메뉴 건너뛰기




Volumn 3, Issue 11-12, 2004, Pages 1026-1031

Refractive index effects on the oscillator strength and radiative decay rate of 2,3-diazabicyclo[2.2.2]oct-2-ene

Author keywords

[No Author keywords available]

Indexed keywords

2,3 DIAZABICYCLO[2.2.2]OCT 2 ENE; BETA CYCLODEXTRIN; CARBON DISULFIDE; HETEROCYCLIC COMPOUND; PERFLEXANE; UNCLASSIFIED DRUG;

EID: 13444282649     PISSN: 1474905X     EISSN: 14749092     Source Type: Journal    
DOI: 10.1039/b412936a     Document Type: Article
Times cited : (91)

References (49)
  • 2
    • 36849126497 scopus 로고
    • Relationship between absorption intensity and fluorescence lifetime of molecules
    • S. J. Strickler R. A. Berg Relationship between absorption intensity and fluorescence lifetime of molecules J. Chem. Phys. 1962 37 814-822.
    • (1962) J. Chem. Phys. , vol.37 , pp. 814-822
    • Strickler, S.J.1    Berg, R.A.2
  • 3
    • 0001281097 scopus 로고
    • The quantum theory of radiation
    • A. Einstein The quantum theory of radiation Physik. Z. 1917 18 121-128.
    • (1917) Physik. Z. , vol.18 , pp. 121-128
    • Einstein, A.1
  • 6
    • 0001433022 scopus 로고    scopus 로고
    • Fluorescence quantum yields and their relation to lifetimes of rhodamine 6G and fluorescein in nine solvents: Improved absolute standards for quantum yields
    • D. Magde R. Wong P. G. Seybold Fluorescence quantum yields and their relation to lifetimes of rhodamine 6G and fluorescein in nine solvents: Improved absolute standards for quantum yields Photochem. Photobiol. 2002 75 327-334.
    • (2002) Photochem. Photobiol. , vol.75 , pp. 327-334
    • Magde, D.1    Wong, R.2    Seybold, P.G.3
  • 8
    • 0001538514 scopus 로고    scopus 로고
    • Influence of surrounding dielectrics on the spontaneous emission of sulforhodamine B molecules
    • P. Lavallard M. Rosenbauer T. Gacoin Influence of surrounding dielectrics on the spontaneous emission of sulforhodamine B molecules Phys. Rev. A 1996 54 5450-5433.
    • (1996) Phys. Rev. A , vol.54
    • Lavallard, P.1    Rosenbauer, M.2    Gacoin, T.3
  • 9
    • 0032613998 scopus 로고    scopus 로고
    • Optical properties of dye molecules as a function of surrounding dielectric medium
    • G. Lamouche P. Lavallard T. Gacoin Optical properties of dye molecules as a function of surrounding dielectric medium Phys. Rev. A 1999 59 4668-4674.
    • (1999) Phys. Rev. A , vol.59 , pp. 4668-4674
    • Lamouche, G.1    Lavallard, P.2    Gacoin, T.3
  • 10
    • 0031998087 scopus 로고    scopus 로고
    • Spontaneous emission of dye molecules as a function of the surrounding dielectric medium
    • G. Lamouche P. Lavallard T. Gacoin Spontaneous emission of dye molecules as a function of the surrounding dielectric medium J. Luminesc. 1998 76/77 662-665.
    • (1998) J. Luminesc. , vol.76-77 , pp. 662-665
    • Lamouche, G.1    Lavallard, P.2    Gacoin, T.3
  • 11
    • 0037061949 scopus 로고    scopus 로고
    • Effect of the solvent refractive index on the excited-state lifetime of a single tryptophan residue in a protein
    • D. Toptygin R. S. Savtchenko N. D. Meadow S. Roseman L. Brand Effect of the solvent refractive index on the excited-state lifetime of a single tryptophan residue in a protein J. Phys.Chem. B 2002 106 3724-3734.
