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Volumn 63, Issue 19, 1998, Pages 6650-6655

Mild and Efficient Flavin-Catalyzed H2O2 Oxidation of Tertiar Amines to Amine N-Oxides

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EID: 1542501014     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo980926d     Document Type: Article
Times cited : (116)

References (88)
  • 60
    • 0027931794 scopus 로고
    • In one case the flavin system has been used to induce a radical chain reaction: Mager, H. I. X.; Tu, S.-C. Tetrahedron 1994, 50, 6759.
    • (1994) Tetrahedron , vol.50 , pp. 6759
    • Mager, H.I.X.1    Tu, S.-C.2
  • 65
    • 0001803662 scopus 로고
    • Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, U.K.
    • Hutchins, R. O.; Hutchins, M. K. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon Press: Oxford, U.K., 1991; Vol. 8, p 25.
    • (1991) Comprehensive Organic Synthesis , vol.8 , pp. 25
    • Hutchins, R.O.1    Hutchins, M.K.2
  • 66
    • 1542713811 scopus 로고    scopus 로고
    • When the reaction was performed under argon, the solubility of the catalyst was low, and no conversion could be seen. However, upon inlet of molecular oxygen the catalyst immediately dissolved, and a rapid oxidation of the amine was observed
    • When the reaction was performed under argon, the solubility of the catalyst was low, and no conversion could be seen. However, upon inlet of molecular oxygen the catalyst immediately dissolved, and a rapid oxidation of the amine was observed.
  • 72
    • 1542608829 scopus 로고    scopus 로고
    • Murahashi et al. describe the formation of a cationic flavin complex as the rate-determining step in a detailed mechanistic study for the flavin-catalyzed oxidation of methyl phenyl sulfide. See ref 37
    • Murahashi et al. describe the formation of a cationic flavin complex as the rate-determining step in a detailed mechanistic study for the flavin-catalyzed oxidation of methyl phenyl sulfide. See ref 37.
  • 73
    • 85088541980 scopus 로고    scopus 로고
    • 4 (0.66 mL) was used to give the same total volume
    • 4 (0.66 mL) was used to give the same total volume.
  • 75
    • 1542713848 scopus 로고    scopus 로고
    • In the flavin-catalyzed oxidation of dibutyl sulfide a TON of 99 has been reported, See ref 37
    • In the flavin-catalyzed oxidation of dibutyl sulfide a TON of 99 has been reported, See ref 37.
  • 81
    • 0000201638 scopus 로고
    • 5-ethyl group were found to be almost identical to what has been reported for the similar compound 5-ethyl-3,7,8,10-tetramethyl-1,5-dihydroisoalloxazine: van Schagen, C. G.; Müller, F. Helv. Chim. Acta 1980, 63, 2187.
    • (1980) Helv. Chim. Acta , vol.63 , pp. 2187
    • Van Schagen, C.G.1    Müller, F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.