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0642381438
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note
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Theoretical molecular weight is calculated from the molar ratio of styrene (180 mmol) and 1 (20 mmol) to initiator 3 (1.0 mmol) and is based on a conversion of 85%.
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0642319998
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note
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1H NMR signal for the methylene protons of grafted butyl methacrylate (δ = 3.9) to the signals of the aromatic protons of the initiator (δ = 6.8-7.2). MALLS studies were performed in 2-butanone at 25 °C with Wyatt DAWN and Optilab instrumentation; dn/dc = 0.1465 for 41, and dn/dc = 0.1460 for 8h.
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0642320007
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note
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Because GPC is calibrated with linear polymers, the polydispersities of the dendrigraft macromolecules may be underestimated.
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note
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4-Hydroxymethylstyrene was prepared from commercially available 4-acetoxymethylstyrene (Kodak) by simple alkaline hydrolysis.
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