Heterospin systems consisting of organic free radicals and magnetic metal ions by self-assembling strategy. Diazodi(4-pyridyl)methane as photo-responsive ligands for metal-carbene-based heterospin magnets

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 305, Issue , 1997, Pages 415-424

  Koga, Noboru ^a   Iwamura, Hiizu ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; FREE RADICALS; IONS; IRRADIATION; ORGANIC COMPOUNDS; PHOTOCHEMICAL REACTIONS; PHOTOLYSIS;

ANTIFERROMAGNETIC INTERACTION; FERRIMAGNETIC CHAIN; FERROMAGNETIC INTERACTION; HETEROSPIN SYSTEM; SELF ASSEMBLING STRATEGY;

MAGNETIC MATERIALS;

EID: 0031358596     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259708045076     Document Type: Article

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34. W = 0.026.
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36. BT). The other symbols have their usual meanings.
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38. For a strategy of using organic conjugated di-and trinitroxide radicals as bridging ligands for magnetic metal ions and constructing heterospin systems having tailored crystal and molecular structures, see: H. Iwamura, K. Inoue, and T. Hayamizu, Pure Appl. Chem. 1996, 68, 243-252. See also refs. 9i and 9j for one-dimensional, ref. 9h and K. Inoue and H.Inoue, Adv. Mater. 1996, 8, 73-76 for two-dimensional, and K. Inoue, T. Hayamizu, H. Iwamura, D. Hashizume, and Y. Ohashi, J. Am. Chem. Soc. 1996, 118, 1803-1804 for three-dimensional structures.
39. For a strategy of using organic conjugated di-and trinitroxide radicals as bridging ligands for magnetic metal ions and constructing heterospin systems having tailored crystal and molecular structures, see: H. Iwamura, K. Inoue, and T. Hayamizu, Pure Appl. Chem. 1996, 68, 243-252. See also refs. 9i and 9j for one-dimensional, ref. 9h and K. Inoue and H.Inoue, Adv. Mater. 1996, 8, 73-76 for two-dimensional, and K. Inoue, T. Hayamizu, H. Iwamura, D. Hashizume, and Y. Ohashi, J. Am. Chem. Soc. 1996, 118, 1803-1804 for three-dimensional structures.
40. For practical applications, sensitivity to oxygen and thermal reactivity of the triplet carbene centers may pose problems and should be overcome.