Regioselective formation of β-alkyl-α-phenyliridabenzenes via unsymmetrical 3-vinylcyclopropenes: Probing steric and electronic influences by varying the alkyl ring substituent

Chemistry - A European Journal

Volumn 11, Issue 4, 2005, Pages 1191-1200

  Wu, He Ping ^a   Weakley, Timothy J R ^a   Haley, Michael M ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

Aromaticity; Iridium; Metallacycles; Strained molecules; Valence isomerization

Indexed keywords

ISOMERIZATION; PROPYLENE; REACTION KINETICS; SYNTHESIS (CHEMICAL); X RAYS;

CYCLOPROPENES; FIRST-ORDER KINETICS; REGIOSELECTIVITY; STRUCTURAL DATA;

BENZENE;

3 (2 IODOVINYL) 2 PHENYL 1 CYCLOPROPENE DERIVATIVE; 3 VINYLCYCLOPROPENE DERIVATIVE; ALKYL GROUP; ALPHA PHENYLIRIDABENZENE DERIVATIVE; BENZENE DERIVATIVE; CYCLOPENTADIENE DERIVATIVE; CYCLOPENTADIENYLIRIDIUM COMPLEX; IRIDABENZENE; IRIDABENZVALENE; IRIDIUM; PHENYL GROUP; PHOSPHINE DERIVATIVE; PROPYLENE; TRIMETHYLPHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; HEATING; INFRARED SPECTROSCOPY; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REPRODUCIBILITY; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS; TECHNIQUE; THERMOSTABILITY; X RAY DIFFRACTION;

EID: 14544301411     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400893     Document Type: Article

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