The Metal-Dependent Regiospecificity in the Exchange Coupling of Manganese(II), Copper(II), and Chromium (III) Ions with the Aminoxyl Radical Attached as a Substituent on the Aromatic Base Ligands

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 334, Issue , 1999, Pages 437-457

  Iwamura, Hiizu ^a   Koga, Noboru ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

Aminoxyl radicals; Copper(II) complexes; Exchange coupling; Free radicals; Hybrid spin systems; Manganese(II) complexes

Indexed keywords

EID: 0041725535     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259908023341     Document Type: Article

References (52)

1. H.S. Longuet-Higgins, J. Phys. Org. Chem., 18, 265 (1950); M. S. Platz, in Diradicals, edited by W. T. Borden (Wiley, New York, 1982), Chapt. 5.
2. H.S. Longuet-Higgins, J. Phys. Org. Chem., 18, 265 (1950); M. S. Platz, in Diradicals, edited by W. T. Borden (Wiley, New York, 1982), Chapt. 5.
3. (a) A.M. Trozzolo, R.W. Murray, G. Smolinsky, W.A. Yager, and E. Wasserman, J. Am. Chem. Soc., 85, 2526 (1963)
4. (b) E. Wasserman, R. W. Murray, W. A. Yager, A. M. Trozzolo, and G. Smolinsky, J. Am. Chem. Soc., 89, 5076 (1967)
5. (c) N. Malaga, Theor. Chem. Acta, 10, 372 (1968)
6. (d) K. Itoh, Chem. Phys/Lett., 1,235 (1967).
7. (a) I. Fujita, Y. Teki, T. Takui, T. Kinoshita, K. Itoh, F. Miko, Y. Sawaki, H. Iwamura, A. Izuoka, and T. Sugawara, J. Am. Chem. Soc., 112, 4074 (1990)
8. (b) N. Nakamura, K. Inoue, H. Iwamura, T. Fujioka, and Y Sawaki, J. Am. Chem. Soc., 114, 1484 (1992)
9. (c) K. Matsuda, N. Nakamura, K. Takahashi, K. Inoue, N. Koga, and H. Iwamura, J. Am. Chem. Soc., 117, 5550 (1995).
10. (a) S. Nakazono, N. Koga, and H. Iwamura, Angew. Chem., Int. Ed. Engl., 37, 1550 (1998)
11. (b) R. Chiarelli, S. Ganbarelli, and A. Rassat, Mol. Cryst. Liq. Cryst., 108, 455 (1997)
12. (c) A. Calder, A. R. Forrester, P. G. James, and G. R. Luckhurst, J. Am. Chem. Soc., 91, 3724 (1969)
13. (d) K. Mukai, H. Nagai, and K. Ishizu, Bull. Chem. Soc. Jpn., 48, 2381 (1975)
14. (e) T. Ishida and H Iwamura, J. Am. Chem. Soc., 113, 4238 (1991)
15. (f) F. Kanno, K. Inoue, N. Koga, and H. Iwamura, J. Phys. Chem., 97, 13267 (1993).
16. (a) H.M. McConnell, J. Chem. Phys., 39, 1910 (1963)
17. (b) H. Iwamura Adv. Phys. Org. Chem., 26, 179 (1990)
18. (c) D.A. Dougherty, Acc. Chem. Res., 24, 88 (1991)
19. (d) A. Rajca, Chem. Rev., 94, 871 (1994).
20. (a) N. Nakamura, K. Inoue, and H. Iwamura, Angew. Chem., Int. Ed. Engl., 32, 872 (1993)
21. (b) K. Matsuda, N. Nakamura, K. Inoue, N. Koga, and H. Iwamura, Bull. Chem. Soc. Jpn., 69, 1483 (1996).
22. K. Matsuda, N. Nakamura, K. Inoue, N. Koga, and H. Iwamura, Chem., Eur. J., 2, 259 (1996).
23. (a) J.F. Nierengarten, C.O. Dietrich-Buchecker, and J.-P. Sauvage, J. Am. Chem. Soc., 116, 375 (1994)
