Mechanism of addition of organocuprates to alkynyl carbonyl compounds. A mechanistic bridge between carbocupration and conjugate addition

Organometallics

Volumn 23, Issue 5, 2004, Pages 1081-1088

  Mori, Seiji ^a   Nakamura, Eiichi ^b   Morokuma, Keiji ^c  

^a IBARAKI UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CALCULATIONS; ESTERS; INFRARED SPECTROSCOPY; LOW TEMPERATURE EFFECTS; MIXTURES; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; THERMODYNAMIC STABILITY;

ALKYNYL CARBONYL COMPOUNDS; CARBOCUPRATION; CONJUGATE ADDITION; LITHIUM DIALKYLCUPRATE; MECHANISTIC BRIDGE; ORGANOCUPRATES; PRODUCT MIXTURE; PUTATIVE PRODUCTS;

COPPER COMPOUNDS;

EID: 1542542329     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034339g     Document Type: Article

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