Oxidation of N-heterocycles by H2O2 catalyzed by a Mn-porphyrin: An easy access to N-oxides under mild conditions

Synthesis

Volumn , Issue 12, 1997, Pages 1387-1388

  Thellend, A ^a   Battioni, P ^a   Sanderson, W ^b   Mansuy, D ^a  

^a UNIVERSITÉ PARIS DESCARTES   (France)

^b Solvay Interox   (United Kingdom)

Author keywords

Heteroaromatic N oxides; Hydrogen peroxide; Mn porphyrin; Oxidation

Indexed keywords

AMINE; HETEROCYCLIC COMPOUND; HYDROGEN PEROXIDE; MANGANESE; OXIDIZING AGENT; PORPHYRIN DERIVATIVE;

ARTICLE; CATALYST; CONTROLLED STUDY; DRUG SYNTHESIS; NONHUMAN; OXIDATION;

EID: 0031452606     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1997-1383     Document Type: Article

References (13)

1. Boekelheide, V.; Linn, W. J. J. Am. Chem. Soc. 1954, 76, 1286.
2. Hardegger, E.; Nikel, E. Helv. Chem. Acta 1957, 2428.
3. Taylor, E. C. Jr.; Crovetti, A. J. Org. Synth., Collective Volume 1963, 4, 704.
4. Mosher, H. S.; Turner, L., Carlsmith, A. Org. Synth., Collective Volume 1963, 4, 828.
5. For review, Albini, P. Heterocyclic N-Oxides, CRC Press:Boca Raton, Fl, 1991, 31-41.
6. Katritzky, A. R.; Lagowski, X. Chemistry of the Heterocylic N-Oxides, Acadamic:, N. Y., 1971, 21-72, 539-542.
7. Brougham, P.; Cooper, M.S.; Cummerson, D.A.; Heaney, H.; Thompson, N. Synthesis 1987, 1015.
8. Murray, R. W.; Jeyaraman, R. J. Org. Chem. 1985, 50, 2847.
9. Payne, G. B.; Deming, P. H.; Williams, P. H. J. Org. Chem. 1961, 26, 659.
10. Chivers, G. E.; Suschitzky, H. J. Chem. Soc. C, 1971, 2867.
11. Robke, J. G.; Behrman, E. J. J. Chem. Res. (S), 1993, 412.
12. Battioni, P.; Renaud, J. P.; Bartoli, J. F.; Mansuy, D.; Fort, M.; Reina-Artiles, M. J. Am. Chem. Soc., 1988, 110, 8462.
13. Thellend, A.; Battioni, P.; Mansuy, D. J. Chem. Soc. Chem. Comm. 1994, 1035.