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Volumn 127, Issue 3, 2005, Pages 848-849

The total synthesis of gambierol

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; CIGUATOXIN; CYCLIC ENOL ETHER; DIENYL STANNANE; GAMBIEROL; MARINE TOXIN; OXEPENE; POLYETHER DERIVATIVE; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG;

EID: 12444338890     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja043396d     Document Type: Article
Times cited : (100)

References (35)
  • 23
    • 12444277266 scopus 로고    scopus 로고
    • note
    • Attempts to generate the acyclic enol ether using other alkylidene reagents (Tebbe, Petasis, Takeda) were also unsuccessful.
  • 24
    • 0000091226 scopus 로고
    • The Tebbe reagent has been used to carry out related cyclizations. (a) Stille, J. R.; Grubbs, R. H. J. Am. Chem. Soc. 1986, 108, 855.
    • (1986) J. Am. Chem. Soc. , vol.108 , pp. 855
    • Stille, J.R.1    Grubbs, R.H.2
  • 30
    • 12444333594 scopus 로고    scopus 로고
    • note
    • 3) into 15 in an unoptimized 60% yield using the Grubbs 2 catalyst.
  • 31
    • 12444296499 scopus 로고    scopus 로고
    • note
    • At present, we do not have a clear explanation for the facial selectivity in the DMDO oxidation of 15. Sasaki observed similar selectivity in the hydroboration of a related oxepene in his gambierol work.4a,b


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.