Acidic sol-gel polymerization of TEOS: Effect of solution composition on cyclization and bimolecular condensation rates

Journal of Physical Chemistry

Volumn 100, Issue 30, 1996, Pages 12517-12531

  Ng, Li Voon ^a   McCormick, Alon V ^a  

^a UNIVERSITY OF MINNESOTA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITION EFFECTS; ISOMERIZATION; PH EFFECTS; POLYMERIZATION; REACTION KINETICS; SOL-GELS; SOLUTIONS;

BIMOLECULAR CONDENSATION RATES; CYCLIZATION; TETRAETHOXYSILANES;

SILANES;

EID: 0030197883     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp960089o     Document Type: Article

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80. 53 systems, but little appreciable depolymerization has been observed up to substantial conversion for ethoxy systems.