Aldol additions of dihydroxyacetone phosphate to N-Cbz-amino aldehydes catalyzed by L-fuculose-1-phosphate aldolase in emulsion systems: Inversion of stereoselectivity as a function of the acceptor aldehyde

Chemistry - A European Journal

Volumn 11, Issue 5, 2005, Pages 1392-1401

  Espelt, Laia ^a   Bujons, Jordi ^a   Parella, Teodor ^b   Calveras, Jordi ^a   Joglar, Jesús ^a   Delgado, Antonio ^c,d   Clapés, Pere ^a  

^a DEPARTMENT OF ENVIRONMENTAL CHEMISTRY   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^c UNIVERSITY OF BARCELONA   (Spain)

^d CSIC   (Spain)

Author keywords

Biotransformations; DHAP dependent aldolases; Enzyme catalysis; Iminocyclitols; Lyases

Indexed keywords

ALDEHYDES; AMINO ACIDS; BONDING; CATALYSTS; EMULSIONS; ENZYMES; MATHEMATICAL MODELS; PHOSPHATES; REACTION KINETICS; STEREOCHEMISTRY; THERMODYNAMIC PROPERTIES;

AMINO ALDEHYDES; DIHYDROXYACETONE PHOSPHATE; EMULSION SYSTEM; STEREOCHEMICAL ANALYSIS;

ALCOHOLS;

ALDEHYDE DERIVATIVE; AMINOPROPANAL; CARBON; DIHYDROXYACETONE PHOSPHATE; FRUCTOSE BISPHOSPHATE ALDOLASE; IMINOCYCLITOL; LEAD; N BENZYLOXYCARBONYL 3 AMINOPROPANAL; N BENZYLOXYCARBONYLALANINAL; N BENZYLOXYCARBONYLAMINOALDEHYDE; N BENZYLOXYCARBONYLGLYCINAL; N,N DIMETHYLFORMAMIDE; UNCLASSIFIED DRUG;

ADDITION REACTION; ALDOL REACTION; AMINATION; ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; EMULSION; ENANTIOMER; EPIMER; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; THERMODYNAMICS;

ALDEHYDE-LYASES; ALDEHYDES; CATALYSIS; COMPUTER SIMULATION; DIHYDROXYACETONE PHOSPHATE; EMULSIONS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; POLYMERS; STEREOISOMERISM; THERMODYNAMICS;

EID: 14844302834     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400648     Document Type: Article

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