ABC BCD polymerization: A self-condensing vinyl and cyclic ester polymerization by combination free-radical and ring-opening techniques

Macromolecules

Volumn 32, Issue 26, 1999, Pages 8753-8759

  Mecerreyes, David ^a   Trollsås, Mikael ^a   Hedrick, James L ^a  

^a IBM ALMADEN RESEARCH CENTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BROMINE COMPOUNDS; COMPOSITION EFFECTS; FREE RADICAL POLYMERIZATION; MOLECULAR STRUCTURE; MONOMERS; POLYACRYLATES; POLYESTERS; RING OPENING POLYMERIZATION; VINYL RESINS;

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP); POLYBROMODIMETHYLPROPIONATE; POLYCAPROLACTONE; POLYHYDROXYETHYL METHACRYLATE;

COPOLYMERS;

EID: 12944288303     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9908898     Document Type: Article

References (36)

1. (a) Fréchet, J. M. J.; Henmi, M.; Gitsov, I.; Aoshima, S.; Leduc, M. R.; Grubbs, R. B. Science 1995, 269, 1080.
2. (b) Hawker, C. J.; Fréchet, J. M. J.; Grubbs, R. G.; Dao, J. J Am. Chem. Soc. 1995, 117, 10763.
3. (c) Gaynor, S. G.; Edelman, S.; Matyjaszewski, K. Macromolecules 1996, 29, 1079.
4. (d) Lu, P.; Paulasaari, J. K.; Webber, W. P. Macromolecules 1997, 30, 7024.
5. (e) Matyjaszewski, K.; Gaynor, S. G.; Kulfan, A.; Podwika, M. Macromolecules 1997, 30, 5192.
6. (f) Matyjaszewski, K.; Pyun, J.; Gaynor, S. Macromol. Rapid Commun. 1998, 19, 665.
7. (g) Weimer, M. W.; Fréchet, J. M. J.; Gitsov, I. J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 955.
8. (a) Weimer, M. W.; Scherman, O. A.; Sogah, D. Y. Macromolecules 1998, 31, 8425.
9. (b) Mecerreyes, D.; Moineau, G.; Dubois, Ph.; Jerome, R.; Hawker, C. J.; Hedrick, J. L.; Malmström, E.; Trollsås, M. Angew. Chem., Int. Ed. Engl. 1998, 37, 1274.
10. (c) Mecerreyes, D.; Atthoff, B.; Boduch, K. A.; Trollsås, M.; Hedrick, J. L. Macromolecules 1999, 32, 5175.
11. (d) Klaerner, G.; Trollsås, M.; Heise, A.; Husemann, M.; Atthoff, B.; Hawker, C. J.; Miller, R. D.; Hedrick, J. L. Macromolecules 1999, 32, 8227.
12. (a) Tomalia, D. A.; Hedstrand, D. M.; Ferrito, M. S. Macromolecules 1991, 24, 1438.
13. (b) Gauthier, M.; Möller, M. Macromolecules 1991, 24, 4548.
14. (c) Hempenius, M. A.; Michelberger, W.; Möller, M. Macromolecules 1997, 30, 5602.
15. Grubbs, R. G.; Hawker, C. J.; Dao, J.; Fréchet, J. M. J. Angew. Chem., Int. Ed. Engl. 1997, 36, 270.
16. (a) Six, J.-L.; Gnanou, Y. Macromol. Symp. 1995, 95, 137.
17. (b) Trollsås, M.; Hedrick, J. L. J. Am. Chem. Soc. 1998, 120, 4644.
18. (c) Trollsås, M.; Claesson, H.; Atthoff, B.; Hedrick, J. L. Angew. Chem., Int. Ed. Engl. 1998, 37, 3132.
19. (d) Atthoff, B.; Trollsås, M.; Claesson, H.; Hedrick, J. L. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1998, 39 (2), 76.
20. (e) Hedrick, J. L.; Trollsås, M.; Hawker, C. J.; Atthoff, B.; Claesson, H.; Heise, A.; Miller, R, D.; Mecerreeyes, D.; Jérôme, R.; Dubois, Ph. Macromolecules 1998, 31, 8691.
21. (f) Birchall, A. C.; North, M. Chem. Commun. 1998, 1335.
22. Trollsàs, M.; Kelly, M.; Claesson, H.; Siemens, R.; Hedrick, J. L. Macromolecules 1999, 32, 4917.
23. (a) Müller, A. H. E.; Van, D.; Wulkow, M. Macromolecules 1997, 30, 7015.
24. (b) Yan, D.; Miller, A. H. E.; Matyjaszewski, K. Macromolecules 1997, 30, 7024.
25. (c) Matyjaszewski, K.; Gaynor, S. G.; Müller, A. H. E. Macromolecules 1997, 30, 7034.
26. (d) Matyjaszewski, K.; Gaynor, S. G. Macromolecules 1997, 30, 7042.
27. (e) Yan, D.; Zhou, D.; Müller, A. H. E.; Macromolecules 1999, published on the Web.
28. 3) for PMMA.
29. 5b (10) The DP's of the PMMA blocks were calculated by a method previously published: Heise, A.; Hedrick, J. L.; Trollsås, M.; Miller, R. D.; Frank, C. W. Macromolecules 1999, 32, 231 and references cited therein.
30. 1H NMR spectroscopy.
31. (a) Kim, Y. H.; Webster, O. J. Am. Chem. Soc. 1990, 112, 4592.
32. (b) Hawker, C. J.; Lee, R.; Fréchet, J. M. J. J. Am. Chem. Soc. 1991, 113, 4583.
33. (c) Johansson, M.; Malmström, E.; Huit, A. J. Polym. Sci. 1993, 31, 619.
34. Masters, A. P.; Sorensen, T. S. Can. J. Chem. 1990, 68, 492.
35. (a) Mecerreyes, D.; Dubois, P.; Jerome, R.; Hedrick, J. L. Macromol. Chem. Phys. 1999, 200, 156.
36. (b) Hawker, C. J.; Mecerreyes, D.; Elce, E.; Dao, J.; Hedrick, J. L.; Barakat, I.; Dubois, P.; Jerome, R.; Volksen, W. Macromol. Chem. Phys. 1997, 198, 155.