A μ4-Peroxo Complex of Antimony: Synthesis and Structure of (o-Tol2SbO)4(O2)2

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 6, 1997, Pages 615-617

  Breunig, Hans Joachim ^a   Krüger, Tamara ^a   Lork, Enno ^a  

^a UNIVERSITY OF BREMEN   (Germany)

Author keywords

Antimony; Main group elements; Peroxides

Indexed keywords

EID: 0030985638     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199706151     Document Type: Article

References (14)

1. A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon press, Oxford, 1984.
2. W. Micklitz, S. G. Bott, J. G. Bentsen, S. J. Lippard, J. Am. Chem. Soc. 1989, 111, 372-374.
3. R. Stomberg, L. Trysberg, I. Larking, Acta Chem. Scand. 1970, 24, 2678-2679.
4. J. Dahlmann, A. Rieche, Chem. Ber. 1967, 100, 1544-1549.
5. Z. A. Starikova, T. M. Shchegolova, V. K. Trunov, I. E. Pokrovskaya, Kristallografiya 1978, 23, 769-773; Sov. Phys. Crystallogr. (Engl. Transl.) 1978, 23, 547-549.
6. Z. A. Starikova, T. M. Shchegolova, V. K. Trunov, I. E. Pokrovskaya, Kristallografiya 1978, 23, 769-773; Sov. Phys. Crystallogr. (Engl. Transl.) 1978, 23, 547-549.
7. M. Mirbach, M. Wieber in Gmelin Handbook of Inorganic Chemistry, Sb Organoantimony Compounds, Part 5, 8th ed., Springer, Berlin, 1990, p. 115.
8. J. Bordner, G. O. Doak, T. S. Everett, J. Am. Chem. Soc. 1986, 108, 4206-4213.
9. R. L. Damley, K. R. Kabre, J. Am. Chem. Soc. 1965, 87, 4805-4810.
10. 2, refinement program : SHELXL-93, number of free parameters: 1307, hydrogen atoms geometrically positioned and refined with a riding model, final R (I>2σI), R1 = 0.0480, wR2 = 0.0917. The crystallographic data (without structural factors) of the structure described in this publication were deposited as "supplementary publication no. CCDC-179-156." at Cambridge Crystallographic Centre. Copies of the data can be obtained free of charge from the following address: The Director, CCDC, 12 Union Road, Cambridge CB21EZ, UK (Fax: Int. code +(1223)336-033; E-mail: deposit@chemcrys.cam.ac.uk).
11. 2O: Sb-O(Sb) 197.4 pm, Sb-O(O) 208.8 pm [5].
12. S. Ahmad, J. D. McCallum, A. K. Shiemke, E. H. Appelman, T. M. Loehr, J. Sanders-Loehr, Inorg. Chem. 1988, 2230-2233.
13. D. B. Sowerby in The Chemistry of Organic Arsenic, Antimony and Bismuth Compounds, (Ed.: S. Patai), Wiley, Chichester, 1994, p. 72.
14. W. Hewertson, H. R. Watson, J. Chem. Soc. 1962, 1490-1494.