    • (2002) J. Phys.Chem. B , vol.106 , pp. 3724-3734
    • Toptygin, D.1    Savtchenko, R.S.2    Meadow, N.D.3    Roseman, S.4    Brand, L.5
  • 12
    • 0027762802 scopus 로고
    • Fluorescence decay of DPH in lipid membranes: Influence of the external refractive index
    • D. Toptygin L. Brand Fluorescence decay of DPH in lipid membranes: Influence of the external refractive index Biophys. Chem. 1993 48 205-220.
    • (1993) Biophys. Chem. , vol.48 , pp. 205-220
    • Toptygin, D.1    Brand, L.2
  • 13
    • 0035803745 scopus 로고    scopus 로고
    • Polarizabilities inside molecular containers
    • C. Marquez W. M. Nau Polarizabilities inside molecular containers Angew. Chem. Int. Ed. 2001 40 4387-4390.
    • (2001) Angew. Chem. Int. Ed. , vol.40 , pp. 4387-4390
    • Marquez, C.1    Nau, W.M.2
  • 14
    • 0000586380 scopus 로고
    • Solvent effects on the oxygen–organic molecule charge-transfer absorption
    • Y. Kuriyama P. R. Ogilby K. V. Mikkelsen Solvent effects on the oxygen–organic molecule charge-transfer absorption J. Phys. Chem. 1994 98 11918-11923.
    • (1994) J. Phys. Chem. , vol.98 , pp. 11918-11923
    • Kuriyama, Y.1    Ogilby, P.R.2    Mikkelsen, K.V.3
  • 18
    • 0017575026 scopus 로고
    • Conjugated polyene fatty acids on fluorescent probes: Spectroscopic characterization
    • L. A. Sklar B. S. Hudson M. Petersen J. Diamond Conjugated polyene fatty acids on fluorescent probes: Spectroscopic characterization Biochemistry 1977 16 813-819.
    • (1977) Biochemistry , vol.16 , pp. 813-819
    • Sklar, L.A.1    Hudson, B.S.2    Petersen, M.3    Diamond, J.4
  • 19
    • 0000074933 scopus 로고
    • Environmental effects on radiative rate constants with applications to linear polyenes
    • J. R. Andrews B. S. Hudson Environmental effects on radiative rate constants with applications to linear polyenes J. Chem. Phys. 1978 68 4587-4594.
    • (1978) J. Chem. Phys. , vol.68 , pp. 4587-4594
    • Andrews, J.R.1    Hudson, B.S.2
  • 20
    • 25544477274 scopus 로고
    • The fluorescence of all-trans diphenyl polyenes
    • J. B. Birks G. N. R. Tripathy M. D. Lumb The fluorescence of all-trans diphenyl polyenes Chem. Phys. 1978 33 185-194.
    • (1978) Chem. Phys. , vol.33 , pp. 185-194
    • Birks, J.B.1    Tripathy, G.N.R.2    Lumb, M.D.3
  • 21
    • 33846187357 scopus 로고
    • The influence of intermolecular interaction on the forbidden near-IR transitions in molecular oxygen
    • B. F. Minaev S. Lunell G. I. Kobzev The influence of intermolecular interaction on the forbidden near-IR transitions in molecular oxygen J. Mol. Struct. (THEOCHEM) 1993 284 1-9.
    • (1993) J. Mol. Struct. (THEOCHEM) , vol.284 , pp. 1-9
    • Minaev, B.F.1    Lunell, S.2    Kobzev, G.I.3
  • 23
    • 0037123407 scopus 로고    scopus 로고
    • Biomolecular and supramolecular kinetics in the submicrosecond time domain: The fluorazophore approach
    • X. Wang W. M. Nau Biomolecular and supramolecular kinetics in the submicrosecond time domain: the fluorazophore approach ChemPhysChem 2002 3 393-398.
