Effect of pH on the final connectivity distribution of the silicon atoms in the Stöber particles

Journal of Sol-Gel Science and Technology

Volumn 33, Issue 3, 2005, Pages 255-260

  Lee, Kangtaek ^a   McCormick, Alon ^b  

^a Yonsei University   (South Korea)

^b University of Minnesota   (United States)

Author keywords

29Si MAS NMR; Condensation kinetics; First shell substitution effect; pH; St ber particles

Indexed keywords

AMMONIA; CONDENSATION; HYDROLYSIS; MATHEMATICAL MODELS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH EFFECTS; PRECIPITATION (CHEMICAL); RATE CONSTANTS;

29SIMAS-NMR; CONDENSATION KINETICS; FIRST SHELL SUBSTITUTION EFFECT; STOB̈ER PARTICLES;

SILICON;

EID: 14844339087     PISSN: 09280707     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10971-005-6374-y     Document Type: Article

References (22)

1. Y.A. Vlasvo, X.-Z. Bo, J.C. Sturm, and D.J. Norris, Nature 414, 289 (2001).
2. H. Goto, T. Isobe, and M. Senna, J. Nanoparticle Res. 1, 205 (1999).
3. Y.J. Kim and L.F. Francis, J. Am. Ceram. Soc. 76, 737 (1993).
4. W. Stöber, A. Fink, and E. Bohn, J. Colloid Interface Sci. 26, 62 (1968).
5. T. Matsoukas and E. Gulari, J. Colloid Interface Sci. 132, 13 (1989).
6. G.H. Bogush and C.F. Zukoski, J. Colloid Interface Sci. 142, 1 (1991).
7. M.T. Harris, Ultrafine Precursor Powders by Homogeneous Precipitation and Electrodispersion, Ph.D. dissertation, Univ. of Tennessee, 1992.
8. A. van Blaaderen and A.P.M. Kentgens, J. Non-Cryst. Solids 149, 161 (1992).
9. K. Lee, J.-L. Look, M.T. Harris, and A.V. McCormick, J. Colloid. Interface Sci. 194, 78 (1997).
10. J. Sanchez, Kinetics and Models of Silicon Alkoxide Polymerization, Ph.D. Dissertation, University of Minnesota, 1994.
11. L. Malier, F. Devreux, F. Chaput, J.P. Boilot, and M.A.V. Axelos, J. Non-Cryst. Solids 147/148, 686 (1992).
12. L. Malier, F. Devreux, F. Chaput, and J.P. Boilot, in Chemical Processing of Advanced Materials, edited by L.L. Hench and J.K. West (John Wiley & Sons, Inc., 1992), p. 59.
13. J. Sanchez, S.E. Rankin, and A.V. McCormick, Ind. Eng. Chem. Res. 35, 117 (1996).
14. J.C. Pouxviel and J.P. Boilot, J. Non-Cryst. Solids 94, 374 (1987).
15. C.J. Brinker and G.W. Scherer, Sol-Gel Science (Academic Press, San Diego, 1990).
16. D.H. Doughty, R.A. Assink, and B.D. Kay, Adv. Chem. 224, 241 (1990).
17. M. Kallala, R. Jullien, and B. Cabane, J. Phys. II France 2, 7 (1992).
18. D.W. Schaefer and K.D. Keefer, in Better Ceramics Through Chemistry, edited by C.J. Brinker, D.E. Clark, and D.R. Ulrich (Material Research Society, Pittsburgh, 1984), p. 1.
19. C.J. Brinker, K.D. Keefer, D.W. Schaefer, R.A. Assink, B.D. Kay, and C.S. Ashley, J. Non-Cryst. Solids 63, 45 (1984).
20. C.J. Brinker and R.A. Assink, J. Non-Cryst. Solids 111, 48 (1989).
21. K.A.M. Thakur, R.T. Kean, J.M. Zupfer, N.U. Buehler, M.A. Doscotch, and E.J. Munson, Macromolecules 29, 8844 (1996).
22. L.V. Ng and A.V. McCormick, J. Phys. Chem. 100, 12517 (1996).