Comparison of the Kinetics and Thermodynamics for Methyl Radical Addition to C=C, C=O, and C=S Double Bonds

Journal of the American Chemical Society

Volumn 126, Issue 6, 2004, Pages 1732-1740

  Henry, David J ^a   Coote, Michelle L ^a   Gómez Balderas, Rodolfo ^a,b,c   Radom, Leo ^a,b  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^b UNIVERSITY OF SYDNEY   (Australia)

^c UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; ENTHALPY; MATHEMATICAL MODELS; OLEFINS; PHASE TRANSITIONS; RATE CONSTANTS; SUBSTRATES;

CONTRATHERMODYNAMIC REACTIONS; REACTION BARRIERS;

METHANOL;

ALKENE; CARBON; CARBONYL DERIVATIVE; METHYL GROUP; OXYGEN; RADICAL; SULFUR; THIOCARBONYL DERIVATIVE; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ADDITION REACTION; ARTICLE; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; COVALENT BOND; DENSITY; DOUBLE BOND; ELECTRON SPIN DENSITY; ENERGY TRANSFER; ENTHALPY; ENTROPY; REACTION TIME; REVERSE BETA SCISSION REACTION; THERMODYNAMICS;

EID: 1242314249     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039139a     Document Type: Article

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