24. (b) J.-M. Lehn, Supramolerular Chemistry,(VCH Publishers, 1995)
25. (c) M. Fujita, F Ibukuro, K. Yamaguchi, and K. Ogura, J. Am. Chem. Soc., 117,4175 (1995)
26. (d) J.F. Nierengarten, C.O. Dietrich-Buchecker, D.B. Amabilino, and J.F. Stoddart, Chem. Rev., 95, 2125 (1995)
27. (e) P. Stang and B. Olenyuk, Angew. Chem., Int. Ed. Engl., 35, 732 (1996).
28. (a) O. Kahn, Molecular Magnetism(VCH Publishers, Inc., Weinheim, 1993)
29. (b) D. Gatteschi, Adv. Mater., 6, 635 (1994)
30. (c) J. S. Miller and A. J. Epstein, Angew. Chem., Int. Ed. Engl., 33, 385 (1994)
31. (d) J.S. Miller and A.J. Epstein, Chem & Eng News,October 2, 30 (1995)
32. (e) O. Kahn, Magnetism: A Supramolecular Function, NATO ASI Series C (Kluwer, Dordrecht, 1996)
33. (f) M.M. Turnbull, T. Sugimoto, and L.K. Thompson, Eds. Molecule-based magnetic materials. In ACS Symposium Series 644. (Washington: ACS, 1996)
34. (g) D. Gatteschi, Curr. Opin. Solid State Mater. Sci., 1,192 (1996).
35. (a) A. Caneschi, D. Gattesch, R. Sessoli, and P. Rey, Acc. Chem. Res., 22, 392 (1989)
36. (b) A. Caneschi, D. Gatteschi, and P. Rey, Progr. Inorg. Chem., 39, 3936 (1991)
37. (c) A.B. Burdukov, V.I. Ovcharenko, V.M. Ikorski, N.V. Pervukhina, N.V. Podberezskaya, I.A. Grigor'ev, S.V. Larionov, and L.B. Volodarsky, Inorg. Chem., 30, 972 (1991)
38. (d) A. Caneschi, P. Chiesi, L. David, F. Ferraro, D. Gatteschi, and R. Sessoli, Inorg. Chem., 32, 1445 (1993)
39. (e) H.O. Stumpf, L. Ouahab, Y. Pei, D. Grandjcan, and O. Kahn, Science, 261, 447 (1993)
40. (f) L.B. Volodarsky, V.A. Reznikov, and V.I. Ovcharenko. Synthetic Chemistry of Stable Nitroxides, (CRC Press, Boca Raton, 1994) Chapt. 4.
41. (a) K. Inoue and H. Iwamura, J. Am. Chem. Soc., 116, 3173 (1994)
42. (b) T. Mitsumori, K. Inoue, N. Koga, and H. Iwamura, J. Am. Chem. Soc., 117, 2467 (1995)
43. (c) K. Inoue, T. Hayamizu, H. Iwamura, D. Hashizume, and Y. Ohashi, J. Am. Chem. Soc., 118, 1803 (1996)
44. (d) D. C. Oniciu, K. Matsuda, and H. Iwamura, J. Chem. Soc. Perkin II, 907 (1996)
45. (e) H. Iwamura, K. Inoue, and T. Hayamixu, Pure Appl. Chem., 68, 243, (1996)..
46. Y. Ishimaru, M. Kitano, H. Kumada, N. Koga, and H. Iwamura, Inorg. Chem., 37, 2273 (1998).
47. D. Luneau, P. Rey, J. Laugier, P. Fries, A. Caneschi, D. Gatteschi, and R. Sessoli, J. Am. Chem. Soc. 113, 1245 (1991).
48. (a) M. Kitano, Y. Ishimaru, K. Inoue, N. Koga, and H. Iwumura, Inorg. Chem., 33, 6012 (1994)
49. (b) M. Kitano, N. Koga, and H. Iwamura, J. Chem. Soc., Chem. Comm., 447 (1994).
50. Y. Ishimaru, K. Inoue, N. Koga, and H. Iwamura, Chem. Lett., 1693 (1994).
51. P. Rabu, M Drillon, H. Iwamura, G. Görlitz, T. Itoh, K. Matsuda, and K. Inoue, to be published elsewhere.
52. We thank Prof. K. Morokuma of Emory Univ. for stimulating discussion concerning this mechanism.