Highly reactive and enantioselective kinetic resolution of terminal epoxides with H2O and HCl catalyzed by new chiral (salen)Co complex linked with Al

Tetrahedron Letters

Volumn 46, Issue 13, 2005, Pages 2263-2266

  Thakur, Santosh Singh ^a   Li, Wenji ^a   Kim, Seong Jin ^b   Kim, Geon Joong ^a  

^a Inha University   (South Korea)

^b RStech Corp #305 Venture Town   (South Korea)

Author keywords

Asymmetric ring opening reactions; Chiral cobalt salen catalyst; Kinetic resolution; Terminal epoxides

Indexed keywords

ALUMINUM; CHLORIDE; EPOXIDE; INORGANIC ACID; WATER;

ARTICLE; CHIRALITY; ENANTIOSELECTIVITY; KINETICS; SYNTHESIS;

EID: 14744302889     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.02.012     Document Type: Article

References (21)

1. L.P.C. Nielson, C.P. Stevenson, D.G. Backmond, and E.N. Jacobson J. Am. Chem. Soc. 126 2004 1360
2. S.K. Kim, and E.N. Jacobsen Angew. Chem., Int. Ed. 43 2004 3952
3. F. Larrow, and E.N. Jacobsen Top. Organomet. Chem. 6 2004 123 and references cited therein
4. E.N. Jacobsen E.N. Jacobsen A. Pfaltz H. Yamamoto Comprehensive Asymmetric Catalysis 2004 Springer-Verlag Berlin, Germany 135 Supplement 2
5. M. Tokunaga, J.F. Larrow, F. Kakiuchi, and E.N. Jacobsen Science 277 1997 936
6. M.E. Furrow, S.E. Schaus, and E.N. Jacobsen J. Org. Chem. 63 1998 6776
7. D.E. White, and E.N. Jacobsen Tetrahedron: Asymmetry 14 2003 3633
8. R. Breinbauer, and E.N. Jacobson Angew. Chem., Int. Ed. 39 2000 3604
9. C.K. Shin, S.J. Kim, and G.-J. Kim Tetrahedron Lett. 45 2004 7429
10. G.-J. Kim, H. Lee, and S.-J. Kim Tetrahedron Lett. 44 2003 5005
11. M. Kwon, and G.-J. Kim Catal. Today 87 2003 145
12. G. Bartoli, M. Bosco, A. Carlone, M. Locatelli, P. Melchiorre, and L. Sambri Org. Lett. 6 2004 3973
13. G. Bartoli, M. Bosco, A. Carlone, M. Locatelli, P. Melchiorre, and L. Sambri Org. Lett. 6 2004 2173
14. Y. Song, X. Yao, H. Chen, C. Bai, X. Hu, and Z. Zheng Tetrahedron Lett. 43 2002 6625
15. J.P. Collman, Z. Wang, A. Straumanis, M. Quelquejeu, and E. Rose J. Am. Chem. Soc. 121 1999 460
16. R.M. Hanson Chem. Rev. 91 1991 437
17. E. Solari, F. Corazza, C. Floriani, A. Chiesi-Villa, and C. Guastini J. Chem. Soc., Dalton Trans. 1990 1345
18. M.S. Taylor, and E.N. Jacobsen Proc. Natl. Acad. Sci. U.S.A. 101 2004 5368
19. H. Aoi, M. Ishimori, and T. Tsuruta Bull. Chem. Soc. Jpn. 48 1975 1897
20. R.G. Konsler, J. Karl, and E.N. Jacobsen J. Am. Chem. Soc. 120 1998 10780
21. R. Breinbauer, and E.N. Jacobsen Angew. Chem., Int. Ed. 39 2000 3604