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Volumn 21, Issue 14, 2002, Pages 2824-2826

Metallabenzenes and valence isomers. 3. Unexpected rearrangement of two regioisomeric iridabenzenes to an (η5-cyclopentadienyl)iridium(I) complex

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Indexed keywords

CHEMICAL SHIFTS;

EID: 0001660455     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0201563     Document Type: Article
Times cited : (64)

References (30)
  • 1
  • 11
    • 84987566668 scopus 로고
    • Cyclopropene 6 was prepared in 30% yield using copper powder instead of the reported rhodium complex as the catalyst for the reaction of 1-phenyl-2-(trimethysilyl)acetylene with ethyl diazoacetate: Müller, P.; Gränicher, C. Helv. Chim. Acta 1993, 76, 521-534.
    • (1993) Helv. Chim. Acta , vol.76 , pp. 521-534
    • Müller, P.1    Gränicher, C.2
  • 15
    • 0037891366 scopus 로고    scopus 로고
    • note
    • 2) = 0.052 (all data). Data were collected on an Enraf-Nonius CAD-4 Turbo diffractometer. Structure refinement (C atoms anisotropic, H atoms isotropic) was accomplished with the teXsan program suite (version 1.7 for SGI workstations).
  • 17
    • 0037553427 scopus 로고    scopus 로고
    • Unpublished results
    • In addition to the NMR experiments, compound 11 can be intercepted by a second iridium fragment, which is only produced at elevated temperatures needed to give 10. The structure of the resultant dinuclear complex has been confirmed by X-ray crystallography: Wu, H.-P.; Weakley, T. J. R.; Haley, M. M. Unpublished results.
    • Wu, H.-P.1    Weakley, T.J.R.2    Haley, M.M.3
  • 20
    • 0000227804 scopus 로고
    • Relevant examples of carbene migratory insertion, inter alia: (a) Threlkel, R. S.; Bercaw, J. E. J. Am. Chem. Soc. 1981, 703, 2650-2659.
    • (1981) J. Am. Chem. Soc. , vol.703 , pp. 2650-2659
    • Threlkel, R.S.1    Bercaw, J.E.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.