    • (2002) ChemPhysChem , vol.3 , pp. 393-398
    • Wang, X.1    Nau, W.M.2
  • 24
    • 0032501391 scopus 로고    scopus 로고
    • A fluorescent probe for antioxidants
    • W. M. Nau A fluorescent probe for antioxidants J. Am. Chem. Soc. 1998 120 12614-12618.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 12614-12618
    • Nau, W.M.1
  • 25
    • 0037174403 scopus 로고    scopus 로고
    • Increased antioxidant reactivity of vitamin C at low pH in model membranes
    • G. Gramlich J. Zhang W. M. Nau Increased antioxidant reactivity of vitamin C at low pH in model membranes J. Am. Chem. Soc. 2002 124 11252-11253.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 11252-11253
    • Gramlich, G.1    Zhang, J.2    Nau, W.M.3
  • 26
    • 2342598922 scopus 로고    scopus 로고
    • Diffusion of a-tocopherol in membrane models: Probing the kinetics of vitamin E antioxidant action by fluorescence in real time
    • G. Gramlich J. Zhang W. M. Nau Diffusion of a-tocopherol in membrane models: Probing the kinetics of vitamin E antioxidant action by fluorescence in real time J. Am. Chem. Soc. 2004 126 5482-5492.
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 5482-5492
    • Gramlich, G.1    Zhang, J.2    Nau, W.M.3
  • 27
    • 0033536469 scopus 로고    scopus 로고
    • An exceedingly long-lived fluorescent state as a distinct structural and dynamic probe for supramolecular association: An exploratory study of host–guest complexation by cyclodextrins
    • W. M. Nau X. Zhang An exceedingly long-lived fluorescent state as a distinct structural and dynamic probe for supramolecular association: An exploratory study of host–guest complexation by cyclodextrins J. Am. Chem. Soc. 1999 121 8022-8032.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 8022-8032
    • Nau, W.M.1    Zhang, X.2
  • 28
    • 2342447320 scopus 로고    scopus 로고
    • Cucurbiturils: Molecular nanocapsules for time-resolved fluorescence-based assays
    • C. Marquez F. Huang W. M. Nau Cucurbiturils: molecular nanocapsules for time-resolved fluorescence-based assays IEEE Trans. Nanobiosci. 2004 3 39-45.
    • (2004) IEEE Trans. Nanobiosci. , vol.3 , pp. 39-45
    • Marquez, C.1    Huang, F.2    Nau, W.M.3
  • 29
    • 0037196288 scopus 로고    scopus 로고
    • A fluorescence-based method for direct measurement of submicrosecond intramolecular contact formation in biopolymers: An exploratory study with polypeptides
    • R. R. Hudgins F. Huang G. Gramlich W. M. Nau A fluorescence-based method for direct measurement of submicrosecond intramolecular contact formation in biopolymers: An exploratory study with polypeptides J. Am. Chem. Soc. 2002 124 556-564.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 556-564
    • Hudgins, R.R.1    Huang, F.2    Gramlich, G.3    Nau, W.M.4
  • 30
    • 0038319135 scopus 로고    scopus 로고
    • A conformational flexibility scale for amino acids in peptides
    • F. Huang W. M. Nau A conformational flexibility scale for amino acids in peptides Angew. Chem. Int. Ed. 2003 42 2269-2272.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 2269-2272
    • Huang, F.1    Nau, W.M.2
  • 31
    • 1642576003 scopus 로고    scopus 로고
    • Kinetics of end-to-end collision in short single-stranded nucleic acids
    • X. Wang W. M. Nau Kinetics of end-to-end collision in short single-stranded nucleic acids J. Am. Chem. Soc. 2004 126 808-813.
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 808-813
    • Wang, X.1    Nau, W.M.2
  • 32
    • 0000113711 scopus 로고
    • Primary processes in the photochemistry of bicyclic azo compounds
    • B. S. Solomon T. F. Thomas C. Steel Primary processes in the photochemistry of bicyclic azo compounds J. Am. Chem. Soc. 1968 90 2249-2258.
    • (1968) J. Am. Chem. Soc. , vol.90 , pp. 2249-2258
    • Solomon, B.S.1    Thomas, T.F.2    Steel, C.3
  • 33
    • 0000630956 scopus 로고    scopus 로고
    • Fluorescence of 2,3-diazabicyclo[2.2.2]oct-2-ene revisited: Solvent-induced quenching of the n, p*-excited state by an aborted hydrogen atom transfer
    • W. M. Nau G. Greiner H. Rau J. Wall M. Olivucci J. C. Scaiano Fluorescence of 2,3-diazabicyclo[2.2.2]oct-2-ene revisited: Solvent-induced quenching of the n, p*-excited state by an aborted hydrogen atom transfer J. Phys. Chem. A 1999 103 1579-1584.
