) K. Severin, Chem. Eur. J. 2002, 8, 1514-1518, and references therein.
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Chem. Eur. J.
, vol.8
, pp. 1514-1518
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Severin, K.1
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a) L. Bonomo, C. Stern, E. Solari, R. Scopelliti, C. Floriani, Angew. Chem. 2001, 113, 1497-1500; Angew. Chem. Int. Ed. 2001, 40, 1449-1452;
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Bonomo, L.1
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a) L. Bonomo, C. Stern, E. Solari, R. Scopelliti, C. Floriani, Angew. Chem. 2001, 113, 1497-1500; Angew. Chem. Int. Ed. 2001, 40, 1449-1452;
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b) V. Rodriguez, I. Atheaux, B. Donnadieu, S. Sabo-Etienne, B. Chaudret, Organometallics 2000, 19, 2916-2926;
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Rodriguez, V.1
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Organometallics
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Abdur-Rashid, K.1
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Abbenhuis, R.A.T.M.1
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Veldman, N.5
Spek, A.L.6
Van Koten, G.7
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53
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For highly active ATRA catalysts see reference [14] and: a) L. Quebatte, R. Scopelliti, K. Severin, Angew. Chem. 2004, 116, 1546-1550;
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Angew. Chem. Int. Ed. 2004, 43, 1520-1524;
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55
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b) O. Tutusaus, C. Viñas, R. Núñez, F. Teixidor, A. Demonceau, S. Delfosse, A. F. Noels, I. Mata, E. Molins, J. Am. Chem. Soc. 2003, 125, 11830-11831;
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Delfosse, S.6
Noels, A.F.7
Mata, I.8
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e) O. Tutusaus, S. Delfosse, A. Demonceau, A. F. Noels, C. Viñas, F. Teixidor, Tetrahedron Lett. 2003, 44, 8421-8425;
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f) R. A. Gossage, L. A. Van de Kuil, G. van Koten, Acc. Chem. Res. 1998, 31, 423-431.
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0011907481
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3 shows similar reactivity: R. Appel, Inorg. Synth. 1986, 24, 107-109.
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Appel, R.1
|