Simple and Efficient Routes to Optically Active chiro- and allo-Inositol Derivatives from myo-Inositol

Synlett

Volumn , Issue 3, 2004, Pages 493-496

  Sureshan, Kana M ^a   Watanabe, Yutaka ^a  

^a EHIME UNIVERSITY   (Japan)

Author keywords

Carbohydrates; Cyclitols; Inhibitors; Inositols; Regioselectivity

Indexed keywords

1,2:4,5 DI O ISOPROPYLIDENE INOSITOL; 1,6:3,4 DI O ISOPROPYLIDENE INOSITOL; CARBAMIC ACID; INOSITOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ENANTIOMER; METHODOLOGY; SYNTHESIS;

EID: 1442286556     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-815443     Document Type: Article

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50. 4) and evaporated. The crude mixture of 3D and 4D thus obtained was dissolved in DMA (7 mL) and reacted with KOAc (500 mg, 5 mmol) at 70-80°C for 5 h. DMA was evaporated and usual work-up of the residue followed by column chromatography yielded 5L (124 mg, 41%) and 8D (186 mg, 54%).