Elucidating the role of silica surfaces in the ring-opening polymerization of lactide: Catalytic behavior of silica-immobilized zinc β-diiminate complexes

Journal of Catalysis

Volumn 222, Issue 2, 2004, Pages 558-564

  Yu, Kunquan ^a   Jones, Christopher W ^a  

^a Georgia Institute of Technology   (United States)

Author keywords

Chain transfer; Lactide; Polymerization; Porous silica; Ring opening; Zn BDI

Indexed keywords

HYDROXYL GROUP; IMINE; LACTIDE; OLIGOMER; POLYLACTIC ACID; POLYMER; SILANE DERIVATIVE; SILANOL; SILICATE; SILICON DIOXIDE; UNCLASSIFIED DRUG; ZINC BETA DIIMINATE COMPLEX;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; DISPERSION; IMMOBILIZATION; MODULATION; MOLECULAR WEIGHT; POLYMERIZATION; POROSITY; RING OPENING;

EID: 1542298160     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jcat.2003.12.004     Document Type: Article

References (23)

1. Drumright R.E., Gruber P.R., Henton D.E. Adv. Mater. 12:2000;1841.
2. O'Keefe B.J., Monnier S.M., Hillmyer M.A., Tolman W.B. J. Am. Chem. Soc. 123:2001;339.
3. Chisholm M.H., Gallucci J., Phomphrai K. Chem. Commun. 2003;48.
4. Dobrzynski P., Kasperczyk J., Janeczek H., Bero M. Macromolecules. 34:2001;5090.
5. Tortosa K., Hamaide T., Boisson C., Spitz R. Macromol. Chem. Phys. 202:2001;1156.
6. Miola-Delaite C., Colomb E., Pollet E., Hamaide T. Macromol. Symp. 153:2000;275.
7. Colomb E., Novat C., Hamaide T. Macromol. Chem. Phys. 200:1999;2525.
8. Kageyama K., Ogino S.-I., Aida T., Tatsumi T. Macromolecules. 31:1998;4069.
9. Kadokawa J., Iwasaki Y., Tagaya H. Green Chem. 4:2002;14.
10. Abdel-Fattah T., Pinnavaia T.J. Chem. Commun. 1996;665.
11. Zhao D., Hou Q., Feng J., Chmelka B.F., Stucky G.D. J. Am. Chem. Soc. 120:1998;6024.
12. Yu K., Jones C.W. Organometallics. 22:2003;2571.
13. Cheng M., Attygalle A.B., Lobkovsky E.B., Coates G.W. J. Am. Chem. Soc. 121:1999;11583.
14. Chamberlain B.M., Cheng M., Moore D.R., Ovitt T.M., Lobkovsky E.B., Coates G.W. J. Am. Chem. Soc. 123:2001;3229.
15. Chisholm M.H., Huffman J.C., Phomphrai K. J. Chem. Soc., Dalton Trans. 2001;222.
16. Cheng M., Lobkovsky B.M., Coates G.W. J. Am. Chem. Soc. 120:1998;11018.
17. Cheng M., Darling N.A., Lobkovsky E.B., Coates G.W. Chem. Commun. 2000;2007.
18. Cheng M., Moore D.R., Reczek J.J., Chamberlain B.M., Lobkovsky E.B., Coates G.W. J. Am. Chem. Soc. 123:2001;8738.
19. Moore D.R., Cheng M., Lobkovsky E.B., Coates G.W. J. Am. Chem. Soc. 125:2003;11911.
20. K. Yu, C.W. Jones, unpublished results
21. Rieth L.R., Moore D.R., Lobkovsky E.B., Coates G.W. J. Am. Chem. Soc. 124:2002;15239.
22. Chisholm M.H., Gallucci J., Phomphrai K. Inorg. Chem. 41:2002;2785.
23. Chisholm M.H., Huffman J.C., Phomphrai K. J. Chem. Soc., Dalton Trans. 2001;222.