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For reviews of persistent triplet carbenes, see: (a) Tomioka, H. Acc. Chem. Res. 1997, 30, 315. (b) Tomioka, H. In Advances in Carbene Chemistry; Brinker, U., Ed.; JAI Press: Greenwich, CT, 1998; Vol. 2. pp 175-214. (c) Tomioka, H. In Advances in Strained and Interesting Organic Molecules; Halton, B., Ed.; JAI Press: Greenwich, CT, 2000; Vol. 8, pp 83-112. (d) Tomioka, H. In Carbene Chemistry; Bertrand, G., Ed.; Fontis Media, S. A.; Lausanne, 2002; pp 103-152.
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For reviews of persistent triplet carbenes, see: (a) Tomioka, H. Acc. Chem. Res. 1997, 30, 315. (b) Tomioka, H. In Advances in Carbene Chemistry; Brinker, U., Ed.; JAI Press: Greenwich, CT, 1998; Vol. 2. pp 175-214. (c) Tomioka, H. In Advances in Strained and Interesting Organic Molecules; Halton, B., Ed.; JAI Press: Greenwich, CT, 2000; Vol. 8, pp 83-112. (d) Tomioka, H. In Carbene Chemistry; Bertrand, G., Ed.; Fontis Media, S. A.; Lausanne, 2002; pp 103-152.
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For reviews of persistent triplet carbenes, see: (a) Tomioka, H. Acc. Chem. Res. 1997, 30, 315. (b) Tomioka, H. In Advances in Carbene Chemistry; Brinker, U., Ed.; JAI Press: Greenwich, CT, 1998; Vol. 2. pp 175-214. (c) Tomioka, H. In Advances in Strained and Interesting Organic Molecules; Halton, B., Ed.; JAI Press: Greenwich, CT, 2000; Vol. 8, pp 83-112. (d) Tomioka, H. In Carbene Chemistry; Bertrand, G., Ed.; Fontis Media, S. A.; Lausanne, 2002; pp 103-152.
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For reviews of persistent triplet carbenes, see: (a) Tomioka, H. Acc. Chem. Res. 1997, 30, 315. (b) Tomioka, H. In Advances in Carbene Chemistry; Brinker, U., Ed.; JAI Press: Greenwich, CT, 1998; Vol. 2. pp 175-214. (c) Tomioka, H. In Advances in Strained and Interesting Organic Molecules; Halton, B., Ed.; JAI Press: Greenwich, CT, 2000; Vol. 8, pp 83-112. (d) Tomioka, H. In Carbene Chemistry; Bertrand, G., Ed.; Fontis Media, S. A.; Lausanne, 2002; pp 103-152.
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note
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Because of inherent instable nature of triplet di(4-pyridyl)carbenes, a viscous matrix such as propanetriol triacetate was required to obtain ESR signal at 77 K.
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23
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0001151072
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For reviews of the EPR and UV/vis spectra of triplet carbenes, see: (a) Sander, W.; Bucher, G.; Wierlacher, S. Chem. Rev. 1993, 93, 1583. (b) Trozzolo, A. M.; Wasserman, E. In Carbenes; Jones, M., Jr., Moss, R. A., Eds.; Wiley: New York, 1975; Vol. 2. pp 185-206.
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24
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0001328124
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Jones, M., Jr., Moss, R. A., Eds.; Wiley: New York
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For reviews of the EPR and UV/vis spectra of triplet carbenes, see: (a) Sander, W.; Bucher, G.; Wierlacher, S. Chem. Rev. 1993, 93, 1583. (b) Trozzolo, A. M.; Wasserman, E. In Carbenes; Jones, M., Jr., Moss, R. A., Eds.; Wiley: New York, 1975; Vol. 2. pp 185-206.
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Trozzolo, A.M.1
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Tomioka, H.; Hirai, K.; Fujii, C. Acta Chim. Scand. 1993, 46, 680.
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(b) Tomioka, H.; Hirai, K.; Nakayama, T. J. Am. Chem. Soc. 1993, 115, 1285.
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For details of our LFP equipments, see; Tomioka, H.; Okada, H.; Watanabe, T.; Banno, K.; Komatsu, K.; Hirai, K. J. Am. Chem. Soc. 1997, 119, 1582.
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Carbonyl oxide formation has been used to monitored carbenes that are transparent in the useful UV region. See, for instance; Morgan, S.; Platz, M. S.; Jones, M., Jr.; Myers, D. R. J. Org. Chem. 1991, 56, 1351.
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