    • (1999) J. Phys. Chem. A , vol.103 , pp. 1579-1584
    • Nau, W.M.1    Greiner, G.2    Rau, H.3    Wall, J.4    Olivucci, M.5    Scaiano, J.C.6
  • 34
    • 0037174415 scopus 로고    scopus 로고
    • Quenching of n, p*-excited states in the gas phase: Variations in absolute reactivity and selectivity
    • D. Klapstein U. Pischel W. M. Nau Quenching of n, p*-excited states in the gas phase: variations in absolute reactivity and selectivity J. Am. Chem. Soc. 2002 124 11349-11357.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 11349-11357
    • Klapstein, D.1    Pischel, U.2    Nau, W.M.3
  • 35
    • 37049129002 scopus 로고
    • The fluorescence of cyclic azo-compounds: Determination of singlet lifetimes
    • C. Steel T. F. Thomas The fluorescence of cyclic azo-compounds: Determination of singlet lifetimes Chem. Commun. 1966 900-902.
    • (1966) Chem. Commun. , pp. 900-902
    • Steel, C.1    Thomas, T.F.2
  • 36
    • 0001753363 scopus 로고
    • Reaction of 1,3-cyclohexadiene with azodicarboxylic acid diethyl ester
    • R. Askani Reaction of 1,3-cyclohexadiene with azodicarboxylic acid diethyl ester Chem. Ber. 1965 98 2551-2555.
    • (1965) Chem. Ber. , vol.98 , pp. 2551-2555
    • Askani, R.1
  • 37
    • 84885393188 scopus 로고
    • Reference materials for fluorescence measurement
    • D. F. Eaton Reference materials for fluorescence measurement Pure Appl. Chem. 1988 60 1107-1114.
    • (1988) Pure Appl. Chem. , vol.60 , pp. 1107-1114
    • Eaton, D.F.1
  • 38
    • 85034326923 scopus 로고    scopus 로고
    • Since any quenching by the solvent itself, solvent impurities or traces of oxygen lower the fluorescence lifetimes and quantum yields by the same extent, the radiative lifetimes of DBO (presenting the ratio of these experimental data) are insensitive to quenching. In other words, all radiationless deactivation processes are explicitly corrected for and can be neglected in the present analysis
    • Since any quenching by the solvent itself, solvent impurities or traces of oxygen lower the fluorescence lifetimes and quantum yields by the same extent, the radiative lifetimes of DBO (presenting the ratio of these experimental data) are insensitive to quenching. In other words, all radiationless deactivation processes are explicitly corrected for and can be neglected in the present analysis.
  • 39
    • 0031950660 scopus 로고    scopus 로고
    • The mechanism for hydrogen abstraction by n, p* excited singlet states: Evidence for thermal activation and deactivation through a conical intersection
    • W. M. Nau G. Greiner J. Wall H. Rau M. Olivucci M. A. Robb The mechanism for hydrogen abstraction by n, p* excited singlet states: Evidence for thermal activation and deactivation through a conical intersection Angew. Chem. Int. Ed. 1998 37 98-101.
    • (1998) Angew. Chem. Int. Ed. , vol.37 , pp. 98-101
    • Nau, W.M.1    Greiner, G.2    Wall, J.3    Rau, H.4    Olivucci, M.5    Robb, M.A.6
  • 40
    • 0010461139 scopus 로고    scopus 로고
    • Structure–reactivity relationships in the photoreduction of n, p*-excited ketones and azoalkanes: The effect of reaction thermodynamics, excited-state electrophilicity and antibonding character in the transition state
    • U. Pischel W. M. Nau Structure–reactivity relationships in the photoreduction of n, p*-excited ketones and azoalkanes: The effect of reaction thermodynamics, excited-state electrophilicity and antibonding character in the transition state Photochem. Photobiol. Sci. 2002 1 141-147.
    • (2002) Photochem. Photobiol. Sci. , vol.1 , pp. 141-147
    • Pischel, U.1    Nau, W.M.2
  • 41
    • 85034356619 scopus 로고    scopus 로고
    • The failure to recognize the large variations in the previous study are due to several circumstances including (1) an incorrectly reported fluorescence quantum yield in the gas phase from the literature (see also main text), (2) a restricted choice of solvents with similar polarizability, (3) larger errors (±15%) of quantum yield measurement, and (4) an apparently erratic fluorescence quantum yield measured for benzene
    • The failure to recognize the large variations in the previous study are due to several circumstances including (1) an incorrectly reported fluorescence quantum yield in the gas phase from the literature (see also main text), (2) a restricted choice of solvents with similar polarizability, (3) larger errors (±15%) of quantum yield measurement, and (4) an apparently erratic fluorescence quantum yield measured for benzene.
  • 42
    • 0000515969 scopus 로고
    • Correction for refractive index in the comparison of radiative lifetimes in vapor and solution phases
    • S. Hirayama D. Phillips Correction for refractive index in the comparison of radiative lifetimes in vapor and solution phases J. Photochem. 1980 12 139-145.
    • (1980) J. Photochem. , vol.12 , pp. 139-145
    • Hirayama, S.1    Phillips, D.2
  • 43
    • 0002520335 scopus 로고
    • The refractive index correction to the radiative rate constant in fluorescence lifetime measurements
    • R. A. Lampert S. R. Meech J. Metcalfe D. Phillips A. P. Schaap The refractive index correction to the radiative rate constant in fluorescence lifetime measurements Chem. Phys. Lett. 1983 94 137-140.
    • (1983) Chem. Phys. Lett. , vol.94 , pp. 137-140
    • Lampert, R.A.1    Meech, S.R.2    Metcalfe, J.3    Phillips, D.4    Schaap, A.P.5
  • 44
    • 0000530498 scopus 로고
    • 2 in n-hexane and n-tetradecane. Medium and deuterium isotope effects on decay processes
    • 2 in n-hexane and n-tetradecane. Medium and deuterium isotope effects on decay processes J. Phys. Chem. 1993 97 2516-2522.
    • (1993) J. Phys. Chem. , vol.97 , pp. 2516-2522
    • Saltiel, J.1    Waller, A.S.2    Sears, J.D.F.3    Garrett, C.Z.4
  • 45
    • 0002697254 scopus 로고
    • The refractive-index correction to the radiative rate constant
    • T. Shibuya The refractive-index correction to the radiative rate constant Chem. Phys. Lett. 1983 103 46-48.
    • (1983) Chem. Phys. Lett. , vol.103 , pp. 46-48
    • Shibuya, T.1
  • 46
    • 0345829103 scopus 로고    scopus 로고
    • Effects of the solvent refractive index and its dispersion on the radiative decay rate and extinction coefficient of a fluorescent solute
    • D. Toptygin Effects of the solvent refractive index and its dispersion on the radiative decay rate and extinction coefficient of a fluorescent solute J. Fluoresc. 2003 13 201-219.
    • (2003) J. Fluoresc. , vol.13 , pp. 201-219
    • Toptygin, D.1
  • 47
    • 0038266113 scopus 로고    scopus 로고
    • Dipole and oscillator strengths of chromophores in solution
    • R. S. Knox Dipole and oscillator strengths of chromophores in solution Photochem. Photobiol. 2003 77 492-496.
    • (2003) Photochem. Photobiol. , vol.77 , pp. 492-496
    • Knox, R.S.1
  • 48
    • 0029556376 scopus 로고
    • Phosphorescence and transient absorption of azoalkane triplet states
    • W. Adam G. Fragale D. Klapstein W. M. Nau J. Wirz Phosphorescence and transient absorption of azoalkane triplet states J. Am. Chem. Soc. 1995 117 12578-12592.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 12578-12592
    • Adam, W.1    Fragale, G.2    Klapstein, D.3    Nau, W.M.4    Wirz, J.5
  • 49
    • 0035498894 scopus 로고    scopus 로고
    • Radiative decay engineering: Biophysical and biomedical applications
    • J. R. Lakowicz Radiative decay engineering: Biophysical and biomedical applications Anal. Biochem. 2001 298 1-24.
    • (2001) Anal. Biochem. , vol.298 , pp. 1-24
    • Lakowicz, J.R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.